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ES357932A1 - PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS. - Google Patents

PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS.

Info

Publication number
ES357932A1
ES357932A1 ES357932A ES357932A ES357932A1 ES 357932 A1 ES357932 A1 ES 357932A1 ES 357932 A ES357932 A ES 357932A ES 357932 A ES357932 A ES 357932A ES 357932 A1 ES357932 A1 ES 357932A1
Authority
ES
Spain
Prior art keywords
ethylene
polyethylene
treated
copolymer
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES357932A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES357932A1 publication Critical patent/ES357932A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Thermoplastic compositions comprise an olefin polymer, 10 to 60 volume per cent of the composition of a calcined aluminosilicate and an organosilane of formula X a (Y b )Si[R n -Z] c , where X is a hydrolysable group capable of reacting with a hydroxyl group, Y is a monovalent hydrocarbon group, R is an alkylene group having 1 to 20 carbon atoms, Z is a group capable of reacting with a free radical, n is 0 or 1, a is 1, 2 or 3, b is 0, 1 or 2, c is 1, 2 or 3 and a + b + c is 4. The polymer may be polyethylene or a copolymer of ethylene with propylene, butenes, ethyl acrylate, methyl methacrylate, vinyl acetate, vinyl chloride, maleic anhydride or fumaric acid or mechanical or polymerization blend thereof with other compatible polymers. A preferred alumino silicate is kaolin. The compositions are preferably prepared by mixing the olefin polymer with the silane treated filler under conditions generating free radicals, e.g. by high shear mixing or by oxidizing the silane to provide peroxy groups. Conventional antioxidants, e.g. 2,6-di-t.-butyl-p-cresol pigments, e.g. titanium dioxide and processing aids, e.g. mineral oil or stearic acid, may also be present. Many suitable polymers and silanes are listed and examples describe compositions comprising polyethylene and calcined kaolin treated with (1-4, 12-14 and 16-18) 3-trimethoxysilylpropyl methacrylate (15, 19 and 20) vinyltriethoxysilane, (21) 3 - triethoxysilylpropylamine and (22) methyl trimethoxysilyl propionate and comprising 3-trimethoxysilylpropyl methacrylate treated calcined kaolin and blends of polyethylene with (24) ethylene/vinyl acetate copolymer and (25) ethylene/ethyl acrylate copolymer.
ES357932A 1966-04-13 1968-09-07 PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS. Expired ES357932A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54236966A 1966-04-13 1966-04-13
US66649767A 1967-09-08 1967-09-08

Publications (1)

Publication Number Publication Date
ES357932A1 true ES357932A1 (en) 1970-04-01

Family

ID=62527931

Family Applications (1)

Application Number Title Priority Date Filing Date
ES357932A Expired ES357932A1 (en) 1966-04-13 1968-09-07 PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS.

Country Status (9)

Country Link
BE (2) BE720532A (en)
CH (1) CH510702A (en)
DE (2) DE1694612A1 (en)
DK (1) DK123304B (en)
ES (1) ES357932A1 (en)
FR (1) FR1579376A (en)
GB (2) GB1110930A (en)
IL (1) IL30663A (en)
NL (1) NL6812835A (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1004386A (en) * 1971-06-14 1977-01-25 National Distillers And Chemical Corporation Fire retardant polymeric uni-insulation compositions
GB1396120A (en) * 1972-10-28 1975-06-04 Dow Corning Ltd Crosslinking process
US4133797A (en) 1974-08-01 1979-01-09 The Richardson Company Mineral-filled, high impact polyolefin molding compositions
US4006037A (en) * 1974-11-04 1977-02-01 The Richardson Company Mineral filled, high impact, polyolefin molding compositions
JPS5483089A (en) * 1977-12-15 1979-07-02 Sekisui Chem Co Ltd Preparation of silane-modified ethylene resin
ZA787062B (en) * 1977-12-27 1980-04-30 Union Carbide Corp Wire or cable insulated with a dielectric composition stabilized against water treeing with organo silane compounds
US4144202A (en) * 1977-12-27 1979-03-13 Union Carbide Corporation Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes
DE3327149A1 (en) * 1983-07-28 1985-04-04 Dynamit Nobel Ag, 5210 Troisdorf METHOD FOR THE PRODUCTION OF SEMI-PRODUCTS OR MOLDED PARTS FROM POLYPROPYLENE
EP0252061A1 (en) * 1986-07-04 1988-01-07 Cableries Et Corderies Du Hainaut S.A. Process for the preparation of vinylpolymers and vinylpolymers crosslinkable by the grafting of a hydrolysable silane compound
GB2254081B (en) * 1991-03-25 1994-11-09 Ecc Int Ltd Mineral fillers
IT1256423B (en) * 1992-11-18 1995-12-05 Enichem Polimeri REINFORCED THERMOPLASTIC POLYOLEFINIC COMPOSITION
WO2005066262A1 (en) * 2003-12-30 2005-07-21 3M Innovative Properties Company Filled composite
RU2309964C1 (en) * 2006-04-10 2007-11-10 Открытое акционерное общество "Белкард" Formula of composite thermoplastic material
JP6343580B2 (en) * 2015-03-31 2018-06-13 住友理工株式会社 Optically transparent laminate
DE102016105525A1 (en) * 2016-03-24 2017-09-28 Blanco Gmbh + Co Kg Curable casting compound for the production of plastic moldings and their use
CN111393784A (en) * 2019-12-18 2020-07-10 宁波能之光新材料科技股份有限公司 Easily-dispersible high-interface-bonding-strength polyolefin filling master batch and preparation method thereof

Also Published As

Publication number Publication date
DE1794107B2 (en) 1974-11-21
DE1694612A1 (en) 1970-09-17
IL30663A (en) 1973-01-30
GB1177200A (en) 1970-01-07
BE720532A (en) 1969-03-06
IL30663A0 (en) 1968-11-27
DK123304B (en) 1972-06-05
NL6812835A (en) 1969-03-11
DE1794107A1 (en) 1972-03-16
FR1579376A (en) 1969-08-22
CH510702A (en) 1971-07-31
GB1110930A (en) 1968-04-24
BE728012A (en) 1969-08-06

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