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GB1429004A - Phosphonate esters useful as fire retardant additives - Google Patents

Phosphonate esters useful as fire retardant additives

Info

Publication number
GB1429004A
GB1429004A GB1390973A GB1390973A GB1429004A GB 1429004 A GB1429004 A GB 1429004A GB 1390973 A GB1390973 A GB 1390973A GB 1390973 A GB1390973 A GB 1390973A GB 1429004 A GB1429004 A GB 1429004A
Authority
GB
United Kingdom
Prior art keywords
alkyl
fire retardant
retardant additives
phosphonate esters
hydroxyalkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1390973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Occidental Chemical Corp
Original Assignee
Hooker Chemicals and Plastics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hooker Chemicals and Plastics Corp filed Critical Hooker Chemicals and Plastics Corp
Publication of GB1429004A publication Critical patent/GB1429004A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
    • C07F9/6521—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C08K5/5353—Esters of phosphonic acids containing also nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C08K5/5373—Esters of phosphonic acids containing heterocyclic rings not representing cyclic esters of phosphonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2965—Cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fireproofing Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1429004 Flame-retardant phosphonate diesters HOOKER CHEMICALS & PLASTICS CORP 22 March 1973 [30 March 1972 (2)] 13909/73 Heading C2P [Also in Divisions C3 and D1] The invention comprises phosphonate ester derivatives of the formula Z-CH 2 P(O)(OE) 2 wherein Z is XHNC(O)NX<SP>1</SP>-, X 2 NC(O)NH-, or (EO) 2 P(O)CH 2 NHC(O)NX-, wherein X is H, C 1 -C 6 hydroxyalkyl or C 1 -C 6 alkyl and each X may be the same or different, X<SP>1</SP> is C 1 -C 6 hydroxyalkyl or C 1 -C 6 alkyl or X and X<SP>1</SP> together are C 2 -C 6 alkylene or C 2 -C 6 alkyleneoxyalkylene and E is C 1 -C 6 alkyl. They may be obtained by reacting a compound: ZCH 2 OH with a trialkyl phosphite: P(OE) 3 and the reaction can be carried out neat, in a solvent or in excess phosphite. The products may be reacted with formaldehyde to form their N- hydroxymethyl derivatives and are useful as flame retardants for textiles, thermoplastic resins and thermosetting resins.
GB1390973A 1972-03-30 1973-03-22 Phosphonate esters useful as fire retardant additives Expired GB1429004A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US23979772A 1972-03-30 1972-03-30
US23980072A 1972-03-30 1972-03-30
US401767A US3885912A (en) 1972-03-30 1973-09-28 Method of rendering textiles flame retardant with phosphorus containing melamine

Publications (1)

Publication Number Publication Date
GB1429004A true GB1429004A (en) 1976-03-24

Family

ID=27399278

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1390973A Expired GB1429004A (en) 1972-03-30 1973-03-22 Phosphonate esters useful as fire retardant additives

Country Status (8)

Country Link
US (1) US3885912A (en)
JP (1) JPS4915291A (en)
BE (1) BE797473A (en)
CA (1) CA1019756A (en)
DE (1) DE2315212A1 (en)
FR (1) FR2178055A1 (en)
GB (1) GB1429004A (en)
NL (1) NL7304498A (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020224A (en) * 1974-07-22 1977-04-26 Monsanto Research Corporation Flame retardant method
GB1547105A (en) * 1976-07-05 1979-06-06 Sanko Kaihatsu Kagaku Kenk Cyclic phosphinates and their use as flame-retardants
US4113795A (en) * 1977-07-05 1978-09-12 Asahi-Dow Limited Flame-retardant polyphenylene ether resin composition
US4299782A (en) * 1980-03-24 1981-11-10 Pennwalt Corporation Phosphorus derivatives of 1,3-diethanolurea
US4461862A (en) * 1980-06-02 1984-07-24 Ludwig Eigenmann Self extinguishing polymeric compositions, which upon contacting a flame provide a nondropping char-forming incandescent crust, and which do not produce flame neither toxic fumes
GB8321643D0 (en) * 1983-08-11 1983-09-14 Ici Plc Fire retardant polyamide compositions
DE3933546A1 (en) * 1989-10-07 1991-04-11 Bayer Ag NEW AMINOMETHANPHOSPHONIC ACID ALTERES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE3933549A1 (en) * 1989-10-07 1991-04-11 Bayer Ag NEW AMINOMETHANPHOSPHONIC ACID ALTERES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE4303648A1 (en) * 1993-02-09 1994-08-11 Basf Ag Use of aminovinylphosphonic acid esters as light stabilizers and stabilizers for organic material
IT1314768B1 (en) * 1996-12-19 2003-01-16 Montell North America Inc PROCESS FOR THE PRODUCTION OF FLAME RESISTANT ADDITIVES FOR POLYMER COMPOSITIONS, AND PRODUCTS OBTAINED FROM THE PROCESS
CA2507209C (en) * 2002-11-29 2011-08-30 Neworld Fibers, Llc Methods, systems and compositions for fire retarding substrates
US20060053739A1 (en) * 2004-09-10 2006-03-16 Jaffee Alan M Methods of providing water protection to floor structures and floor structures formed by the same

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2781281A (en) * 1955-05-23 1957-02-12 Ciba Ltd Flame-proofing of textiles
GB1299373A (en) * 1969-05-09 1972-12-13 Courtaulds Ltd Flame-retardant filaments

Also Published As

Publication number Publication date
NL7304498A (en) 1973-10-02
US3885912A (en) 1975-05-27
FR2178055A1 (en) 1973-11-09
JPS4915291A (en) 1974-02-09
CA1019756A (en) 1977-10-25
BE797473A (en) 1973-09-28
DE2315212A1 (en) 1973-10-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee