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GB1110930A - Polymeric composition and process of preparation - Google Patents

Polymeric composition and process of preparation

Info

Publication number
GB1110930A
GB1110930A GB16721/67A GB1672167A GB1110930A GB 1110930 A GB1110930 A GB 1110930A GB 16721/67 A GB16721/67 A GB 16721/67A GB 1672167 A GB1672167 A GB 1672167A GB 1110930 A GB1110930 A GB 1110930A
Authority
GB
United Kingdom
Prior art keywords
polyethylene
silica
ethylene
silane
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16721/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1110930A publication Critical patent/GB1110930A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Compositions comprise a polyolefin, 10 to 60 volume per cent of the composition of an inorganic filler having an average surface area of 0.5 to 10 square metres/gram and a 1/d ratio of 10 to 1 or less and an organo silane Xa(Yb)Si-(RnZ)c, where X is a hydrolysable group capable of reacting with a hydroxyl group, Y is a monovalent hydrocarbon group, R is a C1- 20 alkylene group, Z is a group capable of reacting with a free radical, n is 0 or 1, a is 1, 2 or 3, b is 0, 1 or 2, c is 1, 2 or 3, and a+b+c is 4. The filler and silane may be heated at 200 DEG C. in the absence of a solvent to adhere the silane to the filler, and the silane treated filler blended with the polyolefin under conditions producing free radicals, e.g. high shear milling, extrusion or peroxidizing the treated filler. The polyolefin may be a homopolymer of ethylene or propylene, or a copolymer thereof with butenes, ethyl acrylate, methyl methacrylate, vinyl acetate, vinyl chloride, maleic anhydride or fumaric acid; or mechanical or polymerization blends thereof with other compatible polymers. Many suitable fillers and silanes are specified and examples describe the preparation of moulding materials from (1, 2 and 9 to 11) polyethylene, silica and 3-trimethoxysilylpropyl methacrylate; (3 and 4) polyethylene, silica and 3-trimethoxypropylamine; (5) polyethylene, silica and vinyltriethoxysilane; silica, 3-trimethoxysilylpropyl methacrylate and (6) polyethylene and ethylene/vinyl acetate copolymer, (7) polyethylene and ethylene/ethyl acrylate copolymer and (8) polypropylene; and (12) an ethylene/propylene copolymer, feldspar and 3-trimethoxysilylpropyl methacrylate.
GB16721/67A 1966-04-13 1967-04-12 Polymeric composition and process of preparation Expired GB1110930A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54236966A 1966-04-13 1966-04-13
US66649767A 1967-09-08 1967-09-08

Publications (1)

Publication Number Publication Date
GB1110930A true GB1110930A (en) 1968-04-24

Family

ID=62527931

Family Applications (2)

Application Number Title Priority Date Filing Date
GB16721/67A Expired GB1110930A (en) 1966-04-13 1967-04-12 Polymeric composition and process of preparation
GB42845/68A Expired GB1177200A (en) 1966-04-13 1968-09-09 Thermoplastic Polymeric Compositions

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB42845/68A Expired GB1177200A (en) 1966-04-13 1968-09-09 Thermoplastic Polymeric Compositions

Country Status (9)

Country Link
BE (2) BE720532A (en)
CH (1) CH510702A (en)
DE (2) DE1694612A1 (en)
DK (1) DK123304B (en)
ES (1) ES357932A1 (en)
FR (1) FR1579376A (en)
GB (2) GB1110930A (en)
IL (1) IL30663A (en)
NL (1) NL6812835A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2228978A1 (en) * 1971-06-14 1973-01-18 Nat Distillers Chem Corp FIRE RESISTANT MASS
US4006037A (en) * 1974-11-04 1977-02-01 The Richardson Company Mineral filled, high impact, polyolefin molding compositions
US4133797A (en) 1974-08-01 1979-01-09 The Richardson Company Mineral-filled, high impact polyolefin molding compositions
US5637629A (en) * 1992-11-18 1997-06-10 Enichem S.P.A. Reinforced polyolefinic thermoplastic composition
WO2005066262A1 (en) * 2003-12-30 2005-07-21 3M Innovative Properties Company Filled composite
US20170314323A1 (en) * 2015-03-31 2017-11-02 Sumitomo Riko Company Limited Light-transmitting laminate for optical use
CN111393784A (en) * 2019-12-18 2020-07-10 宁波能之光新材料科技股份有限公司 Easily-dispersible high-interface-bonding-strength polyolefin filling master batch and preparation method thereof

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1396120A (en) * 1972-10-28 1975-06-04 Dow Corning Ltd Crosslinking process
JPS5483089A (en) * 1977-12-15 1979-07-02 Sekisui Chem Co Ltd Preparation of silane-modified ethylene resin
US4144202A (en) * 1977-12-27 1979-03-13 Union Carbide Corporation Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes
ZA787062B (en) * 1977-12-27 1980-04-30 Union Carbide Corp Wire or cable insulated with a dielectric composition stabilized against water treeing with organo silane compounds
DE3327149A1 (en) * 1983-07-28 1985-04-04 Dynamit Nobel Ag, 5210 Troisdorf METHOD FOR THE PRODUCTION OF SEMI-PRODUCTS OR MOLDED PARTS FROM POLYPROPYLENE
EP0252061A1 (en) * 1986-07-04 1988-01-07 Cableries Et Corderies Du Hainaut S.A. Process for the preparation of vinylpolymers and vinylpolymers crosslinkable by the grafting of a hydrolysable silane compound
GB2254081B (en) * 1991-03-25 1994-11-09 Ecc Int Ltd Mineral fillers
RU2309964C1 (en) * 2006-04-10 2007-11-10 Открытое акционерное общество "Белкард" Formula of composite thermoplastic material
DE102016105525A1 (en) * 2016-03-24 2017-09-28 Blanco Gmbh + Co Kg Curable casting compound for the production of plastic moldings and their use

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2228978A1 (en) * 1971-06-14 1973-01-18 Nat Distillers Chem Corp FIRE RESISTANT MASS
US4133797A (en) 1974-08-01 1979-01-09 The Richardson Company Mineral-filled, high impact polyolefin molding compositions
US4006037A (en) * 1974-11-04 1977-02-01 The Richardson Company Mineral filled, high impact, polyolefin molding compositions
US5637629A (en) * 1992-11-18 1997-06-10 Enichem S.P.A. Reinforced polyolefinic thermoplastic composition
WO2005066262A1 (en) * 2003-12-30 2005-07-21 3M Innovative Properties Company Filled composite
US20170314323A1 (en) * 2015-03-31 2017-11-02 Sumitomo Riko Company Limited Light-transmitting laminate for optical use
CN111393784A (en) * 2019-12-18 2020-07-10 宁波能之光新材料科技股份有限公司 Easily-dispersible high-interface-bonding-strength polyolefin filling master batch and preparation method thereof

Also Published As

Publication number Publication date
NL6812835A (en) 1969-03-11
BE720532A (en) 1969-03-06
BE728012A (en) 1969-08-06
FR1579376A (en) 1969-08-22
CH510702A (en) 1971-07-31
IL30663A (en) 1973-01-30
DK123304B (en) 1972-06-05
DE1694612A1 (en) 1970-09-17
GB1177200A (en) 1970-01-07
ES357932A1 (en) 1970-04-01
DE1794107B2 (en) 1974-11-21
DE1794107A1 (en) 1972-03-16
IL30663A0 (en) 1968-11-27

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