GB1345363A - Process for the preparation of zeolites - Google Patents
Process for the preparation of zeolitesInfo
- Publication number
- GB1345363A GB1345363A GB2239471A GB2239471A GB1345363A GB 1345363 A GB1345363 A GB 1345363A GB 2239471 A GB2239471 A GB 2239471A GB 2239471 A GB2239471 A GB 2239471A GB 1345363 A GB1345363 A GB 1345363A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zeolite
- sio
- prepared
- catalysts
- tetraalkylammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 2
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229910018068 Li 2 O Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 abstract 1
- -1 tetraalkylammonium ions Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/30—Erionite or offretite type, e.g. zeolite T
- C01B39/305—Erionite or offretite type, e.g. zeolite T using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1345363 Zeolite catalyst SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 19 April 1971 [25 Feb 1970] 22394/71 Heading B1E [Also in Divisions Cl and C5] Catalysts -may be prepared by calcining a zeolite which has been loaded with at least one catalyst metal component from the Groups IB, IIB, VA, VIA, VIIA of the Mendeleef Table, particularly Pd and Pt, the zeolite having SiO 2 /Al 2 O 3 between 4 and 10 and containing tetraalkylammonium ions and at least two of Li<SP>+</SP>, Na<SP>+</SP> and K<SP>+</SP> and having been prepared by heating a mixture having the following compositions: a Na 2 O, b K 2 O, c Li 2 O, d R 2 O, Al 2 O 3 , e SiO 2 , f H 2 O where R= tetraalkylammonium a+b+c+d=3.0-4.5 e=9.5-13.0, f=100-500 and where b or c but not both b and c may be zero. Examples describe the hydrocracking of a hydrocarbon mixture and the isomerization of n-hexane using platinum-containing catalysts.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7002636,A NL168194C (en) | 1970-02-25 | 1970-02-25 | PROCESS FOR THE PREPARATION OF ALUMINOSILICATE ZEOLITES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1345363A true GB1345363A (en) | 1974-01-30 |
Family
ID=19809424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2239471A Expired GB1345363A (en) | 1970-02-25 | 1971-04-19 | Process for the preparation of zeolites |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5529008B1 (en) |
| BE (1) | BE763123A (en) |
| DE (1) | DE2108512C3 (en) |
| FR (1) | FR2078973A5 (en) |
| GB (1) | GB1345363A (en) |
| NL (1) | NL168194C (en) |
| ZA (1) | ZA711172B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4375458A (en) * | 1977-08-17 | 1983-03-01 | Mobil Oil Corporation | Synthesis of large crystallite zeolites |
| US4554146A (en) * | 1983-11-10 | 1985-11-19 | Exxon Research And Engineering Co. | Process for preparing a zeolite of the L type using organic templates |
| GB2160188A (en) * | 1984-06-07 | 1985-12-18 | Inst Francais Du Petrole | Synthetic zeolites |
| EP0155851A3 (en) * | 1984-03-21 | 1986-05-21 | Catalysts & Chemicals Industries Co., Ltd. | Hydrocarbon catalytic cracking catalyst compositions |
| US4834961A (en) * | 1983-03-07 | 1989-05-30 | Centre National De La Recherche Scientifique | Aluminosilicate zeolite having an offretite structure |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA735587B (en) * | 1972-08-21 | 1974-07-31 | Universal Oil Prod Co | Catalyst and method of manufacture |
| NZ185397A (en) * | 1976-11-04 | 1979-12-11 | Mobil Oil Corp | Crystalline aluminosilicate zeolites and use as catalysts |
-
1970
- 1970-02-25 NL NLAANVRAGE7002636,A patent/NL168194C/en not_active IP Right Cessation
-
1971
- 1971-02-18 BE BE763123A patent/BE763123A/en unknown
- 1971-02-23 FR FR7106149A patent/FR2078973A5/fr not_active Expired
- 1971-02-23 ZA ZA711172A patent/ZA711172B/en unknown
- 1971-02-23 JP JP842571A patent/JPS5529008B1/ja active Pending
- 1971-02-23 DE DE2108512A patent/DE2108512C3/en not_active Expired
- 1971-04-19 GB GB2239471A patent/GB1345363A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4375458A (en) * | 1977-08-17 | 1983-03-01 | Mobil Oil Corporation | Synthesis of large crystallite zeolites |
| US4834961A (en) * | 1983-03-07 | 1989-05-30 | Centre National De La Recherche Scientifique | Aluminosilicate zeolite having an offretite structure |
| US4554146A (en) * | 1983-11-10 | 1985-11-19 | Exxon Research And Engineering Co. | Process for preparing a zeolite of the L type using organic templates |
| EP0155851A3 (en) * | 1984-03-21 | 1986-05-21 | Catalysts & Chemicals Industries Co., Ltd. | Hydrocarbon catalytic cracking catalyst compositions |
| GB2160188A (en) * | 1984-06-07 | 1985-12-18 | Inst Francais Du Petrole | Synthetic zeolites |
Also Published As
| Publication number | Publication date |
|---|---|
| BE763123A (en) | 1971-08-18 |
| NL7002636A (en) | 1971-08-27 |
| DE2108512C3 (en) | 1980-10-02 |
| JPS5529008B1 (en) | 1980-07-31 |
| FR2078973A5 (en) | 1971-11-05 |
| NL168194B (en) | 1981-10-16 |
| ZA711172B (en) | 1971-11-24 |
| DE2108512B2 (en) | 1979-11-29 |
| DE2108512A1 (en) | 1971-09-09 |
| NL168194C (en) | 1982-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |