GB1292025A - Improvements in or relating to the separation of hydrogen from gaseous mixtures containing hydrogen - Google Patents
Improvements in or relating to the separation of hydrogen from gaseous mixtures containing hydrogenInfo
- Publication number
- GB1292025A GB1292025A GB49552/68A GB4955268A GB1292025A GB 1292025 A GB1292025 A GB 1292025A GB 49552/68 A GB49552/68 A GB 49552/68A GB 4955268 A GB4955268 A GB 4955268A GB 1292025 A GB1292025 A GB 1292025A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- separation
- alloy
- relating
- discontinuous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 4
- 239000001257 hydrogen Substances 0.000 title abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 4
- 239000008246 gaseous mixture Substances 0.000 title abstract 2
- 238000000926 separation method Methods 0.000 title abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 5
- 229910045601 alloy Inorganic materials 0.000 abstract 4
- 239000000956 alloy Substances 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 238000009792 diffusion process Methods 0.000 abstract 2
- 238000004070 electrodeposition Methods 0.000 abstract 2
- 239000012528 membrane Substances 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 229910001316 Ag alloy Inorganic materials 0.000 abstract 1
- 229910001252 Pd alloy Inorganic materials 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0053—Inorganic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0055—Inorganic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02232—Nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
- C01B3/505—Membranes containing palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
1292025 Pd base alloys, electro-deposition of Pd and alloys thereof JOHNSON MATTHEY & CO Ltd 20 Oct 1969 [18 Oct 1968] 49552/68 Headings C7A and C7B [Also in Division B1] A hydrogen diffusion membrane or tube used in the separation of hydrogen from a gaseous mixture or in the purification of hydrogen gas comprises an imperforate substrate of nickel, iron, vanadium, tantalum or niobium metal or an alloy containing one or more of these metals, the substrate being coated on both sides with a film of palladium or an alloy thereof e.g. 10-40% Ag which is discontinuous or porous, or both discontinuous and porous. The coating may be applied by printing techniques, electro-deposition or metal spraying. The membrane or tube may replace the Pd/Ag alloy diffusion element in the preparation of heavy water as described in Specification 973820.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49552/68A GB1292025A (en) | 1968-10-18 | 1968-10-18 | Improvements in or relating to the separation of hydrogen from gaseous mixtures containing hydrogen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49552/68A GB1292025A (en) | 1968-10-18 | 1968-10-18 | Improvements in or relating to the separation of hydrogen from gaseous mixtures containing hydrogen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1292025A true GB1292025A (en) | 1972-10-11 |
Family
ID=10452720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB49552/68A Expired GB1292025A (en) | 1968-10-18 | 1968-10-18 | Improvements in or relating to the separation of hydrogen from gaseous mixtures containing hydrogen |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1292025A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3149084A1 (en) * | 1981-12-11 | 1983-06-23 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Hydrogen diffusion membrane |
| US4496373A (en) * | 1981-12-11 | 1985-01-29 | Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung | Diffusion membrane and process for separating hydrogen from gas mixture |
| US4589891A (en) * | 1983-09-08 | 1986-05-20 | Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung | Hydrogen permeatin membrane, process for its manufacture and use |
| US4857080A (en) * | 1987-12-02 | 1989-08-15 | Membrane Technology & Research, Inc. | Ultrathin composite metal membranes |
| EP0470822A1 (en) * | 1990-08-10 | 1992-02-12 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane |
| WO1996040413A1 (en) * | 1995-06-07 | 1996-12-19 | The Regents Of The University Of California | Composite metal membrane |
| WO2000078434A1 (en) * | 1999-06-18 | 2000-12-28 | The Regents Of The University Of California | Thermally tolerant multilayer metal membrane |
| US6461408B2 (en) * | 1995-11-06 | 2002-10-08 | Robert E. Buxbaum | Hydrogen generator |
| US6503348B1 (en) | 1997-09-03 | 2003-01-07 | Ballard Power Systems Ag | Method of making a metal membrane foil made of a palladium alloy for hydrogen separation |
| US6541676B1 (en) * | 1998-12-02 | 2003-04-01 | Massachusetts Institute Of Technology | Integrated palladium-based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions |
| US6649559B2 (en) | 2000-08-12 | 2003-11-18 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Supported metal membrane, a process for its preparation and use |
| US6800392B2 (en) * | 2000-11-16 | 2004-10-05 | W. C. Heraeus Gmbh & Co. Kg | Niobium alloy and hydrogen permeation membrane produced from it |
| WO2006107710A3 (en) * | 2005-04-02 | 2007-04-05 | Bp Corp North America Inc | Hydrogen separation |
| US20150251905A1 (en) * | 2014-03-07 | 2015-09-10 | Stellar Generation, Inc. | Separating Hydrogen From Disassociated Water |
| AT15581U1 (en) * | 2016-12-09 | 2018-03-15 | Plansee Se | membrane tube |
| CN115069093A (en) * | 2016-06-06 | 2022-09-20 | 联邦科学和工业研究组织 | Method for forming Pd-Au alloy layer on substrate |
-
1968
- 1968-10-18 GB GB49552/68A patent/GB1292025A/en not_active Expired
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3149084A1 (en) * | 1981-12-11 | 1983-06-23 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Hydrogen diffusion membrane |
| US4496373A (en) * | 1981-12-11 | 1985-01-29 | Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung | Diffusion membrane and process for separating hydrogen from gas mixture |
| US4589891A (en) * | 1983-09-08 | 1986-05-20 | Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung | Hydrogen permeatin membrane, process for its manufacture and use |
| EP0141176A3 (en) * | 1983-09-08 | 1988-04-27 | Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung | Permeable membrane for hydrogen, its manufacturing method and use |
| US4857080A (en) * | 1987-12-02 | 1989-08-15 | Membrane Technology & Research, Inc. | Ultrathin composite metal membranes |
| EP0470822A1 (en) * | 1990-08-10 | 1992-02-12 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane |
| WO1996040413A1 (en) * | 1995-06-07 | 1996-12-19 | The Regents Of The University Of California | Composite metal membrane |
| US5738708A (en) * | 1995-06-07 | 1998-04-14 | The Regents Of The University Of California Office Of Technology Transfer | Composite metal membrane |
| US6461408B2 (en) * | 1995-11-06 | 2002-10-08 | Robert E. Buxbaum | Hydrogen generator |
| US6503348B1 (en) | 1997-09-03 | 2003-01-07 | Ballard Power Systems Ag | Method of making a metal membrane foil made of a palladium alloy for hydrogen separation |
| US6810899B2 (en) | 1998-12-02 | 2004-11-02 | Massachusetts Institute Of Technology | Integrated palladium-based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions |
| US6541676B1 (en) * | 1998-12-02 | 2003-04-01 | Massachusetts Institute Of Technology | Integrated palladium-based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions |
| WO2000078434A1 (en) * | 1999-06-18 | 2000-12-28 | The Regents Of The University Of California | Thermally tolerant multilayer metal membrane |
| US6214090B1 (en) * | 1999-06-18 | 2001-04-10 | The Regents Of The University Of California | Thermally tolerant multilayer metal membrane |
| US6649559B2 (en) | 2000-08-12 | 2003-11-18 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Supported metal membrane, a process for its preparation and use |
| US6800392B2 (en) * | 2000-11-16 | 2004-10-05 | W. C. Heraeus Gmbh & Co. Kg | Niobium alloy and hydrogen permeation membrane produced from it |
| WO2006107710A3 (en) * | 2005-04-02 | 2007-04-05 | Bp Corp North America Inc | Hydrogen separation |
| US20150251905A1 (en) * | 2014-03-07 | 2015-09-10 | Stellar Generation, Inc. | Separating Hydrogen From Disassociated Water |
| US9321644B2 (en) * | 2014-03-07 | 2016-04-26 | Stellar Generation, Inc. | Separating hydrogen from disassociated water |
| AU2015226879B2 (en) * | 2014-03-07 | 2016-12-08 | Stellar Generation, Inc. | Separating hydrogen from disassociated water |
| US10259706B2 (en) | 2014-03-07 | 2019-04-16 | Stellar Generation, Inc. | Separating hydrogen from disassociated water |
| CN115069093A (en) * | 2016-06-06 | 2022-09-20 | 联邦科学和工业研究组织 | Method for forming Pd-Au alloy layer on substrate |
| AT15581U1 (en) * | 2016-12-09 | 2018-03-15 | Plansee Se | membrane tube |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |