GB1422185A - Polyvinyl alcohol microgels and dry blends for preparing them - Google Patents
Polyvinyl alcohol microgels and dry blends for preparing themInfo
- Publication number
- GB1422185A GB1422185A GB2631473A GB2631473A GB1422185A GB 1422185 A GB1422185 A GB 1422185A GB 2631473 A GB2631473 A GB 2631473A GB 2631473 A GB2631473 A GB 2631473A GB 1422185 A GB1422185 A GB 1422185A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- vinyl alcohol
- per cent
- acid
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 229920002451 polyvinyl alcohol Polymers 0.000 title abstract 5
- 239000004372 Polyvinyl alcohol Substances 0.000 title abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000000499 gel Substances 0.000 abstract 2
- 239000004310 lactic acid Substances 0.000 abstract 2
- 235000014655 lactic acid Nutrition 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- MSYNCHLYGJCFFY-UHFFFAOYSA-B 2-hydroxypropane-1,2,3-tricarboxylate;titanium(4+) Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O MSYNCHLYGJCFFY-UHFFFAOYSA-B 0.000 abstract 1
- AIFLGMNWQFPTAJ-UHFFFAOYSA-J 2-hydroxypropanoate;titanium(4+) Chemical compound [Ti+4].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O AIFLGMNWQFPTAJ-UHFFFAOYSA-J 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 150000001261 hydroxy acids Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000010952 in-situ formation Methods 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 abstract 1
- 150000003608 titanium Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- -1 titanium ions Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
- B01J13/0065—Preparation of gels containing an organic phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
Abstract
1422185 Gel-forming polyvinyl alcohol compositions E I DU PONT DE NEMOURS & CO 1 June 1973 [5 June 1972] 26314/73 Heading C3P A dry blend, which when mixed with water, forms a cross-linked gel, comprises (A) a hydroxyl polymer which is (i) a vinyl alcohol polymer containing at least 50 mole per cent of vinyl alcohol units and having a Hoeppler viscosity of 4-150 c.p. or (ii) a mixture of at least 0À5 wt. per cent of a polymer as defined in (i) with one or both of up to 99À5 wt. per cent of a starch and up to 33 wt. per cent of sodium carboxymethyl cellulose; (B) a water-soluble solid titanium salt of a C 2-10 hydroxycarboxylic acid, present inan amount which provides 0À05- 10 parts by wt. of tetravalent titanium ions per 100 parts by wt. of (A); and (C) a water-soluble solid C 2-10 hydroxy carboxylic acid present in an amount of from 0À05-20 parts by wt. per 100 parts by wt. of (A). In aqueous solution the Ti ions cross-link the vinyl alcohol polymer, the efficiency of said cross-linking being enhanced by the presence of component (C). In the examples various polyvinyl alcohols, including a vinyl alcohol methylmethacrylate copolymer are compounded with titanium citrate and citric acid, or tetraisopropyl titanate and lactic acid. The latter mixture results in the in situ formation of a mixture of lactic acid and titanium lactate. Other hydroxy acids for use in forming the salt (B) or for use as component (C) are tartaric acidand salicylic acid. The resulting gels are used for size-coating paper.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25966572A | 1972-06-05 | 1972-06-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1422185A true GB1422185A (en) | 1976-01-21 |
Family
ID=22985864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2631473A Expired GB1422185A (en) | 1972-06-05 | 1973-06-01 | Polyvinyl alcohol microgels and dry blends for preparing them |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5742656B2 (en) |
| CA (1) | CA997082A (en) |
| DE (1) | DE2328525A1 (en) |
| FR (1) | FR2187822B1 (en) |
| GB (1) | GB1422185A (en) |
| SE (1) | SE378830B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1080940A3 (en) * | 1999-08-30 | 2002-04-03 | Kuraray Co., Ltd. | Water resistant composition, coating agent, and recording material |
| WO2004108832A3 (en) * | 2003-06-06 | 2005-03-03 | Procter & Gamble | Crosslinking systems for hydroxyl polymers |
| CN100540609C (en) * | 2003-06-06 | 2009-09-16 | 宝洁公司 | Crosslinking system for hydroxyl polymers |
| US7744791B2 (en) | 2004-04-29 | 2010-06-29 | The Procter & Gamble Company | Method for making polymeric structures |
| US7754119B2 (en) | 2004-04-29 | 2010-07-13 | The Procter & Gamble Company | Method for making polymeric structures |
| EP2309059A1 (en) * | 2009-10-02 | 2011-04-13 | Organoclick Aktiebolag | Method of improving properties of cellulose-based fibrous sheet-formed materials |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5823616B2 (en) * | 1976-11-08 | 1983-05-16 | 東レ株式会社 | photosensitive polymer composition |
| JPS626996A (en) * | 1985-06-29 | 1987-01-13 | 神崎製紙株式会社 | Production of paper |
| JPH01119544U (en) * | 1988-02-09 | 1989-08-14 |
-
1973
- 1973-05-30 SE SE7307700*A patent/SE378830B/xx unknown
- 1973-06-01 GB GB2631473A patent/GB1422185A/en not_active Expired
- 1973-06-01 JP JP48061001A patent/JPS5742656B2/ja not_active Expired
- 1973-06-04 CA CA173,106A patent/CA997082A/en not_active Expired
- 1973-06-04 FR FR7320178A patent/FR2187822B1/fr not_active Expired
- 1973-06-05 DE DE2328525A patent/DE2328525A1/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1080940A3 (en) * | 1999-08-30 | 2002-04-03 | Kuraray Co., Ltd. | Water resistant composition, coating agent, and recording material |
| US7947766B2 (en) | 2003-06-06 | 2011-05-24 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US8617303B2 (en) | 2003-06-06 | 2013-12-31 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| CN100540609C (en) * | 2003-06-06 | 2009-09-16 | 宝洁公司 | Crosslinking system for hydroxyl polymers |
| AU2004245565C1 (en) * | 2003-06-06 | 2009-09-24 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US9340657B2 (en) | 2003-06-06 | 2016-05-17 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US8815003B2 (en) | 2003-06-06 | 2014-08-26 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US8357237B2 (en) | 2003-06-06 | 2013-01-22 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| WO2004108832A3 (en) * | 2003-06-06 | 2005-03-03 | Procter & Gamble | Crosslinking systems for hydroxyl polymers |
| AU2004245565B2 (en) * | 2003-06-06 | 2007-07-05 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US8088843B2 (en) | 2003-06-06 | 2012-01-03 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US7960453B2 (en) | 2003-06-06 | 2011-06-14 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
| US8129449B2 (en) | 2003-06-06 | 2012-03-06 | The Procter & Gabmle Company | Crosslinking systems for hydroxyl polymers |
| US8623246B2 (en) | 2004-04-29 | 2014-01-07 | The Procter & Gamble Company | Process of making a fibrous structure |
| US7754119B2 (en) | 2004-04-29 | 2010-07-13 | The Procter & Gamble Company | Method for making polymeric structures |
| US9017586B2 (en) | 2004-04-29 | 2015-04-28 | The Procter & Gamble Company | Polymeric structures and method for making same |
| US7744791B2 (en) | 2004-04-29 | 2010-06-29 | The Procter & Gamble Company | Method for making polymeric structures |
| EP2309059A1 (en) * | 2009-10-02 | 2011-04-13 | Organoclick Aktiebolag | Method of improving properties of cellulose-based fibrous sheet-formed materials |
| WO2011039325A3 (en) * | 2009-10-02 | 2011-05-26 | Organoclick Aktiebolag | Method of improving properties of cellulose-based fibrous sheet-formed materials |
Also Published As
| Publication number | Publication date |
|---|---|
| CA997082A (en) | 1976-09-14 |
| JPS4942757A (en) | 1974-04-22 |
| JPS5742656B2 (en) | 1982-09-09 |
| FR2187822B1 (en) | 1980-04-30 |
| DE2328525A1 (en) | 1974-02-21 |
| SE378830B (en) | 1975-09-15 |
| FR2187822A1 (en) | 1974-01-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed |