GB1163875A - Stabilized Polyolefins - Google Patents
Stabilized PolyolefinsInfo
- Publication number
- GB1163875A GB1163875A GB1645468A GB1645468A GB1163875A GB 1163875 A GB1163875 A GB 1163875A GB 1645468 A GB1645468 A GB 1645468A GB 1645468 A GB1645468 A GB 1645468A GB 1163875 A GB1163875 A GB 1163875A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dithiocarbamate
- octyloxybenzophenone
- hydroxy
- polyethylene
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000098 polyolefin Polymers 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 5
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 3
- 239000012990 dithiocarbamate Substances 0.000 abstract 3
- -1 polyethylene Polymers 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 229920000573 polyethylene Polymers 0.000 abstract 2
- 230000000087 stabilizing effect Effects 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000003017 thermal stabilizer Substances 0.000 abstract 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1,163,875. Stabilizing polyolefins. E. I. DU PONT DE NEMOURS & CO. 5 April. 1968 [10 May, 1967], No. 16454/68. Heading C3P. Normally solid polyolefin compositions comprise a stabilizing amount of a mixture of a nickel dialkyl dithiocarbamate and 2-hydroxy- 4-octyloxybenzophenone, each alkyl group in the dithiocarbamate having 4 to 6 carbon atoms and the weight ratio of dithiocarbamate to benzophenone being 1:1 to 20:1. The polymer may be polyethylene, polypropylene, an ethylene/propylene copolymer or blends thereof with each other or with other polymeric materials, and the compositions may also contain pigments and thermal stabilizers such as phenols and dialkyl thiodipropionates. Examples describe compositions of polyethylene, di-t.-butyl-p-cresol, nickel dibutyl dithiocarbamate and 2-hydroxy-4-octyloxybenzophenone, with and without pigments.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63736167A | 1967-05-10 | 1967-05-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1163875A true GB1163875A (en) | 1969-09-10 |
Family
ID=24555594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1645468A Expired GB1163875A (en) | 1967-05-10 | 1968-04-05 | Stabilized Polyolefins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1163875A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4731949A (en) * | 1984-06-15 | 1988-03-22 | Robinson Brothers Limited | Stabilizing polymers and polymer films |
| US4994511A (en) * | 1987-09-14 | 1991-02-19 | Shell Oil Company | Polyketone stabilization with dihydrocarbyldithiocarbamate salts |
| EP0934984A4 (en) * | 1996-02-21 | 2000-01-19 | Kaneka Corp | Curable composition |
| WO2006058856A1 (en) * | 2004-12-03 | 2006-06-08 | Ciba Specialty Chemicals Holding Inc. | Ultraviolet light absorber stabilizer combination |
-
1968
- 1968-04-05 GB GB1645468A patent/GB1163875A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4731949A (en) * | 1984-06-15 | 1988-03-22 | Robinson Brothers Limited | Stabilizing polymers and polymer films |
| US4994511A (en) * | 1987-09-14 | 1991-02-19 | Shell Oil Company | Polyketone stabilization with dihydrocarbyldithiocarbamate salts |
| EP0934984A4 (en) * | 1996-02-21 | 2000-01-19 | Kaneka Corp | Curable composition |
| WO2006058856A1 (en) * | 2004-12-03 | 2006-06-08 | Ciba Specialty Chemicals Holding Inc. | Ultraviolet light absorber stabilizer combination |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |