GB1213122A - Clays - Google Patents
ClaysInfo
- Publication number
- GB1213122A GB1213122A GB4068566A GB4068566A GB1213122A GB 1213122 A GB1213122 A GB 1213122A GB 4068566 A GB4068566 A GB 4068566A GB 4068566 A GB4068566 A GB 4068566A GB 1213122 A GB1213122 A GB 1213122A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ammonium
- clay
- octadecyl
- ions
- minerals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 3
- 239000011707 mineral Substances 0.000 abstract 3
- -1 sulphonium ions Chemical class 0.000 abstract 3
- 150000002892 organic cations Chemical class 0.000 abstract 2
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 abstract 1
- AGCSGEARWLNPEG-UHFFFAOYSA-N 2-octadecyl-1-propyl-4,5-dihydroimidazole Chemical compound C(CCCCCCCCCCCCCCCCC)C=1N(CCN=1)CCC AGCSGEARWLNPEG-UHFFFAOYSA-N 0.000 abstract 1
- UHTYDBXZOHSDIA-UHFFFAOYSA-N 4,4-dioctadecylmorpholin-4-ium Chemical compound CCCCCCCCCCCCCCCCCC[N+]1(CCCCCCCCCCCCCCCCCC)CCOCC1 UHTYDBXZOHSDIA-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical compound [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-O dodecylazanium Chemical compound CCCCCCCCCCCC[NH3+] JRBPAEWTRLWTQC-UHFFFAOYSA-O 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- HISNRBVYBOVKMB-UHFFFAOYSA-N stibonium Chemical compound [SbH4+] HISNRBVYBOVKMB-UHFFFAOYSA-N 0.000 abstract 1
- 239000008399 tap water Substances 0.000 abstract 1
- 235000020679 tap water Nutrition 0.000 abstract 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/40—Clays
- C01B33/405—Clays not containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Lubricants (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
1,213,122. Synthetic clay-like minerals. LAPORTE INDUSTRIES Ltd. 11 Dec., 1967 [12 Sept., 1966(3)], Nos. 40683/66, 40684/66 and 40685/66. Heading C1A. [Also in Divisions C3and.C5] A process for the production of a clay-like mineral having the empirical formula given below comprises precipitating a magnesium silicate from a solution containing the cations and anions required to be present in the clay, maintaining a pH of at least 8 throughout, and, without washing free from soluble salts, heating the precipitated product under pressure to bring about crystal growth. Synthetic clay-like minerals of the following empirical formula, having a cation exchange capacity of 50 to 120 m.e.g./100 g. and when M is Na+ or Li+ a Bingham Yield Value of from 40 to 250 dynes/ cm.<SP>2</SP> as a 2% w./v. dispersion in tap water, are claimed per se: where M is a sodium, lithium or an equivalent of an organic cation and the values of a, b and c such that either a<6; b > 0 ; c>0 and b + c < 2 ; Œ(o+b+c-6)<2; or a<6; b=0; Œc<2 and Œ(a+b - 6) < 2. Preferred values of a and b are b= 06to 1.05 or, when b=0a=4À5 to 5À9, preferably 5-0 to 5-8. The organic cations may be ammonium, phosphonium, stibonium, arsonium, oxonium or sulphonium ions but are preferably ammonium ions having at least 10 carbon atoms preferably at least 18 and preferred examples are, dimethyl dioctadecyl ammonium, trimethyl octadecyl ammonium, dodecyl ammonium, hexadecyl ammonium, dioctadecyl morpholinium, 1 - propyl - 2 - octadecyl imidazolinium and bis-(2-hydroxyethyl) octadecyl ammonium ions, these may be used singly or in combinations. The clays may be used in making lubricating greases or organosols, they may also be used to form refractory articles.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4068566A GB1213122A (en) | 1966-09-12 | 1966-09-12 | Clays |
| GB1228155D GB1228155A (en) | 1966-09-12 | 1967-04-04 | |
| DK453667A DK135035B (en) | 1966-09-12 | 1967-09-11 | Synthetic magnesium silicate and process for its synthesis. |
| NO169699A NO122012B (en) | 1966-09-12 | 1967-09-11 | |
| BE703698D BE703698A (en) | 1966-09-12 | 1967-09-11 | |
| AT835267A AT283271B (en) | 1966-09-12 | 1967-09-12 | Process for the synthesis of a new, clay-like, aqueous magnesium silicate mineral |
| DE1667502A DE1667502B2 (en) | 1966-09-12 | 1967-09-12 | Synthetic, swellable, clay-like material |
| NL6712477A NL156115B (en) | 1966-09-12 | 1967-09-12 | PROCESS FOR PREPARING A SYNTHETIC CLAY. |
| SE1259267A SE330156B (en) | 1966-09-12 | 1967-09-12 | |
| CH1271667A CH483373A (en) | 1966-09-12 | 1967-09-12 | Synthesis process of a clay mineral |
| FR1565348D FR1565348A (en) | 1966-09-12 | 1967-09-12 | |
| SE498/70A SE343280B (en) | 1966-09-12 | 1970-01-15 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4068566A GB1213122A (en) | 1966-09-12 | 1966-09-12 | Clays |
| GB4068466 | 1966-09-12 | ||
| GB4068366 | 1966-09-12 | ||
| GB1534367 | 1967-04-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1213122A true GB1213122A (en) | 1970-11-18 |
Family
ID=27448305
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4068566A Expired GB1213122A (en) | 1966-09-12 | 1966-09-12 | Clays |
| GB1228155D Expired GB1228155A (en) | 1966-09-12 | 1967-04-04 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1228155D Expired GB1228155A (en) | 1966-09-12 | 1967-04-04 |
Country Status (10)
| Country | Link |
|---|---|
| AT (1) | AT283271B (en) |
| BE (1) | BE703698A (en) |
| CH (1) | CH483373A (en) |
| DE (1) | DE1667502B2 (en) |
| DK (1) | DK135035B (en) |
| FR (1) | FR1565348A (en) |
| GB (2) | GB1213122A (en) |
| NL (1) | NL156115B (en) |
| NO (1) | NO122012B (en) |
| SE (2) | SE330156B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049780A (en) * | 1972-11-14 | 1977-09-20 | Laporte Industries Limited | Production of magnesium silicates |
| WO1994016996A1 (en) * | 1993-01-26 | 1994-08-04 | Laporte Industries Limited | Synthetic clay minerals |
| US6274111B1 (en) | 1997-07-01 | 2001-08-14 | Clariant Gmbh | Synthetic magnesium silicate |
| WO2004000729A1 (en) * | 2002-06-21 | 2003-12-31 | Rockwood Additives Limited | Synthetic magnesium silicate compositions and process for the production thereof |
| EP1393924A2 (en) | 2002-08-27 | 2004-03-03 | Eastman Kodak Company | Ink jet printing process |
| US6730719B2 (en) | 1999-04-28 | 2004-05-04 | Southern Clay Products, Inc. | Process for treating smectite clays to facilitate exfoliation |
| WO2004056704A1 (en) * | 2002-12-20 | 2004-07-08 | Rockwood Additives Limited | Process for the production of synthetic magnesium silicate compositions |
| GB2401103A (en) * | 2003-04-29 | 2004-11-03 | Rockwood Additives Ltd | Synthetic magnesium silicate compositions, methods and uses |
| US6849680B2 (en) | 2001-03-02 | 2005-02-01 | Southern Clay Products, Inc. | Preparation of polymer nanocomposites by dispersion destabilization |
| US6890502B2 (en) | 2001-08-24 | 2005-05-10 | Southern Clay Products, Inc. | Synthetic clay compositions and methods for making and using |
| EP1702887A4 (en) * | 2003-09-18 | 2009-03-11 | Teijin Ltd | Phyllosilicate and thermoplastic resin composition containing the same |
| RU2440295C2 (en) * | 2007-03-16 | 2012-01-20 | Шайонано Сингапур Пте Лтд | Clay particle synthesis process |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1432770A (en) * | 1972-11-14 | 1976-04-22 | Laporte Industries Ltd | Production of magnesium silicates |
| DE3207886A1 (en) * | 1982-03-05 | 1983-09-15 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING A SYNTHETIC HECTORITE |
| DE3526405A1 (en) * | 1985-07-24 | 1987-02-05 | Henkel Kgaa | LAYERED SILICATES WITH RESTRICTED SOURCE, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN DETERGENT AND CLEANING AGENTS |
| DE3631764A1 (en) | 1986-09-18 | 1988-03-24 | Henkel Kgaa | USE OF SWELLABLE, SYNTHETIC LAYERED SILICATES IN AQUEOUS DRILL RING AND HOLE TREATMENT AGENTS |
| TW223043B (en) * | 1991-11-30 | 1994-05-01 | Laporte Industries Ltd | |
| DE4224537A1 (en) * | 1992-07-27 | 1994-02-03 | Henkel Kgaa | Mineral additives for adjusting and / or regulating the rheology and gel structure of aqueous liquid phases and their use |
| GB9500089D0 (en) * | 1995-01-04 | 1995-03-01 | Sofitech Nv | Thixotropic materials |
-
1966
- 1966-09-12 GB GB4068566A patent/GB1213122A/en not_active Expired
-
1967
- 1967-04-04 GB GB1228155D patent/GB1228155A/en not_active Expired
- 1967-09-11 NO NO169699A patent/NO122012B/no unknown
- 1967-09-11 BE BE703698D patent/BE703698A/xx unknown
- 1967-09-11 DK DK453667A patent/DK135035B/en unknown
- 1967-09-12 FR FR1565348D patent/FR1565348A/fr not_active Expired
- 1967-09-12 SE SE1259267A patent/SE330156B/xx unknown
- 1967-09-12 NL NL6712477A patent/NL156115B/en not_active IP Right Cessation
- 1967-09-12 DE DE1667502A patent/DE1667502B2/en not_active Withdrawn
- 1967-09-12 CH CH1271667A patent/CH483373A/en not_active IP Right Cessation
- 1967-09-12 AT AT835267A patent/AT283271B/en not_active IP Right Cessation
-
1970
- 1970-01-15 SE SE498/70A patent/SE343280B/xx unknown
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049780A (en) * | 1972-11-14 | 1977-09-20 | Laporte Industries Limited | Production of magnesium silicates |
| WO1994016996A1 (en) * | 1993-01-26 | 1994-08-04 | Laporte Industries Limited | Synthetic clay minerals |
| US6274111B1 (en) | 1997-07-01 | 2001-08-14 | Clariant Gmbh | Synthetic magnesium silicate |
| US6730719B2 (en) | 1999-04-28 | 2004-05-04 | Southern Clay Products, Inc. | Process for treating smectite clays to facilitate exfoliation |
| US6849680B2 (en) | 2001-03-02 | 2005-02-01 | Southern Clay Products, Inc. | Preparation of polymer nanocomposites by dispersion destabilization |
| US6890502B2 (en) | 2001-08-24 | 2005-05-10 | Southern Clay Products, Inc. | Synthetic clay compositions and methods for making and using |
| WO2004000729A1 (en) * | 2002-06-21 | 2003-12-31 | Rockwood Additives Limited | Synthetic magnesium silicate compositions and process for the production thereof |
| EP1393924A2 (en) | 2002-08-27 | 2004-03-03 | Eastman Kodak Company | Ink jet printing process |
| WO2004056704A1 (en) * | 2002-12-20 | 2004-07-08 | Rockwood Additives Limited | Process for the production of synthetic magnesium silicate compositions |
| GB2401103A (en) * | 2003-04-29 | 2004-11-03 | Rockwood Additives Ltd | Synthetic magnesium silicate compositions, methods and uses |
| EP1702887A4 (en) * | 2003-09-18 | 2009-03-11 | Teijin Ltd | Phyllosilicate and thermoplastic resin composition containing the same |
| US7759420B2 (en) | 2003-09-18 | 2010-07-20 | Teijin Limited | Layered silicate and thermoplastic resin composition containing it |
| RU2440295C2 (en) * | 2007-03-16 | 2012-01-20 | Шайонано Сингапур Пте Лтд | Clay particle synthesis process |
Also Published As
| Publication number | Publication date |
|---|---|
| DK135035C (en) | 1977-09-12 |
| SE330156B (en) | 1970-11-09 |
| DE1667502A1 (en) | 1971-06-16 |
| BE703698A (en) | 1968-03-11 |
| DE1667502B2 (en) | 1978-10-26 |
| NL156115B (en) | 1978-03-15 |
| CH483373A (en) | 1969-12-31 |
| NO122012B (en) | 1971-05-10 |
| NL6712477A (en) | 1968-03-13 |
| FR1565348A (en) | 1969-05-02 |
| GB1228155A (en) | 1971-04-15 |
| DK135035B (en) | 1977-02-28 |
| AT283271B (en) | 1970-07-27 |
| SE343280B (en) | 1972-03-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |