GB1191649A - Production of Vinyl Acetate Polymer and Copolymer Emulsions - Google Patents
Production of Vinyl Acetate Polymer and Copolymer EmulsionsInfo
- Publication number
- GB1191649A GB1191649A GB4439267A GB4439267A GB1191649A GB 1191649 A GB1191649 A GB 1191649A GB 4439267 A GB4439267 A GB 4439267A GB 4439267 A GB4439267 A GB 4439267A GB 1191649 A GB1191649 A GB 1191649A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl acetate
- polymerization
- zone
- polymer
- total
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000839 emulsion Substances 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 229920001577 copolymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 229920013683 Celanese Polymers 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1,191,649. Vinyl acetate polymer emulsions. CELANESE CORP. 29 Sept., 1967 [5 Oct., 1966], No. 44392/67. Heading C3P. A polymer emulsion is produced by polymerizing vinyl acetate alone or together with one or more other ethylenically unsaturated carboxylic acid esters in an aqueous medium comprising the monomers, an emulsifying agent and a free radical polymerization catalyst in a polymerization zone, the total amount of catalyst used being the minimum amount to effect complete polymerization of all the monomer used and the emulsifying agent present in the zone before polymerization commences is from 15 to 50% of the total used in the process, the remainder being added to the zone after an emulsion is formed by polymerization of at least 50% and less than 95% of the total monomer to be used. The polymer may be derived from vinyl acetate, ethyl acrylate and di-2-ethylhexyl maleate. In examples the monomers were polymerized in an aq. mixture of a nonylphenoxy-poly-(ethyleneoxy)-ethanol, hydroxyethyl-cellulose or polyvinyl alcohol, sodium bicarbonate, and sodium persulphate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58434866A | 1966-10-05 | 1966-10-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1191649A true GB1191649A (en) | 1970-05-13 |
Family
ID=24336954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4439267A Expired GB1191649A (en) | 1966-10-05 | 1967-09-29 | Production of Vinyl Acetate Polymer and Copolymer Emulsions |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE704706A (en) |
| CH (1) | CH502389A (en) |
| ES (1) | ES345731A1 (en) |
| GB (1) | GB1191649A (en) |
| GR (1) | GR34669B (en) |
| LU (1) | LU54539A1 (en) |
| NL (1) | NL6713549A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4130523A (en) | 1977-07-18 | 1978-12-19 | Union Carbide Corporation | High solids latexes |
| US4409355A (en) | 1980-03-10 | 1983-10-11 | National Distillers And Chemical Corporation | Process for preparing high solids copolymer latices with low viscosity |
| DE3415453A1 (en) * | 1983-04-25 | 1984-10-25 | Polysar Ltd., Sarnia, Ontario | METHOD FOR EMULSION POLYMERIZATION OF A LATEX AND LATEX OBTAINED THEREOF |
| US6048611A (en) * | 1992-02-03 | 2000-04-11 | 3M Innovative Properties Company | High solids moisture resistant latex pressure-sensitive adhesive |
-
1967
- 1967-09-26 LU LU54539A patent/LU54539A1/xx unknown
- 1967-09-28 GR GR670134669A patent/GR34669B/en unknown
- 1967-09-29 GB GB4439267A patent/GB1191649A/en not_active Expired
- 1967-09-30 ES ES345731A patent/ES345731A1/en not_active Expired
- 1967-10-04 CH CH1391667A patent/CH502389A/en not_active IP Right Cessation
- 1967-10-05 BE BE704706D patent/BE704706A/xx unknown
- 1967-10-05 NL NL6713549A patent/NL6713549A/xx unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4130523A (en) | 1977-07-18 | 1978-12-19 | Union Carbide Corporation | High solids latexes |
| US4409355A (en) | 1980-03-10 | 1983-10-11 | National Distillers And Chemical Corporation | Process for preparing high solids copolymer latices with low viscosity |
| DE3415453A1 (en) * | 1983-04-25 | 1984-10-25 | Polysar Ltd., Sarnia, Ontario | METHOD FOR EMULSION POLYMERIZATION OF A LATEX AND LATEX OBTAINED THEREOF |
| FR2544721A1 (en) * | 1983-04-25 | 1984-10-26 | Polysar Ltd | PROCESS FOR SYNTHESIZING CARBOXYL LATEX AND LATEX OBTAINED |
| GB2138830A (en) * | 1983-04-25 | 1984-10-31 | Polysar Ltd | High solids latex |
| US4657966A (en) * | 1983-04-25 | 1987-04-14 | Polysar Limited | Carboxylated latex |
| US6048611A (en) * | 1992-02-03 | 2000-04-11 | 3M Innovative Properties Company | High solids moisture resistant latex pressure-sensitive adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| GR34669B (en) | 1968-06-05 |
| LU54539A1 (en) | 1967-11-27 |
| ES345731A1 (en) | 1968-11-16 |
| BE704706A (en) | 1968-04-05 |
| CH502389A (en) | 1971-01-31 |
| NL6713549A (en) | 1968-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |