GB1216505A - Improvements in or relating to aromatic polyimides - Google Patents
Improvements in or relating to aromatic polyimidesInfo
- Publication number
- GB1216505A GB1216505A GB2615967A GB2615967A GB1216505A GB 1216505 A GB1216505 A GB 1216505A GB 2615967 A GB2615967 A GB 2615967A GB 2615967 A GB2615967 A GB 2615967A GB 1216505 A GB1216505 A GB 1216505A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- dianhydride
- dicarboxyphenyl
- aminophenyl
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004642 Polyimide Substances 0.000 title abstract 4
- 229920001721 polyimide Polymers 0.000 title abstract 4
- 125000003118 aryl group Chemical group 0.000 title abstract 3
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 150000004985 diamines Chemical class 0.000 abstract 2
- -1 1,7 - bis - (3,4 - dicarboxyphenyl) tetradecafluoroheptane Chemical compound 0.000 abstract 1
- SPXABFZECXRZBT-UHFFFAOYSA-N 3-[3-(3-aminophenyl)-1,1,2,2,3,3-hexafluoropropyl]aniline Chemical compound NC1=CC=CC(C(F)(F)C(F)(F)C(F)(F)C=2C=C(N)C=CC=2)=C1 SPXABFZECXRZBT-UHFFFAOYSA-N 0.000 abstract 1
- LQOWJPLHWGPMDB-UHFFFAOYSA-N 3-[5-(3-aminophenyl)-1,1,2,2,3,3,4,4,5,5-decafluoropentyl]aniline Chemical compound NC1=CC=CC(C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C=2C=C(N)C=CC=2)=C1 LQOWJPLHWGPMDB-UHFFFAOYSA-N 0.000 abstract 1
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 abstract 1
- YQRHQSXYASUCQL-UHFFFAOYSA-N 4-[3-(3,4-dicarboxyphenyl)-1,1,2,2,3,3-hexafluoropropyl]phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(F)(F)C(F)(F)C(F)(F)C1=CC=C(C(O)=O)C(C(O)=O)=C1 YQRHQSXYASUCQL-UHFFFAOYSA-N 0.000 abstract 1
- QQGYZOYWNCKGEK-UHFFFAOYSA-N 5-[(1,3-dioxo-2-benzofuran-5-yl)oxy]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(OC=2C=C3C(=O)OC(C3=CC=2)=O)=C1 QQGYZOYWNCKGEK-UHFFFAOYSA-N 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 125000006159 dianhydride group Chemical group 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
- C08G73/1071—Wholly aromatic polyimides containing oxygen in the form of ether bonds in the main chain
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
1,216,505. Aromatic polyimides. NATIONAL RESEARCH DEVELOPMENT CORP. 6 Sept., 1968 [6 June, 1967; 26 March, 1968], Nos. 26159/67 and 14590/68. Heading C3R. Novel aromatic polyimides contain repeating units of formula where X represents a direct link or a divalent atom or group and A has the formula where Y is a direct link or a divalent atom or group, at least one of X and Y being a straight chain polyfluoroalkylene group in which at least half of the replaceable hydrogen atoms are substituted by fluorine atoms. X and/or Y may be perfluoroalkylene and X or Y when not polyfluoroalkylene or a direct link may be -O- or -CO-. The polyimides are obtained by reacting diamines or their derivatives with aromatic tetracarboxylic acid dianhydrides or their derivatives with aromatic tetracarboxylic acid dianhydrides or their derivatives. In examples, diamines used are 1,5-bis-(3-aminophenyl) decafluoropentane, 1,3 - bis - (3 - aminophenyl) hexafluoropropane and bis-(4-aminophenyl) ether and the dianhydrides used are 1,3-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride, benzophenone 3,3<SP>1</SP>,4,4<SP>1</SP> - tetracarboxylic acid dianhydride, bis - (3,4 - dicarboxyphenyl) ether dianhydride and 1,7 - bis - (3,4 - dicarboxyphenyl) tetradecafluoroheptane dianhydride.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2615967A GB1216505A (en) | 1967-06-06 | 1967-06-06 | Improvements in or relating to aromatic polyimides |
| DE19681770585 DE1770585A1 (en) | 1967-06-06 | 1968-06-06 | Polyfluoroalkylene-containing polyimides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2615967A GB1216505A (en) | 1967-06-06 | 1967-06-06 | Improvements in or relating to aromatic polyimides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1216505A true GB1216505A (en) | 1970-12-23 |
Family
ID=10239299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2615967A Expired GB1216505A (en) | 1967-06-06 | 1967-06-06 | Improvements in or relating to aromatic polyimides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1216505A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1984002529A1 (en) * | 1982-12-20 | 1984-07-05 | Hughes Aircraft Co | Polyimide composition and method for protecting photoreactive cells |
