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GB2002398A - alpha -METHYL STYRENE- NITRILE-DIENE RUBBER GRAFT POLYMERISATION - Google Patents

alpha -METHYL STYRENE- NITRILE-DIENE RUBBER GRAFT POLYMERISATION

Info

Publication number
GB2002398A
GB2002398A GB7832269A GB7832269A GB2002398A GB 2002398 A GB2002398 A GB 2002398A GB 7832269 A GB7832269 A GB 7832269A GB 7832269 A GB7832269 A GB 7832269A GB 2002398 A GB2002398 A GB 2002398A
Authority
GB
United Kingdom
Prior art keywords
alpha
diene rubber
nitrile
styrene
methyl styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7832269A
Other versions
GB2002398B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uniroyal Inc
Original Assignee
Uniroyal Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniroyal Inc filed Critical Uniroyal Inc
Publication of GB2002398A publication Critical patent/GB2002398A/en
Application granted granted Critical
Publication of GB2002398B publication Critical patent/GB2002398B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Alpha-methylstyrene and a copolymerisable nitrile monomer, such as acrylonitrile, are grafted onto a spine of a diene rubber (containing at least 30% small particle size rubber) such as polybutadiene or poly- (butadiene-styrene) (up to 50%, of the alpha-methylstyrene may be replaced by styrene) in aqueous phase using an anionic emulsifier and a water-soluble free-radical polymerization initiator, such as a persulfate. The resultant graft polymer possesses good heat distortion temperature and a good balance between tensile strength, impact strength, and flow.
GB7832269A 1977-08-15 1978-08-04 Graft polymer Expired GB2002398B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US82446777A 1977-08-15 1977-08-15

Publications (2)

Publication Number Publication Date
GB2002398A true GB2002398A (en) 1979-02-21
GB2002398B GB2002398B (en) 1982-03-10

Family

ID=25241477

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7832269A Expired GB2002398B (en) 1977-08-15 1978-08-04 Graft polymer

Country Status (4)

Country Link
JP (1) JPS5452194A (en)
DE (1) DE2835291C2 (en)
FR (1) FR2400529A1 (en)
GB (1) GB2002398B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2908661A (en) * 1957-01-11 1959-10-13 Borg Warner Polymerization of acrylonitrile-alpha methyl styrene mixtures onto polybutadiene and products produced thereby
DE1252902B (en) * 1963-07-30 1967-10-26 Bayer Ag Process for the production of graft polymers

Also Published As

Publication number Publication date
DE2835291A1 (en) 1979-02-22
GB2002398B (en) 1982-03-10
FR2400529A1 (en) 1979-03-16
JPS5452194A (en) 1979-04-24
JPS5523854B2 (en) 1980-06-25
DE2835291C2 (en) 1982-06-09

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Legal Events

Date Code Title Description
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee