GB1530649A - Process for the production of sulphonated polymers - Google Patents
Process for the production of sulphonated polymersInfo
- Publication number
- GB1530649A GB1530649A GB44291/76A GB4429176A GB1530649A GB 1530649 A GB1530649 A GB 1530649A GB 44291/76 A GB44291/76 A GB 44291/76A GB 4429176 A GB4429176 A GB 4429176A GB 1530649 A GB1530649 A GB 1530649A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycidyl
- oct
- copolymer
- formula
- ethylenically unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- -1 glycidyl ester Chemical class 0.000 abstract 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 abstract 1
- SHFJWMWCIHQNCP-UHFFFAOYSA-M hydron;tetrabutylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC SHFJWMWCIHQNCP-UHFFFAOYSA-M 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 abstract 1
- 235000010265 sodium sulphite Nutrition 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1530649 Sulphonation of polymers containing epoxy groups S PAUL and B RANBY 25 Oct 1976 [27 Oct 1975] 44291/76 Heading C3P A polymer which contains units of the formula where R 1 , R 2 and R 3 are H or inert organic groups, R is H or alkyl, M is H or a monovalent cation derived from an inorganic sulphite and P is a unit derived from an ethylenically unsaturated monomer, is prepared by copolymerizing one or more ethylenically unsaturated monomers with a glycidyl ester of an acid of the formula R 1 R 2 C = CR 3 COOH and sulphonating the product in aqueous medium using a water-soluble inorganic sulphite salt. In the examples a copolymer of methyl methacrylate and glycidyl methacyrlate and a copolymer of styrene and glycidyl acrylate are sulphonated using sodium sulphite in the presence of tetrabutyl ammonium bromide or bisulphate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7512003A SE7512003L (en) | 1975-10-27 | 1975-10-27 | POLYMERS WITH REGULATED CONTENT OF SULFONIC ACID OR SULPHONATE GROUPS AND PROCEDURES FOR THE PREPARATION OF THE SAME |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1530649A true GB1530649A (en) | 1978-11-01 |
Family
ID=20325909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB44291/76A Expired GB1530649A (en) | 1975-10-27 | 1976-10-25 | Process for the production of sulphonated polymers |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE847668A (en) |
| CA (1) | CA1107443A (en) |
| DE (1) | DE2648166A1 (en) |
| FR (1) | FR2329680A1 (en) |
| GB (1) | GB1530649A (en) |
| IT (1) | IT1068853B (en) |
| NL (1) | NL7611811A (en) |
| SE (1) | SE7512003L (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514547A (en) * | 1982-07-06 | 1985-04-30 | Shell Oil Company | 2-Hydroxypropane sulphonic acid derivatives: their preparation and curable compositions thereof |
| GB2254332A (en) * | 1991-03-18 | 1992-10-07 | Etsuko Sugo | Deodorizing material for animal breeding and process for producing the same. |
| EP1391473A1 (en) * | 2002-07-29 | 2004-02-25 | Eastman Kodak Company | Water-soluble or water-dispersible polyepoxy compounds containing sulfonate or thiosulfate moieties |
| US20220177620A1 (en) * | 2020-04-17 | 2022-06-09 | Fine-Blend Polymer (Shanghai) Co., Ltd. | Solvent-free adhesion-promoting chain extender, preparation method therefor, and application thereof |
-
1975
- 1975-10-27 SE SE7512003A patent/SE7512003L/en unknown
-
1976
- 1976-10-22 CA CA264,141A patent/CA1107443A/en not_active Expired
- 1976-10-25 DE DE19762648166 patent/DE2648166A1/en active Pending
- 1976-10-25 NL NL7611811A patent/NL7611811A/en not_active Application Discontinuation
- 1976-10-25 GB GB44291/76A patent/GB1530649A/en not_active Expired
- 1976-10-26 IT IT28717/76A patent/IT1068853B/en active
- 1976-10-26 FR FR7632183A patent/FR2329680A1/en not_active Withdrawn
- 1976-10-27 BE BE171816A patent/BE847668A/en unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514547A (en) * | 1982-07-06 | 1985-04-30 | Shell Oil Company | 2-Hydroxypropane sulphonic acid derivatives: their preparation and curable compositions thereof |
| GB2254332A (en) * | 1991-03-18 | 1992-10-07 | Etsuko Sugo | Deodorizing material for animal breeding and process for producing the same. |
| GB2254332B (en) * | 1991-03-18 | 1995-06-21 | Etsuko Sugo | Deodorizing material for animal breeding and process for producing the same |
| US5641482A (en) * | 1991-03-18 | 1997-06-24 | Sugo; Tetsuko | Deodorizing material for animal breeding and process for producing the same |
| EP1391473A1 (en) * | 2002-07-29 | 2004-02-25 | Eastman Kodak Company | Water-soluble or water-dispersible polyepoxy compounds containing sulfonate or thiosulfate moieties |
| US6846938B2 (en) | 2002-07-29 | 2005-01-25 | Eastman Kodak Company | Water-compatible epoxy compounds containing sulfonate or thiosulfate moieties |
| US20220177620A1 (en) * | 2020-04-17 | 2022-06-09 | Fine-Blend Polymer (Shanghai) Co., Ltd. | Solvent-free adhesion-promoting chain extender, preparation method therefor, and application thereof |
| US12221501B2 (en) * | 2020-04-17 | 2025-02-11 | Fine-Blend Polymer (Shanghai) Co., Ltd. | Solvent-free adhesion-promoting chain extender, preparation method therefor, and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1107443A (en) | 1981-08-18 |
| DE2648166A1 (en) | 1977-09-15 |
| BE847668A (en) | 1977-02-14 |
| SE7512003L (en) | 1977-04-28 |
| NL7611811A (en) | 1977-04-29 |
| FR2329680A1 (en) | 1977-05-27 |
| IT1068853B (en) | 1985-03-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |