GB1446279A - Production of azines - Google Patents
Production of azinesInfo
- Publication number
- GB1446279A GB1446279A GB3839974A GB3839974A GB1446279A GB 1446279 A GB1446279 A GB 1446279A GB 3839974 A GB3839974 A GB 3839974A GB 3839974 A GB3839974 A GB 3839974A GB 1446279 A GB1446279 A GB 1446279A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ketone
- acid
- azines
- hydrogen peroxide
- selenium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 150000002576 ketones Chemical class 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 3
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052711 selenium Inorganic materials 0.000 abstract 2
- 239000011669 selenium Substances 0.000 abstract 2
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052714 tellurium Inorganic materials 0.000 abstract 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- -1 ketone peroxide Chemical class 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- RCPRQLSJGVLWRZ-UHFFFAOYSA-N o-aminooxyhydroxylamine Chemical class NOON RCPRQLSJGVLWRZ-UHFFFAOYSA-N 0.000 abstract 1
- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 abstract 1
- QYHFIVBSNOWOCQ-UHFFFAOYSA-N selenic acid Chemical compound O[Se](O)(=O)=O QYHFIVBSNOWOCQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003346 selenoethers Chemical class 0.000 abstract 1
- MCAHWIHFGHIESP-UHFFFAOYSA-N selenous acid Chemical compound O[Se](O)=O MCAHWIHFGHIESP-UHFFFAOYSA-N 0.000 abstract 1
- WQIJNCUKAOHNPM-UHFFFAOYSA-L silver selenite Chemical compound [Ag+].[Ag+].[O-][Se]([O-])=O WQIJNCUKAOHNPM-UHFFFAOYSA-L 0.000 abstract 1
- XHGGEBRKUWZHEK-UHFFFAOYSA-L tellurate Chemical compound [O-][Te]([O-])(=O)=O XHGGEBRKUWZHEK-UHFFFAOYSA-L 0.000 abstract 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 abstract 1
- SITVSCPRJNYAGV-UHFFFAOYSA-L tellurite Chemical compound [O-][Te]([O-])=O SITVSCPRJNYAGV-UHFFFAOYSA-L 0.000 abstract 1
- SITVSCPRJNYAGV-UHFFFAOYSA-N tellurous acid Chemical compound O[Te](O)=O SITVSCPRJNYAGV-UHFFFAOYSA-N 0.000 abstract 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 239000011135 tin Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/16—Hydrazine; Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1446279 Azines BAYER AG 3 Sept 1974 [5 Sept 1973] 38399/74 Heading C2C In the manufacture of azines by reacting ammonia, hydrogen peroxide and an aldehyde or a ketone, the catalyst used is selenium, tellurium or a compound of selenium or tellurium, e.g. selenium dioxide, selenous acid, selenic acid, tellurous acid, telluric acid or an ammonium, alkali metal, alkaline earth metal, zinc, aluminium, tin, lead, arsenic, antimony, bismuth or silver selenite, selenate, selenide, tellurite, tellurate or telluride. The sodium salt of ethylene diamine tetracetic acid may also be present during the reaction. The ketone and hydrogen peroxide may be used, wholly or in part as a ketone peroxide. Similarly the ketone, hydrogen peroxide and ammonia may be used, wholly or in part, in the form of an aminoperoxide of the ketone. Examples describe the preparation of the azines of acetone, methyl ethyl ketone and cyclohexanone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732344604 DE2344604A1 (en) | 1973-09-05 | 1973-09-05 | METHOD OF MANUFACTURING AZINES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1446279A true GB1446279A (en) | 1976-08-18 |
Family
ID=5891601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3839974A Expired GB1446279A (en) | 1973-09-05 | 1974-09-03 | Production of azines |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5050310A (en) |
| BE (1) | BE819411A (en) |
| DE (1) | DE2344604A1 (en) |
| FR (1) | FR2242373B1 (en) |
| GB (1) | GB1446279A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0758642A3 (en) * | 1995-08-14 | 1997-07-30 | Mitsubishi Gas Chemical Co | Synthetic process of ketazine and synthetic process of hydrazine hydrate |
| FR2817863A1 (en) * | 2000-12-07 | 2002-06-14 | Jean Pierre Schirmann | PROCESS FOR THE MANUFACTURE OF HYDRAZINE IN AQUEOUS SOLUTION AND SYNTHESIS INTERMEDIATE PRODUCT IN THIS MANUFACTURE |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4347383A (en) * | 1979-05-11 | 1982-08-31 | Mitsubishi Gas Chemical Company, Inc. | Process for producing benzophenone-azines |
| FR2647444B1 (en) * | 1989-05-24 | 1991-07-26 | Atochem |
-
1973
- 1973-09-05 DE DE19732344604 patent/DE2344604A1/en active Pending
-
1974
- 1974-08-30 BE BE148098A patent/BE819411A/en unknown
- 1974-09-03 GB GB3839974A patent/GB1446279A/en not_active Expired
- 1974-09-03 JP JP10061374A patent/JPS5050310A/ja active Pending
- 1974-09-05 FR FR7430203A patent/FR2242373B1/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0758642A3 (en) * | 1995-08-14 | 1997-07-30 | Mitsubishi Gas Chemical Co | Synthetic process of ketazine and synthetic process of hydrazine hydrate |
| US5986134A (en) * | 1995-08-14 | 1999-11-16 | Mitsubishi Gas Chemical Company, Inc. | Processes for producing ketazine and hydrazine |
| FR2817863A1 (en) * | 2000-12-07 | 2002-06-14 | Jean Pierre Schirmann | PROCESS FOR THE MANUFACTURE OF HYDRAZINE IN AQUEOUS SOLUTION AND SYNTHESIS INTERMEDIATE PRODUCT IN THIS MANUFACTURE |
Also Published As
| Publication number | Publication date |
|---|---|
| BE819411A (en) | 1975-02-28 |
| DE2344604A1 (en) | 1975-03-27 |
| JPS5050310A (en) | 1975-05-06 |
| FR2242373B1 (en) | 1978-04-28 |
| FR2242373A1 (en) | 1975-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |