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GB1399137A - Production of reducing gases - Google Patents

Production of reducing gases

Info

Publication number
GB1399137A
GB1399137A GB3334172A GB3334172A GB1399137A GB 1399137 A GB1399137 A GB 1399137A GB 3334172 A GB3334172 A GB 3334172A GB 3334172 A GB3334172 A GB 3334172A GB 1399137 A GB1399137 A GB 1399137A
Authority
GB
United Kingdom
Prior art keywords
gas
air
catalyst
oxygen
preheated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3334172A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Priority to GB3334172A priority Critical patent/GB1399137A/en
Priority to DE19732352438 priority patent/DE2352438A1/en
Priority to AU61690/73A priority patent/AU485072B2/en
Priority to FR7338697A priority patent/FR2249030B1/fr
Priority to JP48124906A priority patent/JPS5075590A/ja
Priority to LU68795A priority patent/LU68795A1/xx
Publication of GB1399137A publication Critical patent/GB1399137A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/169—Controlling the feed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Manufacture Of Iron (AREA)

Abstract

1399137 Hydrogen-carbon monoxide mixtures BRITISH PETROLEUM CO Ltd 8 Oct 1973 [17 July 1972] 33341/72 Heading C5E In a process for the production of a gas containing at least 94 volume per cent hydrogen and carbon monoxide by the partial oxidation of a C 1 -C 7 hydrocarbon fraction with an oxygencontaining gas, the heat supplied to the reaction is provided entirely by heating the reactants and the time between the contacting of the reactants and their entry into a bed of reforming catalyst is from 5 to 30 milliseconds. Mixing of the reactants before they enter the catalyst bed can be ensured by injecting them tangentially into an inlet chamber through a port which has a nozzle for the hydrocarbons projecting into the pipe for the oxygen-containing gas. The oxygen-containing gas, e.g. oxygen or air can be preheated to 700-1100‹ C. and the hydrocarbon feed, e.g. natural gas or coke oven gas, is not preheated to above 400‹C. The catalyst suitably comprises 3-15 wt. per cent nickel on an alumina, silica, alumino-silicate or magnesia support, which can also contain uranium, barium and/or potassium. The product gas has a temperature of 800-1200‹ C. and can be used for the reduction of iron ore in the upper part of a blast furnace or in a fluidized bed. As shown heaters 12 and 12a, which are alternately heated by combustion of fuel and air from lines 14 and 15, are used to heat the incoming air from line 21. The hydrocarbon feed from storage tank 1 and the preheated air are mixed in the swirl chamber 8 of the reformer 9 which contains a fixed or fluidized bed of the catalyst.
GB3334172A 1972-07-17 1972-07-17 Production of reducing gases Expired GB1399137A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB3334172A GB1399137A (en) 1972-07-17 1972-07-17 Production of reducing gases
DE19732352438 DE2352438A1 (en) 1972-07-17 1973-10-19 PROCESS FOR THE CATALYTIC PARTIAL OXYDATION OF HYDROCARBONS
AU61690/73A AU485072B2 (en) 1972-07-17 1973-10-23 Improvements relating tothe production of reducing gases
FR7338697A FR2249030B1 (en) 1972-07-17 1973-10-30
JP48124906A JPS5075590A (en) 1972-07-17 1973-11-06
LU68795A LU68795A1 (en) 1972-07-17 1973-11-13

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB3334172A GB1399137A (en) 1972-07-17 1972-07-17 Production of reducing gases
DE19732352438 DE2352438A1 (en) 1972-07-17 1973-10-19 PROCESS FOR THE CATALYTIC PARTIAL OXYDATION OF HYDROCARBONS
AU61690/73A AU485072B2 (en) 1972-07-17 1973-10-23 Improvements relating tothe production of reducing gases
FR7338697A FR2249030B1 (en) 1972-07-17 1973-10-30
JP48124906A JPS5075590A (en) 1972-07-17 1973-11-06
LU68795A LU68795A1 (en) 1972-07-17 1973-11-13

Publications (1)

Publication Number Publication Date
GB1399137A true GB1399137A (en) 1975-06-25

Family

ID=27542782

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3334172A Expired GB1399137A (en) 1972-07-17 1972-07-17 Production of reducing gases

Country Status (6)

Country Link
JP (1) JPS5075590A (en)
AU (1) AU485072B2 (en)
DE (1) DE2352438A1 (en)
FR (1) FR2249030B1 (en)
GB (1) GB1399137A (en)
LU (1) LU68795A1 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758375A (en) * 1984-05-02 1988-07-19 The British Petroleum Company P.L.C. Conversion process
US4767569A (en) * 1984-04-05 1988-08-30 The British Petroleum Company P.L.C. Process for producing synthesis gas by partial combustion of hydrocarbons
US5149464A (en) * 1989-06-30 1992-09-22 Gas Research Institute Catalytic gas conversion method
WO2002006154A1 (en) * 2000-07-19 2002-01-24 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and device for producing a gas mixture containing hydrogen and co by staged oxidation of a hydrocarbon
FR2811975A1 (en) * 2000-07-19 2002-01-25 Air Liquide PROCESS AND DEVICE FOR PRODUCING A GASEOUS MIXTURE CONTAINING HYDROGEN AND CO
US6458334B1 (en) 2000-03-02 2002-10-01 The Boc Group, Inc. Catalytic partial oxidation of hydrocarbons
EP1413548A1 (en) * 2002-10-23 2004-04-28 Conocophillips Company Regeneration of partial oxidation catalysts
US7066984B2 (en) 2003-09-25 2006-06-27 The Boc Group, Inc. High recovery carbon monoxide production process
US7090826B2 (en) 2002-12-23 2006-08-15 The Boc Group, Inc. Monolith based catalytic partial oxidation process for syngas production
US7214331B2 (en) 2004-02-26 2007-05-08 The Boc Group, Inc. Catalyst configuration and methods for syngas production
US7351275B2 (en) 2004-12-21 2008-04-01 The Boc Group, Inc. Carbon monoxide production process
RU2333797C2 (en) * 2003-12-18 2008-09-20 Тийода Корпорейшн Catalyst for obtaining synthesis-gas and method for obtaining synthesis-gas using same
RU2350386C1 (en) * 2007-12-06 2009-03-27 Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) Catalyst, method of preparation and method of synthetic gas production from methane
WO2010107332A1 (en) * 2009-03-20 2010-09-23 Институт Катализа Имени Г.К.Борескова Сибирского Отделения Российской Академии Наук Catalyst, a method for the preparation thereof and a method for producing a synthesis gas from methane

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59116102A (en) * 1982-12-22 1984-07-04 Osaka Gas Co Ltd Production of reducing gas using ruthenium catalyst
GB2163449B (en) * 1984-07-18 1988-06-02 Shell Int Research Production of gas mixtures containing hydrogen and carbon monoxide
CA2004219A1 (en) * 1988-11-30 1990-05-31 Michael Dunster Production of hydrogen from hydrocarbonaceous feedstock
LU102057B1 (en) * 2020-09-09 2022-03-09 Wurth Paul Sa Method for operating a blast furnace installation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2141875A1 (en) * 1971-08-20 1973-03-01 Metallgesellschaft Ag METHOD FOR PRODUCING A REDUCING GAS
JPS4853986A (en) * 1971-11-04 1973-07-28
JPS5227629B2 (en) * 1972-01-10 1977-07-21

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4767569A (en) * 1984-04-05 1988-08-30 The British Petroleum Company P.L.C. Process for producing synthesis gas by partial combustion of hydrocarbons
US4758375A (en) * 1984-05-02 1988-07-19 The British Petroleum Company P.L.C. Conversion process
US5149464A (en) * 1989-06-30 1992-09-22 Gas Research Institute Catalytic gas conversion method
US6458334B1 (en) 2000-03-02 2002-10-01 The Boc Group, Inc. Catalytic partial oxidation of hydrocarbons
US6551959B2 (en) 2000-03-02 2003-04-22 The Boc Group, Inc. Catalytic monolith substrate made of ceria and titania
FR2811976A1 (en) * 2000-07-19 2002-01-25 Air Liquide PROCESS AND DEVICE FOR PRODUCING A GASEOUS MIXTURE CONTAINING HYDROGEN AND CO BY STAGE OXIDATION OF A HYDROCARBON
FR2811975A1 (en) * 2000-07-19 2002-01-25 Air Liquide PROCESS AND DEVICE FOR PRODUCING A GASEOUS MIXTURE CONTAINING HYDROGEN AND CO
WO2002006290A3 (en) * 2000-07-19 2003-01-30 Air Liquide Method and device for producing a gas mixture containing hydrogen and carbon monoxide
WO2002006154A1 (en) * 2000-07-19 2002-01-24 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and device for producing a gas mixture containing hydrogen and co by staged oxidation of a hydrocarbon
EP1413548A1 (en) * 2002-10-23 2004-04-28 Conocophillips Company Regeneration of partial oxidation catalysts
US7005455B2 (en) 2002-10-23 2006-02-28 Conocophillips Company Regeneration of partial oxidation catalysts
US7090826B2 (en) 2002-12-23 2006-08-15 The Boc Group, Inc. Monolith based catalytic partial oxidation process for syngas production
US7066984B2 (en) 2003-09-25 2006-06-27 The Boc Group, Inc. High recovery carbon monoxide production process
RU2333797C2 (en) * 2003-12-18 2008-09-20 Тийода Корпорейшн Catalyst for obtaining synthesis-gas and method for obtaining synthesis-gas using same
US7214331B2 (en) 2004-02-26 2007-05-08 The Boc Group, Inc. Catalyst configuration and methods for syngas production
US7351275B2 (en) 2004-12-21 2008-04-01 The Boc Group, Inc. Carbon monoxide production process
RU2350386C1 (en) * 2007-12-06 2009-03-27 Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) Catalyst, method of preparation and method of synthetic gas production from methane
WO2010107332A1 (en) * 2009-03-20 2010-09-23 Институт Катализа Имени Г.К.Борескова Сибирского Отделения Российской Академии Наук Catalyst, a method for the preparation thereof and a method for producing a synthesis gas from methane

Also Published As

Publication number Publication date
AU485072B2 (en) 1975-04-24
DE2352438A1 (en) 1975-04-24
FR2249030B1 (en) 1978-03-17
AU6169073A (en) 1975-04-24
FR2249030A1 (en) 1975-05-23
JPS5075590A (en) 1975-06-20
LU68795A1 (en) 1975-08-20

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee