GB1481563A - Cracking catalyst and cracking process using same - Google Patents
Cracking catalyst and cracking process using sameInfo
- Publication number
- GB1481563A GB1481563A GB3166474A GB3166474A GB1481563A GB 1481563 A GB1481563 A GB 1481563A GB 3166474 A GB3166474 A GB 3166474A GB 3166474 A GB3166474 A GB 3166474A GB 1481563 A GB1481563 A GB 1481563A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- cracking
- component
- catalyst
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005336 cracking Methods 0.000 title abstract 7
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 abstract 9
- 239000002184 metal Substances 0.000 abstract 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000004927 clay Substances 0.000 abstract 2
- 229910052570 clay Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 125000005594 diketone group Chemical group 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003546 flue gas Substances 0.000 abstract 1
- 230000035876 healing Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C10G11/182—Regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C10G11/187—Controlling or regulating
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1481563 Cracking catalyst MOBIL OIL CORP 17 July 1974 [20 Sept 1973 8 Feb 1974] 31664/74 Healing B1E [Also in Divisions Cl and C5] A cracking catalyst in the form of particles suitable for use in a moving-bed or fluidisedbed cracking unit, comprises at least one component catalytically active for cracking of a mixed hydrocarbon feedstock in the absence of added hydrogen and having an average pore size sufficiently large to admit benzene, and a metal component which is a platinum group metal or rhenium or compounds thereof in an amount of up to 50 ppm metal based on the catalyst, the metal component being accessible to the feedstock. The cracking component may be silica in combination with one or more of alumina, magnesia or clay or a zeolite in a matrix of one or more of silica, alumina, magnesia, zirconia or clay. The metal component may be incorporated by ion-exchange or impregnation and may be deposited from a hydrocarbon feedstock containing a dissolved compound thereof, e.g. a metal diketone, metal carbonyl, metallocene, metal-olefin complex having 2 to 20 carbon atoms, metal-acetylene complex metal complex of alkyl- or arylphosphines or metal carboxylate of 1 to 20 carbon atoms. The metal component has the function of reducing the level of CO in the flue gases arising from regeneration of the catalyst by decarbonisation.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39900873A | 1973-09-20 | 1973-09-20 | |
| US44089074A | 1974-02-08 | 1974-02-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1481563A true GB1481563A (en) | 1977-08-03 |
Family
ID=27016466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3166474A Expired GB1481563A (en) | 1973-09-20 | 1974-07-17 | Cracking catalyst and cracking process using same |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5415038B2 (en) |
| AR (1) | AR212419A1 (en) |
| AU (1) | AU497439B2 (en) |
| CA (1) | CA1051411A (en) |
| DE (3) | DE2462866C2 (en) |
| FR (1) | FR2257673B1 (en) |
| GB (1) | GB1481563A (en) |
| IT (1) | IT1022123B (en) |
| NL (1) | NL176084C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2416254A1 (en) * | 1978-02-02 | 1979-08-31 | Mobil Oil Corp | CATALYTIC CRACKING IN FLUID BED |
| US4976847A (en) * | 1988-08-26 | 1990-12-11 | Shell Oil Company | Process for the catalytic cracking of a hydrocarbon feedstock |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN145334B (en) * | 1975-09-29 | 1978-09-23 | Uop Inc | |
| CA1093050A (en) * | 1975-12-19 | 1981-01-06 | Iacovos A. Vasalos | Catalytic cracking with reduced emission of noxious gases |
| US4153535A (en) * | 1975-12-19 | 1979-05-08 | Standard Oil Company (Indiana) | Catalytic cracking with reduced emission of noxious gases |
| US4148751A (en) * | 1976-02-02 | 1979-04-10 | Uop Inc. | Method of regenerating coke-contaminated catalyst with simultaneous combustion of carbon monoxide |
| IL51340A (en) * | 1976-02-19 | 1980-01-31 | Mobil Oil Corp | Catalytic cracking of hydrocarbons |
| US4071436A (en) * | 1976-03-11 | 1978-01-31 | Chevron Research Company | Process for removing sulphur from a gas |
| CA1046484A (en) * | 1976-04-12 | 1979-01-16 | Elroy M. Gladrow | Hydrocarbon conversion catalyst containing a co oxidation promoter |
| US4252632A (en) * | 1976-04-29 | 1981-02-24 | Atlantic Richfield Company | Catalyst and process for conversion of hydrocarbons |
| CA1105406A (en) * | 1976-04-29 | 1981-07-21 | Fred S. Zrinscak, Sr. | Catalytic cracking of metal-contaminated oils |
| US4253939A (en) * | 1976-06-21 | 1981-03-03 | Atlantic Richfield Company | Catalyst and process for conversion of hydrocarbons |
| GB1585507A (en) * | 1976-04-29 | 1981-03-04 | Atlantic Richfield Co | Catalyst and process for conversion of hydrocarbons |
| US4064037A (en) * | 1976-07-09 | 1977-12-20 | Mobil Oil Corporation | Temporary shutdown of co-combustion devices |
| US4107032A (en) * | 1976-11-01 | 1978-08-15 | Mobil Oil Corporation | Process for cracking hydrocarbons |
| CA1124224A (en) * | 1977-04-11 | 1982-05-25 | Chevron Research And Technology Company | Process for removing pollutants from catalyst regenerator flue gas |
| US4222856A (en) * | 1977-06-09 | 1980-09-16 | Air Products And Chemicals, Inc. | Method for promoting regeneration of a catalyst in a fluidized regenerator |
| US4297244A (en) * | 1977-10-27 | 1981-10-27 | Atlantic Richfield Company | Catalyst and process for conversion of hydrocarbons |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2939847A (en) * | 1957-11-21 | 1960-06-07 | Universal Oil Prod Co | Manufacture of noble metal catalyst |
| US3364136A (en) | 1965-12-10 | 1968-01-16 | Mobil Oil Corp | Novel cyclic catalytic process for the conversion of hydrocarbons |
| DE1296726B (en) * | 1963-12-24 | 1969-06-04 | Mobil Oil Corp | Process for reforming heavy gasoline in the presence of a catalyst composed of a crystalline aluminum silicate |
| DE1542188A1 (en) * | 1965-10-05 | 1970-03-26 | Grace W R & Co | Catalyst for hydrocracking hydrocarbons |
| US3650990A (en) | 1969-10-09 | 1972-03-21 | Mobil Oil Corp | Catalyst and method for preparing same |
| US3696025A (en) * | 1970-11-09 | 1972-10-03 | Chevron Res | Catalytic cracking by addition of titanium to catalyst |
-
1974
- 1974-06-12 CA CA202,263A patent/CA1051411A/en not_active Expired
- 1974-07-17 GB GB3166474A patent/GB1481563A/en not_active Expired
- 1974-07-30 JP JP8667974A patent/JPS5415038B2/ja not_active Expired
- 1974-08-07 FR FR7427390A patent/FR2257673B1/fr not_active Expired
- 1974-09-19 IT IT2748274A patent/IT1022123B/en active
- 1974-09-19 NL NL7412423A patent/NL176084C/en not_active IP Right Cessation
- 1974-09-19 DE DE19742462866 patent/DE2462866C2/de not_active Expired - Lifetime
- 1974-09-19 AR AR25565774A patent/AR212419A1/en active
- 1974-09-19 AU AU73507/74A patent/AU497439B2/en not_active Expired
- 1974-09-19 DE DE19742444911 patent/DE2444911B2/en not_active Ceased
- 1974-09-19 DE DE19742462867 patent/DE2462867C2/de not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2416254A1 (en) * | 1978-02-02 | 1979-08-31 | Mobil Oil Corp | CATALYTIC CRACKING IN FLUID BED |
| US4194965A (en) * | 1978-02-02 | 1980-03-25 | Mobil Oil Corporation | Fluid catalytic cracking |
| US4976847A (en) * | 1988-08-26 | 1990-12-11 | Shell Oil Company | Process for the catalytic cracking of a hydrocarbon feedstock |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1051411A (en) | 1979-03-27 |
| NL7412423A (en) | 1975-03-24 |
| FR2257673B1 (en) | 1979-03-09 |
| JPS5057092A (en) | 1975-05-19 |
| DE2462866C2 (en) | 1993-03-18 |
| NL176084C (en) | 1988-04-18 |
| JPS5415038B2 (en) | 1979-06-12 |
| AU7350774A (en) | 1976-03-25 |
| DE2444911B2 (en) | 1981-04-02 |
| FR2257673A1 (en) | 1975-08-08 |
| AU497439B2 (en) | 1978-12-14 |
| IT1022123B (en) | 1978-03-20 |
| DE2462867C2 (en) | 1987-06-11 |
| AR212419A1 (en) | 1978-07-14 |
| DE2444911A1 (en) | 1975-04-03 |
| NL176084B (en) | 1984-09-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 414F | Notice of opposition given (sect. 14/1949) | ||
| 414B | Case decided by the comptroller ** grants allowed (sect. 14/1949) | ||
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19940716 |