GB1409258A - Biconstituent polymer compositions and textile articles formed therefrom - Google Patents
Biconstituent polymer compositions and textile articles formed therefromInfo
- Publication number
- GB1409258A GB1409258A GB5279572A GB5279572A GB1409258A GB 1409258 A GB1409258 A GB 1409258A GB 5279572 A GB5279572 A GB 5279572A GB 5279572 A GB5279572 A GB 5279572A GB 1409258 A GB1409258 A GB 1409258A
- Authority
- GB
- United Kingdom
- Prior art keywords
- units
- acrylonitrile
- fibres
- polyamide
- filaments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000004753 textile Substances 0.000 title 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 2
- 229920002647 polyamide Polymers 0.000 abstract 2
- 238000009987 spinning Methods 0.000 abstract 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical group C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- YCGKJPVUGMBDDS-UHFFFAOYSA-N 3-(6-azabicyclo[3.1.1]hepta-1(7),2,4-triene-6-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2C=3C=C2C=CC=3)=C1 YCGKJPVUGMBDDS-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004760 aramid Substances 0.000 abstract 1
- 229920003235 aromatic polyamide Polymers 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000009998 heat setting Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical group OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1409258 Acrylonitrile / polyamide fibres WOON WAI TSE 15 Nov 1972 52795/72 Heading B5B [Also in Division C3] Filaments or fibres are spun from a solution of a polymer composition which comprises an acrylonitrile polymer or copolymer containing at least 70% by weight of acrylonitrile units in admixture with an aromatic polyamide containing recurring units of the formula where Ar 1 and Ar 2 are the same or different, substituted or unsubstituted, divalent aromatic radicals. The acrylonitrile polymer may contain comonomer units such as units of vinyl acetate, methylacrylate, vinylpyridine and ethylenesulphonic acid. The polyamide preferably consists entirely of the units of the above formula and may be, for example, poly-m-phenylene isophthalamide. The solvent for the spinning solution may be, for example, dimethylformamide and a solubility promoter such as lithium chloride may optionally also be present. After spinning, the filaments or fibres are suitably submitted to washing, drawing and heat setting processes. Drawing is preferably effected to at least 2 times the original length in a steam, hot water or other hot atmosphere, or in contact with a heated surface.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5279572A GB1409258A (en) | 1972-11-15 | 1972-11-15 | Biconstituent polymer compositions and textile articles formed therefrom |
| JP12584473A JPS5042A (en) | 1972-11-15 | 1973-11-08 | |
| DE19732356329 DE2356329A1 (en) | 1972-11-15 | 1973-11-10 | SYNTHETIC HIGH POLYMERS FOR THE MANUFACTURE OF TEXTILE MATERIAL |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5279572A GB1409258A (en) | 1972-11-15 | 1972-11-15 | Biconstituent polymer compositions and textile articles formed therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1409258A true GB1409258A (en) | 1975-10-08 |
Family
ID=10465349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5279572A Expired GB1409258A (en) | 1972-11-15 | 1972-11-15 | Biconstituent polymer compositions and textile articles formed therefrom |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5042A (en) |
| DE (1) | DE2356329A1 (en) |
| GB (1) | GB1409258A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265970A (en) * | 1980-06-06 | 1981-05-05 | Monsanto Company | Acrylic fiber having improved dyeability |
| WO2018044532A1 (en) * | 2016-09-01 | 2018-03-08 | E. I. Du Pont De Nemours And Company | Carbon-containing modacrylic & aramid bicomponent filament yarns |
| US10954609B2 (en) * | 2015-07-29 | 2021-03-23 | Dupont Safety & Construction, Inc. | Yarn from polymers having different decomposition temperatures and process for forming same |
| US10982353B2 (en) | 2016-09-01 | 2021-04-20 | Dupont Safety & Construction, Inc. | Carbon-containing aramid bicomponent filament yarns |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS532622A (en) * | 1976-06-24 | 1978-01-11 | Asahi Chem Ind Co Ltd | Fiber from polymer blend and its preparation |
| JPS61113105U (en) * | 1984-12-28 | 1986-07-17 |
-
1972
- 1972-11-15 GB GB5279572A patent/GB1409258A/en not_active Expired
-
1973
- 1973-11-08 JP JP12584473A patent/JPS5042A/ja active Pending
- 1973-11-10 DE DE19732356329 patent/DE2356329A1/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265970A (en) * | 1980-06-06 | 1981-05-05 | Monsanto Company | Acrylic fiber having improved dyeability |
| US10954609B2 (en) * | 2015-07-29 | 2021-03-23 | Dupont Safety & Construction, Inc. | Yarn from polymers having different decomposition temperatures and process for forming same |
| WO2018044532A1 (en) * | 2016-09-01 | 2018-03-08 | E. I. Du Pont De Nemours And Company | Carbon-containing modacrylic & aramid bicomponent filament yarns |
| US10590567B2 (en) | 2016-09-01 | 2020-03-17 | Dupont Safety & Construction, Inc. | Carbon-containing modacrylic and aramid bicomponent filament yarns |
| US10982353B2 (en) | 2016-09-01 | 2021-04-20 | Dupont Safety & Construction, Inc. | Carbon-containing aramid bicomponent filament yarns |
| US11339508B2 (en) | 2016-09-01 | 2022-05-24 | Dupont Safety & Construction, Inc. | Process for forming a yarn comprising bicomponent filaments |
| US12018407B2 (en) | 2016-09-01 | 2024-06-25 | Dupont Safety & Construction, Inc. | Processes for forming carbon-containing aramid bicomponent filament yarns |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5042A (en) | 1975-01-06 |
| DE2356329A1 (en) | 1974-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |