GB1110359A - Improvements relating to hydroconversion of hydrocarbons - Google Patents
Improvements relating to hydroconversion of hydrocarbonsInfo
- Publication number
- GB1110359A GB1110359A GB57012/66A GB5701266A GB1110359A GB 1110359 A GB1110359 A GB 1110359A GB 57012/66 A GB57012/66 A GB 57012/66A GB 5701266 A GB5701266 A GB 5701266A GB 1110359 A GB1110359 A GB 1110359A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocracking
- catalyst
- charge stock
- zone
- hydrocarbon charge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 7
- 239000003054 catalyst Substances 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
A process for improving the activity and reducing the ageing rate of a catalyst which has become partially deactivated in a process for the hydrocracking of a hydrocarbon charge stock comprises bringing the catalyst into contact under hydrocracking conditions with a hydrocarbon charge stock of reduced polycyclic aromatic content (e.g. containing less than 11% by wt.) as compared with the original charge stock. Suitable hydrocracking catalysts comprise a hydrogenating component such as a Group VIII metal or metal compound, e.g. Ni alone or in conjunction with compounds of molybdenum or tungsten, supported on a cracking component such as Al2O3, MgO, SiO2, or mixtures thereof or a zeolitic alumino-silicate having pore openings of 6-14 <\>rA. Suitable hydrocracking conditions include a temperature of 450-775 DEG F., a pressure of 500-10,000 p.s.i.g. a hydrogen rate of 1000-20,000 SCFB, and a space velocity of liquid charge of 0.1 to 10 vols per vol. of catalyst per hour. When the hydrocarbon charge stock contains more than 20 p.p.m. nitrogen it should be first subjected to a catalytic denitrogenation. If the hydrocracking catalyst is not sensitive to ammonia, the entire effluent from the denitrogenation zone may be sent directly to the hydrocracking zone, but if not, the hydrogen may be subjected to a basic nitrogen removal treatment, e.g. by washing with dilute acid and stripping with an inert gas before being fed to the hydrocracking zone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51608265A | 1965-12-23 | 1965-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1110359A true GB1110359A (en) | 1968-04-18 |
Family
ID=24054057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB57012/66A Expired GB1110359A (en) | 1965-12-23 | 1966-12-20 | Improvements relating to hydroconversion of hydrocarbons |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3436338A (en) |
| DE (1) | DE1542509A1 (en) |
| GB (1) | GB1110359A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6702572A (en) * | 1967-02-21 | 1968-08-22 | ||
| US3620962A (en) * | 1967-10-09 | 1971-11-16 | Atlantic Richfield Co | Process |
| US8747659B2 (en) | 2010-02-23 | 2014-06-10 | Exxonmobil Research And Engineering Company | Hydrotreating process |
| JP5737981B2 (en) | 2011-02-04 | 2015-06-17 | 独立行政法人石油天然ガス・金属鉱物資源機構 | Method for producing hydrocarbon oil |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2614068A (en) * | 1952-10-14 | Multiunit catalytic cracking | ||
| US3158563A (en) * | 1962-03-27 | 1964-11-24 | Standard Oil Co | Process for rejuvenation of hydrocracking catalysts |
-
1965
- 1965-12-23 US US516082A patent/US3436338A/en not_active Expired - Lifetime
-
1966
- 1966-12-20 GB GB57012/66A patent/GB1110359A/en not_active Expired
- 1966-12-23 DE DE19661542509 patent/DE1542509A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE1542509A1 (en) | 1970-03-26 |
| US3436338A (en) | 1969-04-01 |
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