GB1418775A - Phosphonate ester derivatives having flame-retardant properties - Google Patents
Phosphonate ester derivatives having flame-retardant propertiesInfo
- Publication number
- GB1418775A GB1418775A GB1390773A GB1390773A GB1418775A GB 1418775 A GB1418775 A GB 1418775A GB 1390773 A GB1390773 A GB 1390773A GB 1390773 A GB1390773 A GB 1390773A GB 1418775 A GB1418775 A GB 1418775A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- flame
- phenyl
- phosphonate ester
- ester derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Phosphonate ester Chemical class 0.000 title abstract 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title 1
- 239000003063 flame retardant Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- 125000005530 alkylenedioxy group Chemical group 0.000 abstract 1
- 239000012757 flame retardant agent Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000005059 halophenyl group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
- C08K5/5353—Esters of phosphonic acids containing also nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
- C08K5/5373—Esters of phosphonic acids containing heterocyclic rings not representing cyclic esters of phosphonic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fireproofing Substances (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
1418775 Phosphonate ester derivatives HOOKER CHEMICALS & PLASTICS CORP 22 March 1973 [30 March 1972 (2)] 13907/73 Heading C2C [Also in Divisions C3 and D1] The invention comprises compounds of the general formula ZCH 2 P(O)(OR) 2 wherein R is C 1 -C 6 alkyl C 1 -C 6 haloalkyl, C 2 -C 6 alkenyl, phenyl, or phenyl substituted by halogen, C 1 -C 6 alkyl or C 1 -C 6 haloalkyl, and Z is ASO 2 NH- or (W) m P(O)NH- wherein A is C 1 -C 6 alkyl, phenyl, halophenyl or alkylphenyl, m is 1 or 2, and when in is 2 W is C 1 -C 8 alkoxy and when m is 1 W is C 2 -C 8 alkylene dioxy. They may be obtained by reacting a compound: ASO 2 NHCH 2 OH or with a phosphite triester (RO) 3 P, optionally in the presence of a solvent. The products may be reacted with formaldehyde to give the N- hydroxymethyl derivatives and the main products as well as their N-hydroxymethyl derivatives are useful as flame-retardant agents for a wide range of textile materials and for elastomeric, thermoplastic and thermosetting resins.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US239757A US3870771A (en) | 1972-03-30 | 1972-03-30 | Dialkyl alkyl and aromatic sulfonamidomethyl phosphonates |
| US00239799A US3812218A (en) | 1972-03-30 | 1972-03-30 | Diakyl alkyl and cyclic phosporamidomethyl phosphonates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1418775A true GB1418775A (en) | 1975-12-24 |
Family
ID=26932840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1390773A Expired GB1418775A (en) | 1972-03-30 | 1973-03-22 | Phosphonate ester derivatives having flame-retardant properties |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US3812218A (en) |
| JP (1) | JPS4916735A (en) |
| BE (1) | BE797476A (en) |
| CA (1) | CA1004227A (en) |
| DE (1) | DE2315493A1 (en) |
| FR (2) | FR2187802B1 (en) |
| GB (1) | GB1418775A (en) |
| IT (1) | IT982664B (en) |
| NL (1) | NL7304503A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3959551A (en) * | 1972-03-30 | 1976-05-25 | Hooker Chemicals & Plastics Corporation | Dialkyl alkyl and aromatic sulfonamidomethyl phosphonates |
| US4032601A (en) * | 1973-08-06 | 1977-06-28 | Monsanto Company | Process for the production of sulfonamide phosphonates |
| US4031170A (en) * | 1973-08-06 | 1977-06-21 | Monsanto Company | Phosphorus compounds |
| DE2424243A1 (en) * | 1974-05-18 | 1975-11-27 | Bayer Ag | PERFLUORALKANE SULFONAMIDOALKANE PHOSPHONIC ACID OR - PHOSPHIC ACID DERIVATIVES |
| DE2555452A1 (en) * | 1974-12-18 | 1976-06-24 | Ciba Geigy Ag | FLAME RETARDANT FOR PLASTICS |
| US4202706A (en) * | 1979-03-12 | 1980-05-13 | Minnesota Mining And Manufacturing Company | Corrosion resistance treatment of aluminum with N-alkyl-fluoroaliphaticsulfonamidophosphonic acids and salts thereof |
| JPS5610500A (en) * | 1979-07-09 | 1981-02-02 | Hiroyasu Hanawa | Automatic punchinggmachine |
| US6221939B1 (en) | 1998-08-31 | 2001-04-24 | General Electric Company | Flame retardant resin compositions containing phosphoramides, and method for making |
| US6433046B1 (en) | 1999-01-22 | 2002-08-13 | General Electric Company | Flame retardant resin compositions containing phosphoramides, and method of making |
| US6569929B2 (en) | 1999-01-22 | 2003-05-27 | General Electric Company | Method to prepare phosphoramides, and resin compositions containing them |
| EP1194436B1 (en) | 1999-07-06 | 2005-11-30 | Methylgene, Inc. | Sulfonamidomethyl phosphonate inhibitors of beta-lactamase |
| US6921756B2 (en) * | 1999-07-06 | 2005-07-26 | Methylgene, Inc. | Inhibitors of β-lactamase |
| US6884791B2 (en) * | 1999-07-06 | 2005-04-26 | Methylgene, Inc. | Inhibitors of β-lactamase |
| US20050054553A1 (en) * | 2003-06-27 | 2005-03-10 | The Procter & Gamble Company | Liquid fabric softening compositions comprising flame retardant |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2635112A (en) * | 1949-07-28 | 1953-04-14 | Research Corp | Process for producing aminomethylphosphonic acid compounds |
-
1972
- 1972-03-30 US US00239799A patent/US3812218A/en not_active Expired - Lifetime
- 1972-03-30 US US239757A patent/US3870771A/en not_active Expired - Lifetime
-
1973
- 1973-03-22 GB GB1390773A patent/GB1418775A/en not_active Expired
- 1973-03-27 FR FR7310953A patent/FR2187802B1/fr not_active Expired
- 1973-03-28 CA CA167,352A patent/CA1004227A/en not_active Expired
- 1973-03-28 BE BE129396A patent/BE797476A/en unknown
- 1973-03-28 DE DE2315493A patent/DE2315493A1/en active Pending
- 1973-03-30 NL NL7304503A patent/NL7304503A/xx unknown
- 1973-03-30 IT IT22420/73A patent/IT982664B/en active
- 1973-03-30 JP JP48036575A patent/JPS4916735A/ja active Pending
- 1973-09-18 FR FR7333434A patent/FR2196341B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2315493A1 (en) | 1973-10-04 |
| IT982664B (en) | 1974-10-21 |
| FR2187802B1 (en) | 1976-06-11 |
| FR2196341B1 (en) | 1977-03-11 |
| CA1004227A (en) | 1977-01-25 |
| NL7304503A (en) | 1973-10-02 |
| US3870771A (en) | 1975-03-11 |
| FR2196341A1 (en) | 1974-03-15 |
| FR2187802A1 (en) | 1974-01-18 |
| JPS4916735A (en) | 1974-02-14 |
| US3812218A (en) | 1974-05-21 |
| BE797476A (en) | 1973-09-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |