GB1122448A - Process for preparing unsaturated dicarboxylic acids - Google Patents
Process for preparing unsaturated dicarboxylic acidsInfo
- Publication number
- GB1122448A GB1122448A GB4124366A GB4124366A GB1122448A GB 1122448 A GB1122448 A GB 1122448A GB 4124366 A GB4124366 A GB 4124366A GB 4124366 A GB4124366 A GB 4124366A GB 1122448 A GB1122448 A GB 1122448A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dicarboxylic acids
- unsaturated dicarboxylic
- preparing unsaturated
- methylene
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001991 dicarboxylic acids Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- DOBUSJIVSSJEDA-UHFFFAOYSA-L 1,3-dioxa-2$l^{6}-thia-4-mercuracyclobutane 2,2-dioxide Chemical compound [Hg+2].[O-]S([O-])(=O)=O DOBUSJIVSSJEDA-UHFFFAOYSA-L 0.000 abstract 1
- CWNNYYIZGGDCHS-UHFFFAOYSA-N 2-methylideneglutaric acid Chemical compound OC(=O)CCC(=C)C(O)=O CWNNYYIZGGDCHS-UHFFFAOYSA-N 0.000 abstract 1
- NGCJVMZXRCLPRQ-UHFFFAOYSA-N 2-methylidenepentanedinitrile Chemical compound N#CC(=C)CCC#N NGCJVMZXRCLPRQ-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000005749 Copper compound Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000001880 copper compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/08—Preparation of carboxylic acids or their salts, halides or anhydrides from nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
2-Methylene glutaric acid is prepared by reacting 2-methylene glutaronitrile with water in the presence of a mineral acid or an alkaline hydroxide. A catalyst such as copper, a copper compound, or mercuric sulphate may be included and the alkaline hydrolysis may be carried out in the presence of an alkanol such as methanol or ethanol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48940665A | 1965-09-22 | 1965-09-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1122448A true GB1122448A (en) | 1968-08-07 |
Family
ID=23943725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4124366A Expired GB1122448A (en) | 1965-09-22 | 1966-09-15 | Process for preparing unsaturated dicarboxylic acids |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE687139A (en) |
| DE (1) | DE1593175A1 (en) |
| FR (1) | FR1495197A (en) |
| GB (1) | GB1122448A (en) |
| NL (1) | NL6613239A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008062058A1 (en) * | 2006-11-24 | 2008-05-29 | Rhodia Operations | Method for converting nitrile compounds into corresponding carboxylic acids and esters |
| US8119838B2 (en) * | 2006-06-09 | 2012-02-21 | Rhodia Operations | Conversion of nitrile compounds into carboxylic acids and corresponding esters thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113563180A (en) * | 2021-07-26 | 2021-10-29 | 广东嘉博制药有限公司 | (E) Preparation method of (E) -4-ene-1, 8-octanedioic acid |
-
1966
- 1966-09-15 GB GB4124366A patent/GB1122448A/en not_active Expired
- 1966-09-20 BE BE687139D patent/BE687139A/xx unknown
- 1966-09-20 NL NL6613239A patent/NL6613239A/xx unknown
- 1966-09-21 FR FR47731A patent/FR1495197A/en not_active Expired
- 1966-09-22 DE DE19661593175 patent/DE1593175A1/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8119838B2 (en) * | 2006-06-09 | 2012-02-21 | Rhodia Operations | Conversion of nitrile compounds into carboxylic acids and corresponding esters thereof |
| CN101479229B (en) * | 2006-06-09 | 2013-07-24 | 罗地亚运作公司 | Process for converting nitrile compounds to carboxylic acids and corresponding esters |
| WO2008062058A1 (en) * | 2006-11-24 | 2008-05-29 | Rhodia Operations | Method for converting nitrile compounds into corresponding carboxylic acids and esters |
| FR2909088A1 (en) * | 2006-11-24 | 2008-05-30 | Rhodia Recherches & Tech | PROCESS FOR THE TRANSFORMATION OF NITRILIC COMPOUNDS OF CARBOXYLIC ACIDS AND CORRESPONDING ESTERS |
| US8263804B2 (en) | 2006-11-24 | 2012-09-11 | Rhodia Operations | Conversion of nitrile compounds into corresponding carboxylic acids and esters |
| EA017506B1 (en) * | 2006-11-24 | 2013-01-30 | Родиа Операсьон | Method for converting nitrile compounds into carboxylic acids and corresponding esters |
| CN101641318B (en) * | 2006-11-24 | 2013-04-24 | 罗地亚运作公司 | Method for converting nitrile compounds into corresponding carboxylic acids and esters |
| TWI415832B (en) * | 2006-11-24 | 2013-11-21 | Rhodia Operations | Process for the conversion of nitrile compounds to carboxylic acids and corresponding esters |
Also Published As
| Publication number | Publication date |
|---|---|
| BE687139A (en) | 1967-03-01 |
| DE1593175A1 (en) | 1970-07-30 |
| NL6613239A (en) | 1967-03-23 |
| FR1495197A (en) | 1967-09-15 |
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