GB1444048A - Random copolymers - Google Patents
Random copolymersInfo
- Publication number
- GB1444048A GB1444048A GB1156974A GB1156974A GB1444048A GB 1444048 A GB1444048 A GB 1444048A GB 1156974 A GB1156974 A GB 1156974A GB 1156974 A GB1156974 A GB 1156974A GB 1444048 A GB1444048 A GB 1444048A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- copolymer
- phthalimide
- vinylcarbazole
- vinylamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005604 random copolymer Polymers 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 8
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 abstract 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- IGDLZDCWMRPMGL-UHFFFAOYSA-N 2-ethenylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(C=C)C(=O)C2=C1 IGDLZDCWMRPMGL-UHFFFAOYSA-N 0.000 abstract 2
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 abstract 1
- LOTKRQAVGJMPNV-UHFFFAOYSA-N 1-fluoro-2,4-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(F)C([N+]([O-])=O)=C1 LOTKRQAVGJMPNV-UHFFFAOYSA-N 0.000 abstract 1
- WFQDTOYDVUWQMS-UHFFFAOYSA-N 1-fluoro-4-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(F)C=C1 WFQDTOYDVUWQMS-UHFFFAOYSA-N 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 230000004888 barrier function Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 abstract 1
- 238000003384 imaging method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920006267 polyester film Polymers 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/07—Polymeric photoconductive materials
- G03G5/071—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G5/072—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising pending monoamine groups
- G03G5/073—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising pending monoamine groups comprising pending carbazole groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
- C08F26/12—N-Vinyl-carbazole
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1444048 Copolymers of N-vinyl carbazole XEROX CORP 15 March 1974 [19 March 1973] 11569/74 Heading C3P A random copolymer is derived from components comprising at least first and second components respectively corresponding to (i) N-vinyl carbazole and (ii) at least one monomer selected from N-vinyl phthalimide, N-vinylamine and an electron acceptor other than N- vinyl phthalimide or N-vinylamine. The N- vinyl carbazole/N-vinyl phthalimide copolymer may be prepared in solution in benzene using a catalyst such as azobisisobutyronitrile. The resulting copolymer may be treated with hydrazine hydrate to yeild an N-vinyl carbazole/ vinylamine copolymer which is subsequently reacted with (a) a tetrahalophthalic anhydride to form N - vinylcarbazole/tetrabromotetrachloro- or tetraiodo-phthalimide copolymer, (b) 2,4 - dinitrofluorobenzene to form N- vinylcarbazole/N - vinyl - 2,4 - dinitroaniline copolymer or (c) 1-fluoro-4-nitrobenzene to form N - vinylcarbazole/N - vinyl - 4 - nitroaniline copolymer. Solutions of the copolymers may be applied to a conductive substrate, e.g. aluminized polyester film substrate, optionally coated with a barrier layer to form the photoconductive layer of an electrophotographic imaging member.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US342646A US3877936A (en) | 1973-03-19 | 1973-03-19 | Photoconductive copolymer of N-vinylcarbazole and N-vinylphthalimide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1444048A true GB1444048A (en) | 1976-07-28 |
Family
ID=23342683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1156974A Expired GB1444048A (en) | 1973-03-19 | 1974-03-15 | Random copolymers |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3877936A (en) |
| JP (1) | JPS5233495B2 (en) |
| BE (1) | BE812436A (en) |
| BR (1) | BR7402072D0 (en) |
| CA (1) | CA1024696A (en) |
| DE (1) | DE2409108A1 (en) |
| ES (1) | ES424411A1 (en) |
| FR (1) | FR2223400B1 (en) |
| GB (1) | GB1444048A (en) |
| IT (1) | IT1010697B (en) |
| NL (1) | NL7403708A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4898915A (en) * | 1983-08-24 | 1990-02-06 | University Of Akron | Alternating copolymerization of donor monomers having protected amine groups with acceptor monomers |
| US5326661A (en) * | 1991-11-13 | 1994-07-05 | Hoechst Celanese Corp. | Photorefractive polymers containing discrete photoconductive and electrooptical units |
| US5958288A (en) * | 1996-11-26 | 1999-09-28 | Cabot Corporation | Composition and slurry useful for metal CMP |
| US7732116B2 (en) * | 2007-09-27 | 2010-06-08 | Eastman Kodak Company | Photoconductors containing N-arylphthalimides |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3155503A (en) * | 1959-02-26 | 1964-11-03 | Gevaert Photo Prod Nv | Electrophotographic material |
| NL253125A (en) * | 1959-07-01 | |||
| US3073785A (en) * | 1959-07-02 | 1963-01-15 | Electrically conductive polymeric | |
| US3287122A (en) * | 1961-07-24 | 1966-11-22 | Azoplate Corp | Process for the sensitization of photoconductors |
| US3418116A (en) * | 1963-02-21 | 1968-12-24 | Matsushita Electric Industrial Co Ltd | Electrophotographic materials comprising polymeric intramolecular charge transfer complexes |
| US3697264A (en) * | 1970-03-02 | 1972-10-10 | Richard M Podhajny | Novel photoconductive carbazole polymers and photoconductive elements embodying same |
-
1973
- 1973-03-19 US US342646A patent/US3877936A/en not_active Expired - Lifetime
-
1974
- 1974-02-07 CA CA192,004A patent/CA1024696A/en not_active Expired
- 1974-02-26 DE DE2409108A patent/DE2409108A1/en active Pending
- 1974-03-15 IT IT12600/74A patent/IT1010697B/en active
- 1974-03-15 GB GB1156974A patent/GB1444048A/en not_active Expired
- 1974-03-18 BE BE142114A patent/BE812436A/en unknown
- 1974-03-18 ES ES424411A patent/ES424411A1/en not_active Expired
- 1974-03-18 JP JP49030855A patent/JPS5233495B2/ja not_active Expired
- 1974-03-18 BR BR742072A patent/BR7402072D0/en unknown
- 1974-03-19 NL NL7403708A patent/NL7403708A/xx unknown
- 1974-03-19 FR FR7409307A patent/FR2223400B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES424411A1 (en) | 1976-11-01 |
| BR7402072D0 (en) | 1974-12-24 |
| FR2223400A1 (en) | 1974-10-25 |
| IT1010697B (en) | 1977-01-20 |
| JPS50111189A (en) | 1975-09-01 |
| US3877936A (en) | 1975-04-15 |
| AU6663774A (en) | 1975-09-18 |
| DE2409108A1 (en) | 1974-09-26 |
| CA1024696A (en) | 1978-01-17 |
| NL7403708A (en) | 1974-09-23 |
| BE812436A (en) | 1974-07-15 |
| FR2223400B1 (en) | 1977-06-17 |
| JPS5233495B2 (en) | 1977-08-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |