GB1250734A - - Google Patents
Info
- Publication number
- GB1250734A GB1250734A GB1250734DA GB1250734A GB 1250734 A GB1250734 A GB 1250734A GB 1250734D A GB1250734D A GB 1250734DA GB 1250734 A GB1250734 A GB 1250734A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxide
- acid
- graft
- diethylene triamine
- graft polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 4
- 229920000578 graft copolymer Polymers 0.000 abstract 4
- 150000002924 oxiranes Chemical class 0.000 abstract 4
- -1 heterocyclic amino compound Chemical class 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000008065 acid anhydrides Chemical class 0.000 abstract 2
- 239000004922 lacquer Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920000962 poly(amidoamine) Polymers 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 abstract 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 238000010559 graft polymerization reaction Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 1
- 229960001124 trientine Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
Abstract
1,250,734. Graft polymer compositions. FARBENFABRIKEN BAYER A.G. 6 Feb., 1970 [6 Feb., 1969], No. 5736/70. Heading C3G. A coating composition contains (A) a graft polymer of an epoxide derived from a polyhydric phenol and containing more than one epoxide group in the molecule and, optionally, 1.5 to 7% by weight of hydroxyl groups, the epoxide being grafted with a mixture of (a) 99.5 to 60% by weight of methyl methacrylate and (b) 0.5 to 40% of an ethylenically unsaturated acid and/or acid anhydride and (c) 0 to 20% of an additional ethylenically unsaturated monomer, free from acid groups, the graft base content of the graft polymer being from 30 to 98% by weight and (B) an aliphatic, cycloaliphatic or heterocyclic amino compound containing at least 3 hydrogen atoms attached to the nitrogen of the amino groups. The epoxide may be modified by reaction with, e.g. a mono- or polyamine, carboxylic acid or acid anhydride, polyalcohol or mono- or diisooyanate prior to being grafted, or the graft polymer may be reacted during or after graft polymerization with an aliphatic epoxide. In examples, lacquers are prepared containing a bisphenol A-epichlorohydrin epoxide resin, the graft monomers (b) and (c) and amine compound (B) being as follows: (1) acrylic acid and a polyamido amine or diethylene triamine; (2) methacrylic acid and diethylene triamine; (3) acrylic acid and styrene, or acrylonitrile, and diethylene triamine, triethylene tetramine or tetraethylene pentamine; and (4) maleic acid anhydride and diethylene triamine or a polyamido amine. TiO 2 is incorporated in some of the lacquers.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691905869 DE1905869A1 (en) | 1969-02-06 | 1969-02-06 | Air-drying paints and coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1250734A true GB1250734A (en) | 1971-10-20 |
Family
ID=5724500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1250734D Expired GB1250734A (en) | 1969-02-06 | 1970-02-06 |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE745631A (en) |
| DE (1) | DE1905869A1 (en) |
| FR (1) | FR2035183A5 (en) |
| GB (1) | GB1250734A (en) |
| NL (1) | NL7001304A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4212781A (en) | 1977-04-18 | 1980-07-15 | Scm Corporation | Modified epoxy resins, processes for making and using same and substrates coated therewith |
| US4308185A (en) | 1976-05-11 | 1981-12-29 | Scm Corporation | Graft polymer compositions of terminated epoxy resin, processes for making and using same, and substrates coated therewith |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2608869A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608828A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608839A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608880A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608942A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608931A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| DE2608901A1 (en) * | 1976-03-04 | 1977-09-08 | Hoechst Ag | Process for the preparation of hardenable, liquid, graft copolymers containing epoxy groups |
| GB1585486A (en) * | 1976-05-11 | 1981-03-04 | Scm Corp | Epoxy resins processes for making and using same and substrates coated therewith |
| SE441599B (en) * | 1976-05-11 | 1985-10-21 | Scm Corp | SUMMARY POLYMER COMPOSITION OF AN EPOXID HEART AND ETHENIC UNLESSED ADDITION POLYMERIZABLE MONOMER AND PROCEDURE FOR PREPARING THEREOF |
-
1969
- 1969-02-06 DE DE19691905869 patent/DE1905869A1/en active Pending
-
1970
- 1970-01-29 NL NL7001304A patent/NL7001304A/xx unknown
- 1970-02-06 FR FR7004332A patent/FR2035183A5/fr not_active Expired
- 1970-02-06 BE BE745631D patent/BE745631A/en unknown
- 1970-02-06 GB GB1250734D patent/GB1250734A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4308185A (en) | 1976-05-11 | 1981-12-29 | Scm Corporation | Graft polymer compositions of terminated epoxy resin, processes for making and using same, and substrates coated therewith |
| US4212781A (en) | 1977-04-18 | 1980-07-15 | Scm Corporation | Modified epoxy resins, processes for making and using same and substrates coated therewith |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7001304A (en) | 1970-08-10 |
| DE1905869A1 (en) | 1970-09-10 |
| FR2035183A5 (en) | 1970-12-18 |
| BE745631A (en) | 1970-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |