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GB1230142A - - Google Patents

Info

Publication number
GB1230142A
GB1230142A GB1230142DA GB1230142A GB 1230142 A GB1230142 A GB 1230142A GB 1230142D A GB1230142D A GB 1230142DA GB 1230142 A GB1230142 A GB 1230142A
Authority
GB
United Kingdom
Prior art keywords
hydrodesulphurization
sulphide
butane
propane
june
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1230142A publication Critical patent/GB1230142A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1,230,142. Hydrodesulphurization. ESSO RESEARCH & ENG. CO. 14 June, 1968 [26 June, 1967], No. 28368/68. Heading C5E. A process for the hydrodesulphurization of a sulphur-containing petroleum oil containing residual components comprises contacting said oil with hydrogen at mild hydrodesulphurization conditions in the presence of a porous hydrodesulphurization catalyst comprising an oxide and/or sulphide of nickel and/or cobalt and an oxide and/or sulphide of molybdenum and/or tungsten deposited on a support material comprising 1 to 6 weight per cent silica and 94 to 99 weight per cent alumina, the catalyst having a major portion of the pore volume and surface area in pores having diameters in the range 30 to 70 Š. The feedstock may be pretreated to remove metals by HF treatment or by solvent precipitation with propane, butane, mixtures of propane and butane, pentane, hexane or naphtha.
GB1230142D 1967-06-26 1968-06-14 Expired GB1230142A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US64860467A 1967-06-26 1967-06-26

Publications (1)

Publication Number Publication Date
GB1230142A true GB1230142A (en) 1971-04-28

Family

ID=24601480

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1230142D Expired GB1230142A (en) 1967-06-26 1968-06-14

Country Status (7)

Country Link
US (1) US3509044A (en)
JP (1) JPS4810364B1 (en)
BE (1) BE717161A (en)
DE (1) DE1770704C3 (en)
FR (1) FR1569510A (en)
GB (1) GB1230142A (en)
NL (1) NL158837B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2301703C1 (en) * 2006-03-15 2007-06-27 Открытое акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" Catalyst and oil stock hydrotreatment process utilizing it

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3509044A (en) * 1967-06-26 1970-04-28 Exxon Research Engineering Co Hydrodesulfurization of petroleum residuum
US3770618A (en) * 1967-06-26 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization of residua
US3658681A (en) * 1970-02-24 1972-04-25 Texaco Inc Production of low sulfur fuel oil
US3668116A (en) * 1970-10-16 1972-06-06 Exxon Research Engineering Co Slurry hydrodesulfurization of a heavy petroleum oil
US3691152A (en) * 1971-03-10 1972-09-12 Texaco Inc Hydrodesulfurization and blending of residue-containing petroleum oil
US3732155A (en) * 1971-03-31 1973-05-08 Exxon Research Engineering Co Two-stage hydrodesulfurization process with hydrogen addition in the first stage
DE2233943A1 (en) * 1971-07-14 1973-01-25 Exxon Research Engineering Co HYDRATION CATALYST, METHOD FOR MANUFACTURING IT AND ITS USE
GB1408759A (en) * 1971-12-07 1975-10-01 Shell Int Research Catalytic hydrodesulphurisation process
US3960712A (en) * 1973-04-30 1976-06-01 Universal Oil Products Company Hydrodesulfurization of asphaltene-containing black oil with a gamma-alumina composite catalyst of specified particle density
US4341625A (en) * 1973-08-09 1982-07-27 Chevron Research Company Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst
FR2247528A1 (en) 1973-10-12 1975-05-09 American Cyanamid Co Porous hydrotreating catalyst particles - with specified geometric and pore structure characteristics
GB1415417A (en) * 1973-10-12 1975-11-26 American Cyanamid Co Hydrotreating of petroleum distillates using shaped catalyst prtticles
JPS5652620B2 (en) * 1973-10-20 1981-12-14
DE2366459C2 (en) * 1973-10-31 1989-09-28 American Cyanamid Co., Wayne, N.J., Us
US3933623A (en) * 1974-08-09 1976-01-20 Texaco Inc. Desulfurization process
US4028227A (en) * 1974-09-24 1977-06-07 American Cyanamid Company Hydrotreating of petroleum residuum using shaped catalyst particles of small diameter pores
DE2730698A1 (en) * 1977-07-07 1979-01-18 Exxon Research Engineering Co Hydrodesulphurisation of oils contg. asphaltene cpds. - using catalyst on alumina carrier with specified pore size and distribution
US4366047A (en) * 1981-06-02 1982-12-28 Exxon Research And Engineering Co. Combination hydrorefining, heat-treating and hydrocracking process
US4513090A (en) * 1981-07-09 1985-04-23 Exxon Research And Engineering Co. Crystalline silica zeolite-containing catalyst
US4368113A (en) * 1981-08-31 1983-01-11 Exxon Research And Engineering Co. Hydrocarbon hydrocracking process
CA1221353A (en) * 1983-01-24 1987-05-05 Alfredo Morales Catalyst for the simultaneous demetallization and desulfurization of heavy hydrocarbon feedstocks
US4652545A (en) * 1985-05-06 1987-03-24 American Cyanamid Company Catalyst for hydroconversion of heavy oils and method of making the catalyst
US4634515A (en) * 1985-10-25 1987-01-06 Exxon Research And Engineering Company Nickel adsorbent for sulfur removal from hydrocarbon feeds
JPS62199687A (en) * 1986-04-28 1987-09-03 ユニオン・オイル・コンパニ−・オブ・カリフオルニア Hydrogenation using catalyst having large pores
US5851381A (en) * 1990-12-07 1998-12-22 Idemitsu Kosan Co., Ltd. Method of refining crude oil
US5210061A (en) * 1991-09-24 1993-05-11 Union Oil Company Of California Resid hydroprocessing catalyst
US6218333B1 (en) 1999-02-15 2001-04-17 Shell Oil Company Preparation of a hydrotreating catalyst
US6281158B1 (en) 1999-02-15 2001-08-28 Shell Oil Company Preparation of a co-containing hydrotreating catalyst precursor and catalyst
GB0817109D0 (en) * 2008-09-18 2008-10-29 Johnson Matthey Plc Catalyst and process

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2437533A (en) * 1942-12-24 1948-03-09 Union Oil Co Catalysts
US2760907A (en) * 1953-09-01 1956-08-28 Union Oil Co Hydrocarbon conversion process and catalyst
GB785158A (en) * 1954-12-21 1957-10-23 Exxon Research Engineering Co Methods of preparing hydrofining catalysts and processes for using same
US2890162A (en) * 1955-02-28 1959-06-09 Exxon Research Engineering Co Porous silica free gamma alumina base contacting agents and use thereof
US2983676A (en) * 1958-01-13 1961-05-09 Union Oil Co Hydrorefining of heavy mineral oils
US2988501A (en) * 1958-08-18 1961-06-13 Union Oil Co Hydrorefining of crude oils
US3020245A (en) * 1959-05-27 1962-02-06 Catalysts & Chem Inc Preparation of catalysts containing cobalt and molybdenum oxides
NL256096A (en) * 1959-09-21
US3169918A (en) * 1962-07-02 1965-02-16 Universal Oil Prod Co Hydrorefining heavy oils using a pseudo-dry catalyst
US3340180A (en) * 1964-08-25 1967-09-05 Gulf Research Development Co Hydrofining-hydrocracking process employing special alumina base catalysts
US3322666A (en) * 1964-08-25 1967-05-30 Gulf Research Development Co Chemical process for hydrocracking and hydrorefining of hydrocarbon oils
US3425934A (en) * 1965-02-23 1969-02-04 Chevron Res Catalytic refining with hydrogen
US3393148A (en) * 1965-11-30 1968-07-16 Standard Oil Co Hydrofining catalyst and process using same
US3509044A (en) * 1967-06-26 1970-04-28 Exxon Research Engineering Co Hydrodesulfurization of petroleum residuum

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2301703C1 (en) * 2006-03-15 2007-06-27 Открытое акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" Catalyst and oil stock hydrotreatment process utilizing it

Also Published As

Publication number Publication date
US3509044A (en) 1970-04-28
DE1770704B2 (en) 1980-10-09
DE1770704C3 (en) 1981-07-30
NL158837B (en) 1978-12-15
DE1770704A1 (en) 1971-12-09
NL6808924A (en) 1968-12-27
FR1569510A (en) 1969-05-30
JPS4810364B1 (en) 1973-04-03
BE717161A (en) 1968-12-27

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee