GB1361542A - Monoazo benzthiazole basic dyes - Google Patents
Monoazo benzthiazole basic dyesInfo
- Publication number
- GB1361542A GB1361542A GB73172A GB73172A GB1361542A GB 1361542 A GB1361542 A GB 1361542A GB 73172 A GB73172 A GB 73172A GB 73172 A GB73172 A GB 73172A GB 1361542 A GB1361542 A GB 1361542A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- benzthiazole
- dyes
- basic dyes
- monoazo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- IOJUPLGTWVMSFF-UHFFFAOYSA-N cyclobenzothiazole Natural products C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000981 basic dye Substances 0.000 title abstract 3
- -1 Monoazo benzthiazole Chemical compound 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/02—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group
- C09B44/04—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group from coupling components containing amino as the only directing group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
1361542 Monoazo benzthiazole basic dyes YORKSHIRE CHEMICALS Ltd 5 Jan 1973 [7 Jan 1972] 731/72 Heading C4P The invention comprises water-soluble basic dyes where R<SP>1</SP> is H, alkyl, aryl or aralkyl, R<SP>2</SP> is alkylene, R<SP>3</SP> is H or alkyl, R<SP>4</SP> is alkyl, R<SP>5</SP> is alkyl, aryl, cycloalkyl, aralkyl or amino, and R<SP>3</SP>, R<SP>4</SP> and R<SP>5</SP> together with the nitrogen may represent a heterocyclic ring; each R<SP>6</SP> may be F, Cl, Br, or I; X is a water-solubilizing anion, and n is 1 to 4, with the proviso that when n is 1 or 2 and R<SP>6</SP> represents Cl and/or Br in the 4 and/or 6 position in the benzthiazole, then either R<SP>5</SP> represents an amino group or a cycloalkyl group or R<SP>3</SP>, R<SP>4</SP> and R<SP>5</SP> together with the nitrogen represent a heterocyclic ring; the nucleus B and the substituent groups may be further substituted, but not by carboxylic or sulphonic acid groups. The alkylene and alkyl groups may contain 1 to 4 C atoms. Exemplified anions (X-) are Cl<SP>1</SP>, Br<SP>1</SP>, ZnCl<SP>1</SP> 3 , SO<SP>11</SP> 4 , CH 3 COO<SP>1</SP>, CH 3 SO<SP>1</SP> 4 and PO<SP>111</SP> 4 . The dyes are prepared by coupling equal moles of The dyes are used to colour Tannin-mordanted cotton, cellulose acetate, and modified polyamide or polyester fibres, or polyacrylonitrile or its copolymers. Orange to violet shades are produced. On polyacrylonitrile fibres reddish shades of very good fastness are produced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB73172A GB1361542A (en) | 1973-01-05 | 1973-01-05 | Monoazo benzthiazole basic dyes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB73172A GB1361542A (en) | 1973-01-05 | 1973-01-05 | Monoazo benzthiazole basic dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1361542A true GB1361542A (en) | 1974-07-24 |
Family
ID=9709550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB73172A Expired GB1361542A (en) | 1973-01-05 | 1973-01-05 | Monoazo benzthiazole basic dyes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1361542A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2389662A1 (en) * | 1977-05-03 | 1978-12-01 | Ici Ltd |
-
1973
- 1973-01-05 GB GB73172A patent/GB1361542A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2389662A1 (en) * | 1977-05-03 | 1978-12-01 | Ici Ltd |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |