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GB1204970A - Production of a fluorophenyl salicylic acid derivative - Google Patents

Production of a fluorophenyl salicylic acid derivative

Info

Publication number
GB1204970A
GB1204970A GB38482/68A GB3848268A GB1204970A GB 1204970 A GB1204970 A GB 1204970A GB 38482/68 A GB38482/68 A GB 38482/68A GB 3848268 A GB3848268 A GB 3848268A GB 1204970 A GB1204970 A GB 1204970A
Authority
GB
United Kingdom
Prior art keywords
acetyl
fluorophenyl
salicylic acid
chloride
aug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38482/68A
Inventor
Erwin Frederick Schoenewaldt
George Gustave Hazen
Richard Ferris Shuman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck and Co Inc
Original Assignee
Merck and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck and Co Inc filed Critical Merck and Co Inc
Publication of GB1204970A publication Critical patent/GB1204970A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/60Salicylic acid; Derivatives thereof
    • A61K31/612Salicylic acid; Derivatives thereof having the hydroxy group in position 2 esterified, e.g. salicylsulfuric acid
    • A61K31/616Salicylic acid; Derivatives thereof having the hydroxy group in position 2 esterified, e.g. salicylsulfuric acid by carboxylic acids, e.g. acetylsalicylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/84Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
    • C07C69/86Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with esterified hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/94Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of polycyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Bag Frames (AREA)

Abstract

1,204,970. O-Acetyl-5-(4-fluorophenyl) salicylic acid. MERCK & CO. Inc. 12 Aug., 1968 [14 Aug., 1967], No. 38482/68. Heading C2C. O - Acetyl - 5 - (4 - fluorophenyl) salicylic acid is prepared by reacting 5-(4-fluorophenyl) salicylic acid with an agent capable of forming an acetyl radical which is reactive with phenolic hydroxyl groups or with a phenol derivative capable of providing the phenoxy radical. Preferred acetylating agents are acetic anhydride, acetyl chloride, acetyl bromide, acetic propionic anhydride; and isopropenyl acetate. Other agents have the formula CH 3 COX, where X is I, F, N 3 , phenoxy, 2,4-dinitrophenoxy, phenylmercapto, p-nitrophenylmercapto, imidazolyl, alkoxy, hydroxy, carbodiimidoxyl, α,#-unsaturated alkenoxy, aliphatic acyloxy, organophosphato, dialkyl arseno, sulphonoxy, cyanoalkoxy, N-methyl pyrroliniumoxy chloride and N,N-dimethyliminiumacetoxy chloride. The reaction may be effected in presence or absence of acidic or basic catalysts.
GB38482/68A 1967-08-14 1968-08-12 Production of a fluorophenyl salicylic acid derivative Expired GB1204970A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA997829 1967-08-14

Publications (1)

Publication Number Publication Date
GB1204970A true GB1204970A (en) 1970-09-09

Family

ID=4142993

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38482/68A Expired GB1204970A (en) 1967-08-14 1968-08-12 Production of a fluorophenyl salicylic acid derivative

Country Status (14)

Country Link
AT (1) AT283339B (en)
BE (1) BE719415A (en)
CH (1) CH500158A (en)
DE (1) DE1793121A1 (en)
ES (1) ES357104A1 (en)
FI (1) FI49152C (en)
FR (1) FR1589699A (en)
GB (1) GB1204970A (en)
IE (1) IE32261B1 (en)
IL (1) IL30497A0 (en)
NL (1) NL6811554A (en)
NO (1) NO123846B (en)
SE (1) SE353713B (en)
YU (1) YU32384B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4068082A (en) * 1971-03-02 1978-01-10 Lee Pharmaceuticals Process for preparing esters

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4068082A (en) * 1971-03-02 1978-01-10 Lee Pharmaceuticals Process for preparing esters

Also Published As

Publication number Publication date
FR1589699A (en) 1970-04-06
ES357104A1 (en) 1970-02-16
NO123846B (en) 1972-01-24
FI49152C (en) 1975-04-10
IE32261L (en) 1969-02-14
IE32261B1 (en) 1973-05-30
AT283339B (en) 1970-08-10
YU32384B (en) 1974-10-31
SE353713B (en) 1973-02-12
FI49152B (en) 1974-12-31
IL30497A0 (en) 1968-10-24
BE719415A (en) 1969-02-13
DE1793121A1 (en) 1971-12-23
NL6811554A (en) 1969-02-18
CH500158A (en) 1970-12-15
YU187768A (en) 1974-04-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees