GB201013201D0 - Adhesive composition with enhanced cure through volume - Google Patents
Adhesive composition with enhanced cure through volumeInfo
- Publication number
- GB201013201D0 GB201013201D0 GBGB1013201.7A GB201013201A GB201013201D0 GB 201013201 D0 GB201013201 D0 GB 201013201D0 GB 201013201 A GB201013201 A GB 201013201A GB 201013201 D0 GB201013201 D0 GB 201013201D0
- Authority
- GB
- United Kingdom
- Prior art keywords
- radically curable
- component
- curing
- ester
- metal salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000000853 adhesive Substances 0.000 title abstract 2
- 230000001070 adhesive effect Effects 0.000 title abstract 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 abstract 1
- 239000001263 FEMA 3042 Substances 0.000 abstract 1
- 239000004825 One-part adhesive Substances 0.000 abstract 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- -1 chromanols Natural products 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 229940074391 gallic acid Drugs 0.000 abstract 1
- 235000004515 gallic acid Nutrition 0.000 abstract 1
- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 150000002429 hydrazines Chemical class 0.000 abstract 1
- 229960004337 hydroquinone Drugs 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 229940079877 pyrogallol Drugs 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 235000015523 tannic acid Nutrition 0.000 abstract 1
- 229940033123 tannic acid Drugs 0.000 abstract 1
- 229920002258 tannic acid Polymers 0.000 abstract 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 abstract 1
- 229930003799 tocopherol Natural products 0.000 abstract 1
- 239000011732 tocopherol Substances 0.000 abstract 1
- 235000019149 tocopherols Nutrition 0.000 abstract 1
- 150000004992 toluidines Chemical class 0.000 abstract 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Curing through large bond gaps, of approximately 0.5-1.0mm, has proven particularly challenging in the field of adhesives technology. There is difficulty associated with providing one-part adhesive formulations capable of curing through large bond gaps. Disclosed herein are radically curable compositions comprising a radically curable component, and an initiator component capable of initiating cure of the radically curable component. The initiator comprises at least one metal salt and a free radical generating component. The metal salt of the composition is chosen so that it is reduced at the surface to which it is applied. The compositions further comprise a reducing additive, such as a benzoin or ester thereof, ascorbic acid or an ester thereof, hydrazines, toluidines, tin (II) salts or compounds illustrated by two general structures disclosed within the application. Compounds according to the structures may, for example, be tocopherols, chromanols, gallic acid, tannic acid, pyrogallol or hydroquinone.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1013201.7A GB2482531B (en) | 2010-08-05 | 2010-08-05 | Adhesive composition with enhanced cure through volume |
| PCT/EP2011/063491 WO2012017057A1 (en) | 2010-08-05 | 2011-08-04 | Adhesive composition with enhanced cure through volume |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1013201.7A GB2482531B (en) | 2010-08-05 | 2010-08-05 | Adhesive composition with enhanced cure through volume |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB201013201D0 true GB201013201D0 (en) | 2010-09-22 |
| GB2482531A GB2482531A (en) | 2012-02-08 |
| GB2482531B GB2482531B (en) | 2013-11-13 |
Family
ID=42931253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1013201.7A Expired - Fee Related GB2482531B (en) | 2010-08-05 | 2010-08-05 | Adhesive composition with enhanced cure through volume |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB2482531B (en) |
| WO (1) | WO2012017057A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104959117B (en) * | 2015-06-25 | 2017-05-10 | 福州大学 | A kind of pyrogallol bonded silica gel adsorbent and its preparation method and application |
| WO2019178645A1 (en) * | 2018-03-23 | 2019-09-26 | Csl Limited | Method of treating asthma |
| AU2024290964A1 (en) | 2023-07-05 | 2026-01-08 | CSL Innovation Pty Ltd | Methods of treating or preventing a complication of sickle cell disease |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3970505A (en) | 1973-01-15 | 1976-07-20 | Loctite Corporation | Anaerobic compositions and surface activator therefor |
| GB2279354A (en) * | 1993-06-24 | 1995-01-04 | Nat Starch Chem Corp | Method of sealing leaks in underground gas mains and compositions for use therein |
| CA2136882A1 (en) | 1993-12-20 | 1995-06-21 | William J. Catena | Structural acrylic adhesives |
| DE19501933A1 (en) * | 1995-01-24 | 1996-07-25 | Henkel Kgaa | Aerobically curable adhesive |
| JP3534598B2 (en) * | 1997-12-18 | 2004-06-07 | 電気化学工業株式会社 | Adhesive composition, cured body, composite and bonding method |
| DE19810268A1 (en) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymer dispersions or polymer solutions containing stabilizers and polymer preparations obtainable therefrom |
| JP2000104041A (en) * | 1998-09-28 | 2000-04-11 | Daicel Chem Ind Ltd | Heat-sensitive adhesive, heat-sensitive adhesive sheet, and method for producing heat-sensitive adhesive sheet |
| EP1239015A1 (en) * | 2001-03-08 | 2002-09-11 | Sika AG, vorm. Kaspar Winkler & Co. | Easy to manufacture meth (acrylic) adhesive compositions |
| DE602005017472D1 (en) * | 2004-03-09 | 2009-12-17 | Henkel Corp | HEAT-CONDUCTIVE TWO-COMPONENT ADHESIVE COMPOSITION |
| US7776963B2 (en) * | 2005-05-03 | 2010-08-17 | Illinois Tool Works Inc. | Acrylic adhesives for metal bonding applications |
| FR2887552B1 (en) * | 2005-06-24 | 2007-10-12 | Rhodia Chimie Sa | USE OF AN ORGANOPOLYSILOXANIC COMPOSITION VULCANIZABLE FROM AMBIENT TEMPERATURE TO FORM AN ADHERENT AUTO ELASTOMER |
| US20070078207A1 (en) * | 2005-09-30 | 2007-04-05 | Jonn Jerry Y | Stabilizer cyanoacrylate formulations |
| JP5235271B2 (en) * | 2005-12-22 | 2013-07-10 | 日東電工株式会社 | Water-dispersible acrylic pressure-sensitive adhesive composition for re-peeling and pressure-sensitive adhesive sheet |
| US8609881B2 (en) * | 2008-05-07 | 2013-12-17 | Henkel IP US LCC | Cure accelerators for anaerobic curable compositions |
| JP5550818B2 (en) * | 2008-05-09 | 2014-07-16 | 電気化学工業株式会社 | Adhesive for optical components |
| US20090288771A1 (en) | 2008-05-23 | 2009-11-26 | Loctite (R&D) Limited | Surface-promoted cure of one-part radically curable compositions |
| CN101368330B (en) * | 2008-09-25 | 2010-12-15 | 湖南多喜爱纺织科技有限公司 | Preparation method for polymer reduction nanometer silver antibiotic finishing agent and uses thereof |
-
2010
- 2010-08-05 GB GB1013201.7A patent/GB2482531B/en not_active Expired - Fee Related
-
2011
- 2011-08-04 WO PCT/EP2011/063491 patent/WO2012017057A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012017057A1 (en) | 2012-02-09 |
| GB2482531A (en) | 2012-02-08 |
| GB2482531B (en) | 2013-11-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20150805 |