| US4569988A (en) * | 1984-12-24 | 1986-02-11 | United Technologies Corporation | Polyimides of 4,4'-(hexafluoroisopropylidene)bis(o-phthalic anhydride) and aliphatic diamines |
| US4631335A (en) * | 1984-12-24 | 1986-12-23 | United Technologies Corporation | Polyimide of alkylene diamine and 4,4'(hexafluoroisopropylidene)bis(o-phthalic anhydride) |
| US4742152A (en) * | 1986-05-27 | 1988-05-03 | United Technologies Corporation | High temperature fluorinated polyimides |
| US4758380A (en) * | 1986-10-29 | 1988-07-19 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Substituted 1,1,1-triaryl-2,2,2-trifluoroethanes and processes for their synthesis |
| US4801682A (en) * | 1986-05-27 | 1989-01-31 | United Technologies Corporation | High temperature fluorinated polymer |
| US4863640A (en) * | 1986-05-27 | 1989-09-05 | United Technologies Corporation | Monomers for high temperature fluorinated polyimides |
| US4871833A (en) * | 1986-05-03 | 1989-10-03 | Hoechst Aktiengesellschaft | Polyamic acids, polyimides prepared from these and process for producing high-temperature resistant layers |
| US5070181A (en) * | 1987-03-09 | 1991-12-03 | Kanegafuchi Chemical Ind. Co., Ltd. | Polyimide film |
| US5298601A (en) * | 1992-12-04 | 1994-03-29 | United Technologies Corporation | High temperature 3f-polyimides |
| US5298600A (en) * | 1992-12-04 | 1994-03-29 | United Technologies Corporation | Fluorinated condensation copolyimides |
| WO2022175168A1 (en) * | 2021-02-16 | 2022-08-25 | Solvay Specialty Polymers Italy S.P.A. | Polyimides having low dielectric loss |
| EP4151614A4 (en) * | 2020-05-11 | 2024-05-22 | Daikin Industries, Ltd. | FLUORINATED AMIDE COMPOUND, COMPOUND HAVING A FLUORINATED NITROGEN-CONTAINING HETEROCYCLIC RING AND FLUORINATED COMPOUND |
| EP4151672A4 (en) * | 2020-05-11 | 2024-05-29 | Daikin Industries, Ltd. | AMIDE COMPOUND, COMPOUND COMPRISING A HETEROCYCLE WITH NITROGEN CONTENT, AND CROSS-LINKED PRODUCT |
-
1967
- 1967-06-06 GB GB2615967A patent/GB1216505A/en not_active Expired
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1984002529A1 (en) * | 1982-12-20 | 1984-07-05 | Hughes Aircraft Co | Polyimide composition and method for protecting photoreactive cells |
| US4569988A (en) * | 1984-12-24 | 1986-02-11 | United Technologies Corporation | Polyimides of 4,4'-(hexafluoroisopropylidene)bis(o-phthalic anhydride) and aliphatic diamines |
| US4631335A (en) * | 1984-12-24 | 1986-12-23 | United Technologies Corporation | Polyimide of alkylene diamine and 4,4'(hexafluoroisopropylidene)bis(o-phthalic anhydride) |
| US4871833A (en) * | 1986-05-03 | 1989-10-03 | Hoechst Aktiengesellschaft | Polyamic acids, polyimides prepared from these and process for producing high-temperature resistant layers |
| US4863640A (en) * | 1986-05-27 | 1989-09-05 | United Technologies Corporation | Monomers for high temperature fluorinated polyimides |
| US4801682A (en) * | 1986-05-27 | 1989-01-31 | United Technologies Corporation | High temperature fluorinated polymer |
| US4742152A (en) * | 1986-05-27 | 1988-05-03 | United Technologies Corporation | High temperature fluorinated polyimides |
| US4758380A (en) * | 1986-10-29 | 1988-07-19 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Substituted 1,1,1-triaryl-2,2,2-trifluoroethanes and processes for their synthesis |
| US5070181A (en) * | 1987-03-09 | 1991-12-03 | Kanegafuchi Chemical Ind. Co., Ltd. | Polyimide film |
| US5298601A (en) * | 1992-12-04 | 1994-03-29 | United Technologies Corporation | High temperature 3f-polyimides |
| US5298600A (en) * | 1992-12-04 | 1994-03-29 | United Technologies Corporation | Fluorinated condensation copolyimides |
| EP4151614A4 (en) * | 2020-05-11 | 2024-05-22 | Daikin Industries, Ltd. | FLUORINATED AMIDE COMPOUND, COMPOUND HAVING A FLUORINATED NITROGEN-CONTAINING HETEROCYCLIC RING AND FLUORINATED COMPOUND |
| EP4151672A4 (en) * | 2020-05-11 | 2024-05-29 | Daikin Industries, Ltd. | AMIDE COMPOUND, COMPOUND COMPRISING A HETEROCYCLE WITH NITROGEN CONTENT, AND CROSS-LINKED PRODUCT |
| WO2022175168A1 (en) * | 2021-02-16 | 2022-08-25 | Solvay Specialty Polymers Italy S.P.A. | Polyimides having low dielectric loss |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |