GB1460795A - Process for the manufacture of partly crystalline polybutene-1 - Google Patents
Process for the manufacture of partly crystalline polybutene-1Info
- Publication number
- GB1460795A GB1460795A GB1613574A GB1613574A GB1460795A GB 1460795 A GB1460795 A GB 1460795A GB 1613574 A GB1613574 A GB 1613574A GB 1613574 A GB1613574 A GB 1613574A GB 1460795 A GB1460795 A GB 1460795A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butene
- aluminium
- ticl
- trialkyl
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229920001748 polybutylene Polymers 0.000 title 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 239000004411 aluminium Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- IZMHKHHRLNWLMK-UHFFFAOYSA-M chloridoaluminium Chemical compound Cl[Al] IZMHKHHRLNWLMK-UHFFFAOYSA-M 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
1460795 Butene-1 polymerization CHEMISCHE WERKE HULS AG 11 April 1974 [14 April 1973] 16135/74 Heading C3P Butene-1 is homopolymerized or copolymerized with up to 10% of other monomers in butene-1 itself as reaction medium or in a C 4 fraction containing butene-1 at 60‹ to 120‹ C. and in the presence of a catalyst comprising (a) TiCl 3 .n.AlCl 3 where n is 0À2 to 0À6 and (b) a mixture of 85 to 99À9 mol per cent of a dialkyl aluminium monochloride and 0À1 to 15 mol per cent of an aluminium trialkyl. The mixture of organoaluminium compounds (b) may be separately added to the isolated component (a) or the component (a) is prepared by reducing TiCl 4 with Et 3 Al 2 Cl 3 followed by addition of sufficient of a trialkyl aluminium to the resulting mixture of TiCl 3 .n.AlCl 3 and EtAlCl 2 to convert the latter to Et 2 AlOl and to leave a suitable quantity of unreacted trialkyl aluminium, thus forming the catalyst of (a) + (b) in situ.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732318901 DE2318901C3 (en) | 1973-04-14 | 1973-04-14 | Process for the production of partially crystalline polybutene-1 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1460795A true GB1460795A (en) | 1977-01-06 |
Family
ID=5878092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1613574A Expired GB1460795A (en) | 1973-04-14 | 1974-04-11 | Process for the manufacture of partly crystalline polybutene-1 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS579365B2 (en) |
| DE (1) | DE2318901C3 (en) |
| FR (1) | FR2225448B1 (en) |
| GB (1) | GB1460795A (en) |
| IT (1) | IT1004223B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005017200A1 (en) * | 2005-04-13 | 2006-10-19 | Degussa Ag | Use of a high-viscosity, largely amorphous polyolefin for producing a film |
| DE102005017201A1 (en) * | 2005-04-13 | 2006-10-19 | Degussa Ag | High viscosity, largely amorphous polyolefin |
-
1973
- 1973-04-14 DE DE19732318901 patent/DE2318901C3/en not_active Expired
-
1974
- 1974-03-22 FR FR7409819A patent/FR2225448B1/fr not_active Expired
- 1974-04-11 IT IT5033274A patent/IT1004223B/en active
- 1974-04-11 GB GB1613574A patent/GB1460795A/en not_active Expired
- 1974-04-13 JP JP4159374A patent/JPS579365B2/ja not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US7459511B2 (en) | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US8030421B2 (en) | 2001-06-12 | 2011-10-04 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2225448A1 (en) | 1974-11-08 |
| FR2225448B1 (en) | 1979-04-20 |
| JPS509684A (en) | 1975-01-31 |
| DE2318901C3 (en) | 1979-11-08 |
| JPS579365B2 (en) | 1982-02-20 |
| DE2318901A1 (en) | 1974-11-07 |
| IT1004223B (en) | 1976-07-10 |
| DE2318901B2 (en) | 1979-03-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |