GB1182073A - Improvements in and relating to Aqueous Copolymer Dispersions - Google Patents
Improvements in and relating to Aqueous Copolymer DispersionsInfo
- Publication number
- GB1182073A GB1182073A GB2720/68A GB272068A GB1182073A GB 1182073 A GB1182073 A GB 1182073A GB 2720/68 A GB2720/68 A GB 2720/68A GB 272068 A GB272068 A GB 272068A GB 1182073 A GB1182073 A GB 1182073A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- oxide
- copolymer
- monomers
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 5
- 239000006185 dispersion Substances 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 3
- 229920001567 vinyl ester resin Polymers 0.000 abstract 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- SYQPYBIKHVKDLE-UHFFFAOYSA-N (4-hydroxyphenyl)-phenylmethanone;prop-2-enoic acid Chemical compound OC(=O)C=C.C1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 SYQPYBIKHVKDLE-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 125000005396 acrylic acid ester group Chemical group 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 229940040526 anhydrous sodium acetate Drugs 0.000 abstract 1
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- WOUGTQSGQAEECP-UHFFFAOYSA-N ethenyl 2-(4-benzoylphenoxy)acetate Chemical compound C(=C)OC(COC1=CC=C(C=C1)C(C1=CC=CC=C1)=O)=O WOUGTQSGQAEECP-UHFFFAOYSA-N 0.000 abstract 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- OJMGRWMGCRBVGD-UHFFFAOYSA-N n-(4-benzoylphenyl)prop-2-enamide Chemical compound C1=CC(NC(=O)C=C)=CC=C1C(=O)C1=CC=CC=C1 OJMGRWMGCRBVGD-UHFFFAOYSA-N 0.000 abstract 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- 235000012222 talc Nutrition 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052724 xenon Inorganic materials 0.000 abstract 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/10—Vinyl esters of monocarboxylic acids containing three or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
1,182,073. Aqueous copolymer dispersion. FARBWERKE HOECHST A.G. 18 Jan., 1968 [18 Jan., 19671, No. 2720/68. Heading C3P. An aqueous dispersion of a copolymer is prepared by copolymerizing, by an emulsion p )lymerization, (1) a vinyl ester, an acrylic acid ester, a methacrylic acid ester, or a mixture of any two or more of these substances, if desired together with up to 50%, based on the weight of the total monomer mixture, of one or more other olefinically unsaturated monomers, and (2) at least one monomer of the formula in which n is 1 or 2, B, represents a methyl or a phenyl group and, when n is 1, R 2 represents -OCH 2 COOCH=CH 2 , -COO-CH = CH 2 and when n is 2, R 2 represents in which radicals R 3 represent a straight-chained or branched alkyl radical having from I to 10 carbon atoms, in the presence of from 0.1 to 15% by weight, based on the monomers, of at least one emulsifier and/or protective colloid. In the examples vinyl acetate, vinyl esters of a mixture of C 9 _ 11 aliphatic carboxylic acids branched in the a-position, p-benzoyl-phenoxyacetic acid vinyl ester, p-hydroxybenzophenone acrylate, benzophenone-o-carboxylic acid vinyl ester, 4 - acrylamido - benzophenone, di - nbutylmaleate monomers of formula methyl methacrylate, acrylic acid and butyl acrylate were copolymerized in the presence of water, hydroxyethylation product of nonyl phenol with ethylene oxide, sodium vinylsulphonate, anhydrous sodium acetate, reaction l product of polypropylene oxide and ethylene t oxide, a copolymer of N-vinyl-N-methylacetamide and di-2-ethylhexylmaleate, potassium persulphate and polyvinyl alcohol. The copolymers are pigmented, e.g. with titanium dioxide, barium sulphate, talcum, chalk, heavy spar and hydrated iron oxide and cross-linked with a xenon lamp.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0051278 | 1967-01-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1182073A true GB1182073A (en) | 1970-02-25 |
Family
ID=7104486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2720/68A Expired GB1182073A (en) | 1967-01-18 | 1968-01-18 | Improvements in and relating to Aqueous Copolymer Dispersions |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE709565A (en) |
| DE (1) | DE1720605B2 (en) |
| FR (1) | FR1551563A (en) |
| GB (1) | GB1182073A (en) |
| NL (1) | NL154527B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4287039A (en) | 1978-12-14 | 1981-09-01 | Basf Aktiengesellschaft | Radiation-curable aqueous binder dispersions, their preparation and their use |
| TWI455952B (en) * | 2010-12-16 | 2014-10-11 | Agi Corp | Crosslinkable liquid benzophenone (meth) acrylate |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010002232A1 (en) | 2010-02-23 | 2011-08-25 | Evonik Röhm GmbH, 64293 | Benzophenone-containing dispersions for textile applications |
-
1967
- 1967-01-18 DE DE1720605A patent/DE1720605B2/en not_active Withdrawn
-
1968
- 1968-01-12 NL NL686800501A patent/NL154527B/en unknown
- 1968-01-17 FR FR1551563D patent/FR1551563A/fr not_active Expired
- 1968-01-18 BE BE709565D patent/BE709565A/xx unknown
- 1968-01-18 GB GB2720/68A patent/GB1182073A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4287039A (en) | 1978-12-14 | 1981-09-01 | Basf Aktiengesellschaft | Radiation-curable aqueous binder dispersions, their preparation and their use |
| TWI455952B (en) * | 2010-12-16 | 2014-10-11 | Agi Corp | Crosslinkable liquid benzophenone (meth) acrylate |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6800501A (en) | 1968-07-19 |
| DE1720605B2 (en) | 1975-11-20 |
| FR1551563A (en) | 1968-12-27 |
| NL154527B (en) | 1977-09-15 |
| BE709565A (en) | 1968-07-18 |
| DE1720605A1 (en) | 1971-06-24 |
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