ES357932A1 - PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS. - Google Patents
PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS.Info
- Publication number
- ES357932A1 ES357932A1 ES357932A ES357932A ES357932A1 ES 357932 A1 ES357932 A1 ES 357932A1 ES 357932 A ES357932 A ES 357932A ES 357932 A ES357932 A ES 357932A ES 357932 A1 ES357932 A1 ES 357932A1
- Authority
- ES
- Spain
- Prior art keywords
- ethylene
- polyethylene
- treated
- copolymer
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Thermoplastic compositions comprise an olefin polymer, 10 to 60 volume per cent of the composition of a calcined aluminosilicate and an organosilane of formula X a (Y b )Si[R n -Z] c , where X is a hydrolysable group capable of reacting with a hydroxyl group, Y is a monovalent hydrocarbon group, R is an alkylene group having 1 to 20 carbon atoms, Z is a group capable of reacting with a free radical, n is 0 or 1, a is 1, 2 or 3, b is 0, 1 or 2, c is 1, 2 or 3 and a + b + c is 4. The polymer may be polyethylene or a copolymer of ethylene with propylene, butenes, ethyl acrylate, methyl methacrylate, vinyl acetate, vinyl chloride, maleic anhydride or fumaric acid or mechanical or polymerization blend thereof with other compatible polymers. A preferred alumino silicate is kaolin. The compositions are preferably prepared by mixing the olefin polymer with the silane treated filler under conditions generating free radicals, e.g. by high shear mixing or by oxidizing the silane to provide peroxy groups. Conventional antioxidants, e.g. 2,6-di-t.-butyl-p-cresol pigments, e.g. titanium dioxide and processing aids, e.g. mineral oil or stearic acid, may also be present. Many suitable polymers and silanes are listed and examples describe compositions comprising polyethylene and calcined kaolin treated with (1-4, 12-14 and 16-18) 3-trimethoxysilylpropyl methacrylate (15, 19 and 20) vinyltriethoxysilane, (21) 3 - triethoxysilylpropylamine and (22) methyl trimethoxysilyl propionate and comprising 3-trimethoxysilylpropyl methacrylate treated calcined kaolin and blends of polyethylene with (24) ethylene/vinyl acetate copolymer and (25) ethylene/ethyl acrylate copolymer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54236966A | 1966-04-13 | 1966-04-13 | |
| US66649767A | 1967-09-08 | 1967-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES357932A1 true ES357932A1 (en) | 1970-04-01 |
Family
ID=62527931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES357932A Expired ES357932A1 (en) | 1966-04-13 | 1968-09-07 | PROCEDURE FOR THE PREPARATION OF THERMOPLASTIC POLYMER COMPOSITIONS. |
Country Status (9)
| Country | Link |
|---|---|
| BE (2) | BE720532A (en) |
| CH (1) | CH510702A (en) |
| DE (2) | DE1694612A1 (en) |
| DK (1) | DK123304B (en) |
| ES (1) | ES357932A1 (en) |
| FR (1) | FR1579376A (en) |
| GB (2) | GB1110930A (en) |
| IL (1) | IL30663A (en) |
| NL (1) | NL6812835A (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1004386A (en) * | 1971-06-14 | 1977-01-25 | National Distillers And Chemical Corporation | Fire retardant polymeric uni-insulation compositions |
| GB1396120A (en) * | 1972-10-28 | 1975-06-04 | Dow Corning Ltd | Crosslinking process |
| US4133797A (en) | 1974-08-01 | 1979-01-09 | The Richardson Company | Mineral-filled, high impact polyolefin molding compositions |
| US4006037A (en) * | 1974-11-04 | 1977-02-01 | The Richardson Company | Mineral filled, high impact, polyolefin molding compositions |
| JPS5483089A (en) * | 1977-12-15 | 1979-07-02 | Sekisui Chem Co Ltd | Preparation of silane-modified ethylene resin |
| ZA787062B (en) * | 1977-12-27 | 1980-04-30 | Union Carbide Corp | Wire or cable insulated with a dielectric composition stabilized against water treeing with organo silane compounds |
| US4144202A (en) * | 1977-12-27 | 1979-03-13 | Union Carbide Corporation | Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes |
| DE3327149A1 (en) * | 1983-07-28 | 1985-04-04 | Dynamit Nobel Ag, 5210 Troisdorf | METHOD FOR THE PRODUCTION OF SEMI-PRODUCTS OR MOLDED PARTS FROM POLYPROPYLENE |
| EP0252061A1 (en) * | 1986-07-04 | 1988-01-07 | Cableries Et Corderies Du Hainaut S.A. | Process for the preparation of vinylpolymers and vinylpolymers crosslinkable by the grafting of a hydrolysable silane compound |
| GB2254081B (en) * | 1991-03-25 | 1994-11-09 | Ecc Int Ltd | Mineral fillers |
| IT1256423B (en) * | 1992-11-18 | 1995-12-05 | Enichem Polimeri | REINFORCED THERMOPLASTIC POLYOLEFINIC COMPOSITION |
| WO2005066262A1 (en) * | 2003-12-30 | 2005-07-21 | 3M Innovative Properties Company | Filled composite |
| RU2309964C1 (en) * | 2006-04-10 | 2007-11-10 | Открытое акционерное общество "Белкард" | Formula of composite thermoplastic material |
| JP6343580B2 (en) * | 2015-03-31 | 2018-06-13 | 住友理工株式会社 | Optically transparent laminate |
| DE102016105525A1 (en) * | 2016-03-24 | 2017-09-28 | Blanco Gmbh + Co Kg | Curable casting compound for the production of plastic moldings and their use |
| CN111393784A (en) * | 2019-12-18 | 2020-07-10 | 宁波能之光新材料科技股份有限公司 | Easily-dispersible high-interface-bonding-strength polyolefin filling master batch and preparation method thereof |
-
1967
- 1967-03-23 DE DE19671694612 patent/DE1694612A1/en active Pending
- 1967-04-12 GB GB16721/67A patent/GB1110930A/en not_active Expired
-
1968
- 1968-09-04 IL IL30663A patent/IL30663A/en unknown
- 1968-09-06 BE BE720532D patent/BE720532A/xx unknown
- 1968-09-06 DK DK430868AA patent/DK123304B/en unknown
- 1968-09-07 ES ES357932A patent/ES357932A1/en not_active Expired
- 1968-09-09 NL NL6812835A patent/NL6812835A/xx unknown
- 1968-09-09 GB GB42845/68A patent/GB1177200A/en not_active Expired
- 1968-09-09 FR FR1579376D patent/FR1579376A/fr not_active Expired
- 1968-09-09 CH CH1345368A patent/CH510702A/en not_active IP Right Cessation
- 1968-09-09 DE DE1794107A patent/DE1794107B2/en active Pending
-
1969
- 1969-02-06 BE BE728012D patent/BE728012A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1794107B2 (en) | 1974-11-21 |
| DE1694612A1 (en) | 1970-09-17 |
| IL30663A (en) | 1973-01-30 |
| GB1177200A (en) | 1970-01-07 |
| BE720532A (en) | 1969-03-06 |
| IL30663A0 (en) | 1968-11-27 |
| DK123304B (en) | 1972-06-05 |
| NL6812835A (en) | 1969-03-11 |
| DE1794107A1 (en) | 1972-03-16 |
| FR1579376A (en) | 1969-08-22 |
| CH510702A (en) | 1971-07-31 |
| GB1110930A (en) | 1968-04-24 |
| BE728012A (en) | 1969-08-06 |
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