GB1264377A - - Google Patents
Info
- Publication number
- GB1264377A GB1264377A GB1264377DA GB1264377A GB 1264377 A GB1264377 A GB 1264377A GB 1264377D A GB1264377D A GB 1264377DA GB 1264377 A GB1264377 A GB 1264377A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acyloxylated
- olefin
- catalyst
- contacting
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 238000010926 purge Methods 0.000 abstract 2
- 241001292396 Cirrhitidae Species 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q21/00—Antenna arrays or systems
- H01Q21/06—Arrays of individually energised antenna units similarly polarised and spaced apart
- H01Q21/20—Arrays of individually energised antenna units similarly polarised and spaced apart the units being spaced along or adjacent to a curvilinear path
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
- C07C69/01—Vinyl esters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q1/00—Details of, or arrangements associated with, antennas
- H01Q1/42—Housings not intimately mechanically associated with radiating elements, e.g. radome
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,264,377. Acyloxylation of olefins. HALCON INTERNATIONAL Inc. 4 July, 1969 [5 July, 1968], No. 33785/69. Heading C2C. A continuous process for the production of acyloxylated olefins comprises (a) contacting a gaseous reaction mixture containing molecular oxygen, olefin to be acyloxylated and carboxylic acid with a first body of catalyst, said contacting being carried out at a temperature within the range of from 50 to 350‹ C. at a space velocity from 20 to 5000 hours<SP>-1</SP> whereby a conversion of olefin within the range of from 4% to 20% is obtained; (b) removing acyloxylated olefin from the resulting mixture; (c) purging a portion of the remaining mixture; (d) recycling the portion of the mixture remaining after purging for further contact with said first catalyst; (e) contacting the purged gaseous mixture with a second body of catalyst, said contacting being carried out at a temperature in the range of from 50‹ to 350‹ C. at a space velocity from 20 to 5000 hours<SP>-1</SP>; and (f) recovering additional acyloxylated olefin, both said first and second bodies of catalyst comprising a Group VIII metal having an atomic number of at least 44.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74256468A | 1968-07-05 | 1968-07-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1264377A true GB1264377A (en) | 1972-02-23 |
Family
ID=24985332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1264377D Expired GB1264377A (en) | 1968-07-05 | 1969-07-04 |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE735550A (en) |
| DE (1) | DE1934169A1 (en) |
| FR (1) | FR2012378A1 (en) |
| GB (1) | GB1264377A (en) |
| NL (1) | NL6909851A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001000559A1 (en) * | 1999-06-29 | 2001-01-04 | Celanese International Corporation | Ethylene recovery system |
| WO2005100296A1 (en) | 2004-04-15 | 2005-10-27 | Wacker Chemie Ag | Method for recovery of ethylene in a recirculating gas process for the production of vinyl acetate |
| US12325684B2 (en) | 2020-06-09 | 2025-06-10 | Nova Chemicals (International) S.A. | Limiting acetic acid production in ethane ODH process |
-
1969
- 1969-06-26 NL NL6909851A patent/NL6909851A/xx not_active Application Discontinuation
- 1969-07-02 BE BE735550D patent/BE735550A/xx unknown
- 1969-07-04 FR FR6922721A patent/FR2012378A1/fr not_active Withdrawn
- 1969-07-04 GB GB1264377D patent/GB1264377A/en not_active Expired
- 1969-07-05 DE DE19691934169 patent/DE1934169A1/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001000559A1 (en) * | 1999-06-29 | 2001-01-04 | Celanese International Corporation | Ethylene recovery system |
| RU2221771C2 (en) * | 1999-06-29 | 2004-01-20 | Селаниз Интернэшнл Корпорейшн | Ethylene recovery method (options) |
| AU779136B2 (en) * | 1999-06-29 | 2005-01-06 | Celanese International Corporation | Ethylene recovery system |
| CZ299681B6 (en) * | 1999-06-29 | 2008-10-15 | Celanese International Corporation | Ethylene recovery method |
| WO2005100296A1 (en) | 2004-04-15 | 2005-10-27 | Wacker Chemie Ag | Method for recovery of ethylene in a recirculating gas process for the production of vinyl acetate |
| US7803965B2 (en) | 2004-04-15 | 2010-09-28 | Wacker Chemie Ag | Method for recovery of ethylene in a recirculating gas process for the production of vinyl acetate |
| US12325684B2 (en) | 2020-06-09 | 2025-06-10 | Nova Chemicals (International) S.A. | Limiting acetic acid production in ethane ODH process |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2012378A1 (en) | 1970-03-20 |
| NL6909851A (en) | 1970-01-07 |
| BE735550A (en) | 1970-01-02 |
| DE1934169A1 (en) | 1970-02-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |