GB1164361A - Aqueous Emulsions of Vinyl-Type Copolymers - Google Patents
Aqueous Emulsions of Vinyl-Type CopolymersInfo
- Publication number
- GB1164361A GB1164361A GB2838667A GB2838667A GB1164361A GB 1164361 A GB1164361 A GB 1164361A GB 2838667 A GB2838667 A GB 2838667A GB 2838667 A GB2838667 A GB 2838667A GB 1164361 A GB1164361 A GB 1164361A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ester
- itaconic
- acid
- hydroxypropyl
- polyoxyalkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 239000000839 emulsion Substances 0.000 title abstract 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 5
- 150000002148 esters Chemical class 0.000 abstract 5
- -1 polyoxypropylene Polymers 0.000 abstract 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 3
- CWNNYYIZGGDCHS-UHFFFAOYSA-N 2-methylideneglutaric acid Chemical compound OC(=O)CCC(=C)C(O)=O CWNNYYIZGGDCHS-UHFFFAOYSA-N 0.000 abstract 2
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 abstract 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 abstract 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 abstract 1
- 244000215068 Acacia senegal Species 0.000 abstract 1
- 235000006491 Acacia senegal Nutrition 0.000 abstract 1
- 229920000084 Gum arabic Polymers 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004141 Sodium laurylsulphate Substances 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 235000010489 acacia gum Nutrition 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 abstract 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/064—Polymers containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,164,361. Vinyl ester/polyoxyalkylene ester copolymers. PFIZER Ltd. 19 June, 1968 [20 June, 1967], No. 28386/67. Headings C3P and C3R. An aqueous emulsion of a copolymer of a vinyl ester and a polyoxyalkylene ester of an α,#-unsaturated carboxylic acid, the polyoxyalkylene ester containing at least one -CO/OR) n X group linked to an ethylenically unsaturated group, where R is a vicinal alkylene group, X is an hydroxyl group or a halogen atom and n is at least 3. Suitable α,#-unsaturated carboxylic acids are acrylic, methacrylic, crotonio, achloroacrylic, a monoalkyl or mono-2-hydroxyalkyl ester of fumaric, maleic, itaconic or 2- methylene glutaric acid, fumaric, maleic, itaconic or 2-methylene glutaric acid. The polyoxyalkylene ester may be the reaction product of propylene oxide with a 2-hydroxy alkyl ester of an α,#-unsaturated carboxylic acid. In the examples polyoxypropylene esters are prepared from 2-hydroxypropyl di-ester of itaconic acid, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 2-hydroxyethyl di-ester of itaconic acid, 2-hydroxypropyl mono-ester of itaconic acid and propylene oxide in the presence of boron trifluoride diethyletherate. These esters are copolymerized with vinyl acetate in the presence of gum acacia, sodium dioctyl sulphosuccinate, water, potassium persulphate, hydroxyethyl cellulose, sodium lauryl sulphate, sodium persulphate and sodium tetradecyl sulphate.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2838667A GB1164361A (en) | 1967-06-20 | 1967-06-20 | Aqueous Emulsions of Vinyl-Type Copolymers |
| DE19681770661 DE1770661A1 (en) | 1967-06-20 | 1968-06-19 | Copolymers of polyoxyalkylene esters of unsaturated carboxylic acids and vinyl esters |
| FR1570974D FR1570974A (en) | 1967-06-20 | 1968-06-20 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2838667A GB1164361A (en) | 1967-06-20 | 1967-06-20 | Aqueous Emulsions of Vinyl-Type Copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1164361A true GB1164361A (en) | 1969-09-17 |
Family
ID=10274817
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2838667A Expired GB1164361A (en) | 1967-06-20 | 1967-06-20 | Aqueous Emulsions of Vinyl-Type Copolymers |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1770661A1 (en) |
| FR (1) | FR1570974A (en) |
| GB (1) | GB1164361A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5110859A (en) * | 1987-09-02 | 1992-05-05 | Peter Flesher | Polymers, their production and uses |
| US5273676A (en) * | 1989-05-09 | 1993-12-28 | Basf Aktiengesellschaft | Copolymers with monomers containing polyalkylene oxide blocks, preparation thereof and use thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4708999A (en) * | 1985-04-26 | 1987-11-24 | Air Products And Chemicals, Inc. | Copolymers of vinyl acetate and poly(alkyleneoxy) acrylates |
| US4618648A (en) * | 1985-04-26 | 1986-10-21 | Air Products And Chemicals, Inc. | Copolymers of vinyl alcohol and poly(alkyleneoxy)acrylates |
| DE3781256T2 (en) * | 1986-11-27 | 1992-12-17 | Allied Colloids Ltd | POLYMERS, THEIR PRODUCTION AND USE. |
-
1967
- 1967-06-20 GB GB2838667A patent/GB1164361A/en not_active Expired
-
1968
- 1968-06-19 DE DE19681770661 patent/DE1770661A1/en active Pending
- 1968-06-20 FR FR1570974D patent/FR1570974A/fr not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5110859A (en) * | 1987-09-02 | 1992-05-05 | Peter Flesher | Polymers, their production and uses |
| US5273676A (en) * | 1989-05-09 | 1993-12-28 | Basf Aktiengesellschaft | Copolymers with monomers containing polyalkylene oxide blocks, preparation thereof and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1770661A1 (en) | 1972-04-06 |
| FR1570974A (en) | 1969-06-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |