GB1244080A - Preparation of phenyl esters and phenols - Google Patents
Preparation of phenyl esters and phenolsInfo
- Publication number
- GB1244080A GB1244080A GB61440/69A GB6144069A GB1244080A GB 1244080 A GB1244080 A GB 1244080A GB 61440/69 A GB61440/69 A GB 61440/69A GB 6144069 A GB6144069 A GB 6144069A GB 1244080 A GB1244080 A GB 1244080A
- Authority
- GB
- United Kingdom
- Prior art keywords
- preparation
- phenols
- esters
- phenolic
- phenyl esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002989 phenols Chemical class 0.000 title abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 title 1
- 238000000034 method Methods 0.000 abstract 2
- -1 phenolic ester Chemical class 0.000 abstract 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/035—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with saturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,244,080. Preparation of phenolic esters and phenols. INSTITUT NEFTEKHIMICHESKOGO SINTEZA IMENI A.V. TOPCHIEVA AN SSSR. 17 Dec., 1969, No. 61440/69. Heading C2C. A process for the preparation of a phenolic ester comprises oxidizing an alkylaromatic hydrocarbon or a phenolic ester containing at least one alkyl group in the ring with oxygen, at a temperature of from 100‹ to 300‹ C. and a pressure from 1 to 100 atmosphere, in the presence of an anhydride or acid chloride of a carboxylic acid and of from 0.0006 to 10 mole per cent of an acid catalyst. The esters produced by the process may be saponified to prepare the corresponding phenols.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL696918100A NL151976B (en) | 1969-12-02 | 1969-12-02 | PROCESS FOR PREPARING PHENOLS. |
| GB61440/69A GB1244080A (en) | 1969-12-02 | 1969-12-17 | Preparation of phenyl esters and phenols |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL696918100A NL151976B (en) | 1969-12-02 | 1969-12-02 | PROCESS FOR PREPARING PHENOLS. |
| GB61440/69A GB1244080A (en) | 1969-12-02 | 1969-12-17 | Preparation of phenyl esters and phenols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1244080A true GB1244080A (en) | 1971-08-25 |
Family
ID=26267850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB61440/69A Expired GB1244080A (en) | 1969-12-02 | 1969-12-17 | Preparation of phenyl esters and phenols |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB1244080A (en) |
| NL (1) | NL151976B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2912098A1 (en) * | 1978-03-27 | 1979-10-18 | Suntech | METHOD OF CATALYTIC OXYDATION OF METHYLAROMATS |
| US4191839A (en) * | 1978-03-27 | 1980-03-04 | Suntech, Inc. | Direct oxidation of toluene to benzylidene diacetate |
| DE2944078A1 (en) * | 1978-11-03 | 1980-05-14 | Suntech | METHOD FOR THE OXYDATION OF AETHYLBENZENE |
| US4260808A (en) * | 1978-11-03 | 1981-04-07 | Suntech, Inc. | Catalytic process for the conversion of toluene to equimolar amounts of phenol acetate and methylene diacetate |
| US4504672A (en) * | 1978-11-03 | 1985-03-12 | Suntech, Inc. | Catalytic process for the conversion of toluene to equimolar amounts of phenyl acetate and methylene diacetate |
-
1969
- 1969-12-02 NL NL696918100A patent/NL151976B/en unknown
- 1969-12-17 GB GB61440/69A patent/GB1244080A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2912098A1 (en) * | 1978-03-27 | 1979-10-18 | Suntech | METHOD OF CATALYTIC OXYDATION OF METHYLAROMATS |
| FR2421162A1 (en) * | 1978-03-27 | 1979-10-26 | Suntech | CATALYTIC CONVERSION OF TOLUENE TO PHENOL AND FORMALDEHYDE |
| US4191839A (en) * | 1978-03-27 | 1980-03-04 | Suntech, Inc. | Direct oxidation of toluene to benzylidene diacetate |
| DE2944078A1 (en) * | 1978-11-03 | 1980-05-14 | Suntech | METHOD FOR THE OXYDATION OF AETHYLBENZENE |
| US4225728A (en) * | 1978-11-03 | 1980-09-30 | Suntech, Inc. | Catalytic process for the conversion of ethyl benzene to equimolar amounts of vinyl acetate and phenol |
| US4260808A (en) * | 1978-11-03 | 1981-04-07 | Suntech, Inc. | Catalytic process for the conversion of toluene to equimolar amounts of phenol acetate and methylene diacetate |
| US4504672A (en) * | 1978-11-03 | 1985-03-12 | Suntech, Inc. | Catalytic process for the conversion of toluene to equimolar amounts of phenyl acetate and methylene diacetate |
Also Published As
| Publication number | Publication date |
|---|---|
| NL151976B (en) | 1977-01-17 |
| NL6918100A (en) | 1971-06-04 |
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