GB1269068A - Process for the polymerization and copolymerization of olefins - Google Patents
Process for the polymerization and copolymerization of olefinsInfo
- Publication number
- GB1269068A GB1269068A GB4511771A GB4511771A GB1269068A GB 1269068 A GB1269068 A GB 1269068A GB 4511771 A GB4511771 A GB 4511771A GB 4511771 A GB4511771 A GB 4511771A GB 1269068 A GB1269068 A GB 1269068A
- Authority
- GB
- United Kingdom
- Prior art keywords
- product
- homo
- aug
- molecular weight
- achieve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
1,269,068. Product control in supported catalytic olefin polymerization. SOLVAY & CIE. 1 Aug., 1969 [26 Aug., 1968], No. 45117/71. Divided out of 1,269,067. Heading C3P. Olefins are homo- or co-polymerized in the presence of hydrogen and a catalytic system comprising the reaction product of a halogencontaining transition metal compound and a solid support activated by an organometallic compound to form a product having a melt index (M.I.) of at least 4 g./10 min. and a narrow molecular weight distribution (C D less than 10), the process being carried out at a hydrogen concentration of 10 to 20 gms. per kg of olefin (to achieve said M.I.) and with control of temperature (85‹ to 120‹ C.) and/or a molecular weight decreasing agent (to achieve said C D ). The support or activator may also be modified to influence these properties. In examples (mostly comparison), ethylene is homo- or copolymerized with butene-1 in the presence of (C 2 H 5 ) 3 Al or (i-C 4 H 9 ) 3 Al/TiCl 4 -MgO or hydromagnesite/H 2 and optionally octanol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR164128 | 1968-08-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1269068A true GB1269068A (en) | 1972-03-29 |
Family
ID=8654008
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3863569A Expired GB1269067A (en) | 1968-08-26 | 1969-08-01 | Process for the polymerization and copolymerization of olefins |
| GB4511771A Expired GB1269068A (en) | 1968-08-26 | 1969-08-01 | Process for the polymerization and copolymerization of olefins |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3863569A Expired GB1269067A (en) | 1968-08-26 | 1969-08-01 | Process for the polymerization and copolymerization of olefins |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS4837753B1 (en) |
| AT (1) | AT312278B (en) |
| BE (1) | BE737643A (en) |
| BR (1) | BR6911488D0 (en) |
| CH (1) | CH513216A (en) |
| CS (1) | CS167250B2 (en) |
| DE (1) | DE1938461A1 (en) |
| DK (1) | DK124761B (en) |
| ES (1) | ES369932A1 (en) |
| FR (1) | FR1582942A (en) |
| GB (2) | GB1269067A (en) |
| IE (1) | IE33193B1 (en) |
| NL (1) | NL6911629A (en) |
| NO (1) | NO131678C (en) |
| PL (1) | PL80207B1 (en) |
| RO (1) | RO55763A (en) |
| SE (1) | SE382067B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0003159A1 (en) * | 1978-01-06 | 1979-07-25 | Du Pont Canada Inc. | Ethylene copolymers with a high melt index and manufacture of containers with these |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2126725C3 (en) * | 1970-05-29 | 1983-04-21 | Mitsui Petrochemical Industries Ltd., Tokyo | Process for the production of a modified polyethylene wax |
| DE2630262C2 (en) * | 1976-07-06 | 1985-01-03 | Ruhrchemie Ag, 4200 Oberhausen | Process for the production of polyolefins |
| IT1141068B (en) * | 1979-09-26 | 1986-10-01 | Nippon Oil Co Ltd | POLYOLEFIN PREPARATION PROCEDURE |
| US4342855A (en) * | 1980-08-27 | 1982-08-03 | Idemitsu Kosan Company Limited | Process for the production of polyethylene |
-
1968
- 1968-08-26 FR FR1582942D patent/FR1582942A/fr not_active Expired
-
1969
- 1969-07-04 IE IE91969A patent/IE33193B1/en unknown
- 1969-07-22 CH CH1120169A patent/CH513216A/en not_active IP Right Cessation
- 1969-07-25 NO NO308869A patent/NO131678C/no unknown
- 1969-07-26 ES ES369932A patent/ES369932A1/en not_active Expired
- 1969-07-29 DE DE19691938461 patent/DE1938461A1/en active Pending
- 1969-07-30 NL NL6911629A patent/NL6911629A/xx unknown
- 1969-08-01 GB GB3863569A patent/GB1269067A/en not_active Expired
- 1969-08-01 GB GB4511771A patent/GB1269068A/en not_active Expired
- 1969-08-04 JP JP6110969A patent/JPS4837753B1/ja active Pending
- 1969-08-07 AT AT762569A patent/AT312278B/en active
- 1969-08-13 BR BR21148869A patent/BR6911488D0/en unknown
- 1969-08-19 BE BE737643D patent/BE737643A/xx unknown
- 1969-08-20 RO RO6085269A patent/RO55763A/ro unknown
- 1969-08-22 DK DK451569A patent/DK124761B/en unknown
- 1969-08-25 SE SE1177869A patent/SE382067B/en unknown
- 1969-08-25 PL PL13550569A patent/PL80207B1/pl unknown
- 1969-08-26 CS CS585069A patent/CS167250B2/cs unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0003159A1 (en) * | 1978-01-06 | 1979-07-25 | Du Pont Canada Inc. | Ethylene copolymers with a high melt index and manufacture of containers with these |
Also Published As
| Publication number | Publication date |
|---|---|
| BR6911488D0 (en) | 1973-01-09 |
| IE33193L (en) | 1970-02-26 |
| DK124761B (en) | 1972-11-20 |
| CS167250B2 (en) | 1976-04-29 |
| ES369932A1 (en) | 1971-06-16 |
| SE382067B (en) | 1976-01-12 |
| DE1938461A1 (en) | 1970-05-06 |
| FR1582942A (en) | 1969-10-10 |
| GB1269067A (en) | 1972-03-29 |
| AT312278B (en) | 1973-12-27 |
| JPS4837753B1 (en) | 1973-11-13 |
| IE33193B1 (en) | 1974-04-17 |
| PL80207B1 (en) | 1975-08-30 |
| BE737643A (en) | 1970-02-19 |
| NO131678C (en) | 1975-07-09 |
| NL6911629A (en) | 1970-03-02 |
| NO131678B (en) | 1975-04-01 |
| CH513216A (en) | 1971-09-30 |
| RO55763A (en) | 1974-01-03 |
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