GB1165479A - Process for the Preparation of Tertiary Monoolefins - Google Patents
Process for the Preparation of Tertiary MonoolefinsInfo
- Publication number
- GB1165479A GB1165479A GB3261368A GB3261368A GB1165479A GB 1165479 A GB1165479 A GB 1165479A GB 3261368 A GB3261368 A GB 3261368A GB 3261368 A GB3261368 A GB 3261368A GB 1165479 A GB1165479 A GB 1165479A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tertiary
- olefins
- steam
- catalyst
- monoolefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000005673 monoalkenes Chemical group 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical group COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
- C07C7/14891—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,165,479. Tertiary mono-olefins. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 9 July, 1968, No. 32613/68. Heading C5E. [Also in Division C2] Tertiary mono-olefins are prepared by decomposing ethers of the formula R-O-R<SP>1</SP>, wherein R is a C 4 -C 7 alkyl or cycloalkyl group having a tertiary carbon atom in the α-position and R<SP>1</SP> is C 1 -C 6 alkyl group, at elevated temperature in the presence of steam and of a catalyst comprising alumina having a surface area of at least 25 m.<SP>2</SP>/g., into C 4 -C 7 tertiary monoolefins and C 1 -C 6 primary alcohols. The process may be carried out at 180-300‹ C. with a steam :ether molar ratio of 10: 1 to 1: 1. The catalyst is preferably γ-alumina containing up to 10 wt. per cent of thermally stable anionic groups such as SO 4 --, and free of alkali or alkaline earth metals. Examples describe the decomposition of methyl tertiary-butylether to isobutene and methanol.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3261368A GB1165479A (en) | 1968-07-09 | 1968-07-09 | Process for the Preparation of Tertiary Monoolefins |
| DE19691934422 DE1934422C3 (en) | 1968-07-09 | 1969-07-07 | Process for the separation of one or more tertiary monoolefins with four to seven carbon atoms in the molecule from hydrocarbon mixtures |
| NL6910382A NL160234C (en) | 1968-07-09 | 1969-07-07 | METHOD FOR INSULATING TERTIARY MONO-ALKINES FROM HYDROCARBON MIXTURES. |
| FR6922961A FR2012552A1 (en) | 1968-07-09 | 1969-07-07 | Tertiary olefins prodn and purification - using an ion-exchange catalyst |
| BE735740D BE735740A (en) | 1968-07-09 | 1969-07-07 | |
| ES369252A ES369252A1 (en) | 1968-07-09 | 1969-07-07 | A PROCEDURE FOR THE ISOLATION OF ONE OR MORE MONO-OLE-TERTIARY FINES. |
| SE956669A SE349559B (en) | 1968-07-09 | 1969-07-07 | |
| CA056379A CA929537A (en) | 1968-07-09 | 1969-07-07 | Process for the isolation of tertiary mono-olefins from hydrocarbon mixtures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3261368A GB1165479A (en) | 1968-07-09 | 1968-07-09 | Process for the Preparation of Tertiary Monoolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1165479A true GB1165479A (en) | 1969-10-01 |
Family
ID=10341353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3261368A Expired GB1165479A (en) | 1968-07-09 | 1968-07-09 | Process for the Preparation of Tertiary Monoolefins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1165479A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4006198A (en) * | 1974-08-02 | 1977-02-01 | Snam Progetti, S.P.A. | Method for the preparation of tertiary olefins |
| US4083889A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4083888A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4320232A (en) | 1979-07-14 | 1982-03-16 | Basf Aktiengesellschaft | Process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene |
| US6696612B2 (en) | 2001-06-21 | 2004-02-24 | Sumitomo Chemical Company, Limited | Process for producing isobutylene and methanol |
| US6852899B2 (en) | 2001-06-21 | 2005-02-08 | Sumitomo Chemical Company Limited | Process for producing isobutylene and methanol |
| RU2319686C2 (en) * | 2005-11-16 | 2008-03-20 | Открытое акционерное общество "Каучук" | Method of processing isobutene-containing hydrocarbon mixture |
| CN100467124C (en) * | 2002-12-06 | 2009-03-11 | 华东理工大学 | Catalyst for producing isobutene by cracking methyl tert-butyl ether |
| CN104437451A (en) * | 2013-09-16 | 2015-03-25 | 中国石油化工股份有限公司 | Preparation method and use method of eggshell type catalyst |
-
1968
- 1968-07-09 GB GB3261368A patent/GB1165479A/en not_active Expired
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4006198A (en) * | 1974-08-02 | 1977-02-01 | Snam Progetti, S.P.A. | Method for the preparation of tertiary olefins |
| US4083889A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4083888A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4320232A (en) | 1979-07-14 | 1982-03-16 | Basf Aktiengesellschaft | Process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene |
| US6696612B2 (en) | 2001-06-21 | 2004-02-24 | Sumitomo Chemical Company, Limited | Process for producing isobutylene and methanol |
| US6852899B2 (en) | 2001-06-21 | 2005-02-08 | Sumitomo Chemical Company Limited | Process for producing isobutylene and methanol |
| CN100467124C (en) * | 2002-12-06 | 2009-03-11 | 华东理工大学 | Catalyst for producing isobutene by cracking methyl tert-butyl ether |
| RU2319686C2 (en) * | 2005-11-16 | 2008-03-20 | Открытое акционерное общество "Каучук" | Method of processing isobutene-containing hydrocarbon mixture |
| CN104437451A (en) * | 2013-09-16 | 2015-03-25 | 中国石油化工股份有限公司 | Preparation method and use method of eggshell type catalyst |
| CN104437451B (en) * | 2013-09-16 | 2016-08-17 | 中国石油化工股份有限公司 | The preparation method of a kind of egg-shell catalyst and the using method of this catalyst |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |