GB1499570A - Production of white mineral oil - Google Patents
Production of white mineral oilInfo
- Publication number
- GB1499570A GB1499570A GB1463175A GB1463175A GB1499570A GB 1499570 A GB1499570 A GB 1499570A GB 1463175 A GB1463175 A GB 1463175A GB 1463175 A GB1463175 A GB 1463175A GB 1499570 A GB1499570 A GB 1499570A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- catalyst
- mineral oil
- weight
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002480 mineral oil Substances 0.000 title abstract 6
- 235000010446 mineral oil Nutrition 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 abstract 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 6
- 239000001257 hydrogen Substances 0.000 abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000003921 oil Substances 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229910052763 palladium Inorganic materials 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 239000010937 tungsten Substances 0.000 abstract 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- VNTLIPZTSJSULJ-UHFFFAOYSA-N chromium molybdenum Chemical compound [Cr].[Mo] VNTLIPZTSJSULJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 abstract 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 150000004682 monohydrates Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 150000004684 trihydrates Chemical class 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/14—White oil, eating oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1499570 Producing white mineral oil ATLANTIC RICHFIELD CO 9 April 1975 [11 April 1974] 14631/75 Heading C5E White mineral oil is produced from a mineral oil distillate of lubricating viscosity by first contacting the distillate with hydrogen in the presence of a sulphur-resistant catalyst to form a hydrogenated oil and then contacting at least a portion of the hydrogenated oil with hydrogen in the presence of a second catalyst to form a refined oil from which the white mineral oil is recovered, the second catalyst comprising a major amount of a support, a minor catalytically-effective amount of at least one palladium component and a minor amount of at least one halogen component sufficient to improve the hydrogenation activity of the second catalyst. The first contacting step may be effected at a temperature of 600‹-800‹ F., a pressure of 1500-5000 p.s.i.g., a weight hourly space velocity of 0À1-1À0 and a hydrogen to mineral oil distillate ratio of 1000-5000 s.c.f./b. and the second contacting step may be effected at a temperature of 400‹-650‹ F., a pressure of 1500-5000 p.s.i.g., a weight hourly space velocity of 0À1-1À0 and a hydrogen to hydrogenated oil ratio of 500-5000 s.c.f./b. The first catalyst may comprise a major amount of a support and a minor amount of a metallic component, e.g. tin, vanadium, chromium, molybdenum, tungsten, iron, cobalt or nickel present as free metals, oxides or sulphides, and preferably comprises 5-40% by weight of a Group VIB metal, chromium molybdenum or tungsten calculated as metal oxide and 2-15% by weight of a Group VIII metal, iron, cobalt or nickel, calculated as free metal. The support for the first and second catalysts may be calcined or otherwise activated alumina derived from hydrous alumina comprising alumina trihydrate, alumina monohydrate, amorphous hydrous alumina and mixtures thereof. The palladium component of the second catalyst may be present as the metal or sulphide or oxide, preferably in an amount of 0À01-5% by weight. The halogen component, which may be fluorine, chlorine or bromine or mixtures thereof, may be added in an amount of 0À1-4% by weight and may be added to the alumina support during preparation of the support or before or after the addition of palladium. The halogen may be added as an aqueous solution or gaseous stream of hydrogen fluoride, hydrogen chloride or hydrogen bromide, or by the use of a mixture of chloropalladic acid and hydrogen chloride. The catalysts used in the first and second stages may be hydrogen purged and/or prereduced prior to use, by heating in the presence of hydrogen at 300‹-600‹ F.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45999474A | 1974-04-11 | 1974-04-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1499570A true GB1499570A (en) | 1978-02-01 |
Family
ID=23826986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1463175A Expired GB1499570A (en) | 1974-04-11 | 1975-04-09 | Production of white mineral oil |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS50143802A (en) |
| BE (1) | BE827839A (en) |
| BR (1) | BR7502202A (en) |
| CA (1) | CA1069452A (en) |
| DE (1) | DE2515880A1 (en) |
| FR (1) | FR2267360B3 (en) |
| GB (1) | GB1499570A (en) |
| IT (1) | IT1035252B (en) |
| NL (1) | NL7504276A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5158671A (en) * | 1987-12-18 | 1992-10-27 | Exxon Research And Engineering Company | Method for stabilizing hydroisomerates |
| WO1992020759A1 (en) * | 1991-05-10 | 1992-11-26 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst and its use |
| US6221328B1 (en) | 1996-10-28 | 2001-04-24 | Dsm N.V. | Process for preparing hydroxylammonium salts |
| US6274029B1 (en) | 1995-10-17 | 2001-08-14 | Exxon Research And Engineering Company | Synthetic diesel fuel and process for its production |
| US6309432B1 (en) | 1997-02-07 | 2001-10-30 | Exxon Research And Engineering Company | Synthetic jet fuel and process for its production |
| US6765025B2 (en) | 2002-01-17 | 2004-07-20 | Dalian Institute Of Chemical Physics, Chinese Academy Of Science | Process for direct synthesis of diesel distillates with high quality from synthesis gas through Fischer-Tropsch synthesis |
| US6822131B1 (en) | 1995-10-17 | 2004-11-23 | Exxonmobil Reasearch And Engineering Company | Synthetic diesel fuel and process for its production |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1597165A (en) * | 1977-03-30 | 1981-09-03 | Exxon France | White oils and method of making same |
| CA1328635C (en) * | 1987-12-18 | 1994-04-19 | Ian Alfred Cody | Method for stabilizing hydroisomerates |
-
1975
- 1975-04-04 CA CA223,891A patent/CA1069452A/en not_active Expired
- 1975-04-09 FR FR7511055A patent/FR2267360B3/fr not_active Expired
- 1975-04-09 GB GB1463175A patent/GB1499570A/en not_active Expired
- 1975-04-10 BR BR7502202A patent/BR7502202A/en unknown
- 1975-04-10 NL NL7504276A patent/NL7504276A/en unknown
- 1975-04-10 IT IT4902475A patent/IT1035252B/en active
- 1975-04-11 DE DE19752515880 patent/DE2515880A1/en active Pending
- 1975-04-11 BE BE155325A patent/BE827839A/en unknown
- 1975-04-11 JP JP50044173A patent/JPS50143802A/ja active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5158671A (en) * | 1987-12-18 | 1992-10-27 | Exxon Research And Engineering Company | Method for stabilizing hydroisomerates |
| WO1992020759A1 (en) * | 1991-05-10 | 1992-11-26 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst and its use |
| US5182248A (en) * | 1991-05-10 | 1993-01-26 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst |
| US5290426A (en) * | 1991-05-10 | 1994-03-01 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst and its use |
| US6274029B1 (en) | 1995-10-17 | 2001-08-14 | Exxon Research And Engineering Company | Synthetic diesel fuel and process for its production |
| US6296757B1 (en) | 1995-10-17 | 2001-10-02 | Exxon Research And Engineering Company | Synthetic diesel fuel and process for its production |
| US6607568B2 (en) | 1995-10-17 | 2003-08-19 | Exxonmobil Research And Engineering Company | Synthetic diesel fuel and process for its production (law3 1 1) |
| US6822131B1 (en) | 1995-10-17 | 2004-11-23 | Exxonmobil Reasearch And Engineering Company | Synthetic diesel fuel and process for its production |
| US6221328B1 (en) | 1996-10-28 | 2001-04-24 | Dsm N.V. | Process for preparing hydroxylammonium salts |
| US6309432B1 (en) | 1997-02-07 | 2001-10-30 | Exxon Research And Engineering Company | Synthetic jet fuel and process for its production |
| US6669743B2 (en) | 1997-02-07 | 2003-12-30 | Exxonmobil Research And Engineering Company | Synthetic jet fuel and process for its production (law724) |
| US6765025B2 (en) | 2002-01-17 | 2004-07-20 | Dalian Institute Of Chemical Physics, Chinese Academy Of Science | Process for direct synthesis of diesel distillates with high quality from synthesis gas through Fischer-Tropsch synthesis |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1069452A (en) | 1980-01-08 |
| FR2267360A1 (en) | 1975-11-07 |
| DE2515880A1 (en) | 1975-10-23 |
| BR7502202A (en) | 1975-12-09 |
| FR2267360B3 (en) | 1977-07-01 |
| NL7504276A (en) | 1975-10-14 |
| JPS50143802A (en) | 1975-11-19 |
| IT1035252B (en) | 1979-10-20 |
| BE827839A (en) | 1975-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |