GB1154061A - Process for the Production of Oxalic Acid. - Google Patents
Process for the Production of Oxalic Acid.Info
- Publication number
- GB1154061A GB1154061A GB1257667A GB1257667A GB1154061A GB 1154061 A GB1154061 A GB 1154061A GB 1257667 A GB1257667 A GB 1257667A GB 1257667 A GB1257667 A GB 1257667A GB 1154061 A GB1154061 A GB 1154061A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxalic acid
- nitric acid
- march
- production
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 title abstract 9
- 235000006408 oxalic acid Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 3
- 229910017604 nitric acid Inorganic materials 0.000 abstract 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/27—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids
- C07C51/275—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids of hydrocarbyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,154,061. Oxalic acid. RHONE-POULENC S.A. 17 March, 1967 [17 March, 1966], No. 12576/67. Heading C2C. Oxalic acid is prepared by oxidizing propylene by introducing to nitric acid at 10‹ to 40‹ C. and heating to 45‹ to 100‹ C., with the simultaneous removal of the nitrogen oxides. The nitric acid concentration in the solution is maintained in the range 50 to 75% by weight, and the molar ratio of propylene to 100% nitric acid maintained throughout at between 0À01 to 1 and 0À5 to 1. Oxygen or oxygen containing gas may be introduced before or during either heating stage, and an elevated pressure may be employed. The process may be continuous, and suitable reactor series are described.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR53808A FR1471632A (en) | 1965-03-26 | 1966-03-17 | Tab rule |
| FR53888A FR1501725A (en) | 1966-03-17 | 1966-03-17 | Process for obtaining oxalic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1154061A true GB1154061A (en) | 1969-06-04 |
Family
ID=26169266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1257667A Expired GB1154061A (en) | 1966-03-17 | 1967-03-17 | Process for the Production of Oxalic Acid. |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE695615A (en) |
| CH (1) | CH467740A (en) |
| DE (1) | DE1618816C3 (en) |
| ES (1) | ES338147A1 (en) |
| FR (1) | FR1501725A (en) |
| GB (1) | GB1154061A (en) |
| LU (1) | LU53206A1 (en) |
| NL (2) | NL6703693A (en) |
| SE (1) | SE350023B (en) |
-
0
- NL NL133042D patent/NL133042C/xx active
-
1966
- 1966-03-17 CH CH387567A patent/CH467740A/en unknown
- 1966-03-17 FR FR53888A patent/FR1501725A/en not_active Expired
-
1967
- 1967-03-09 NL NL6703693A patent/NL6703693A/xx unknown
- 1967-03-16 BE BE695615D patent/BE695615A/xx unknown
- 1967-03-16 SE SE369167A patent/SE350023B/xx unknown
- 1967-03-16 LU LU53206D patent/LU53206A1/xx unknown
- 1967-03-17 GB GB1257667A patent/GB1154061A/en not_active Expired
- 1967-03-17 ES ES338147A patent/ES338147A1/en not_active Expired
- 1967-03-17 DE DE1967R0045537 patent/DE1618816C3/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1618816A1 (en) | 1972-04-13 |
| NL6703693A (en) | 1967-09-18 |
| DE1618816C3 (en) | 1979-03-29 |
| BE695615A (en) | 1967-09-18 |
| NL133042C (en) | |
| FR1501725A (en) | 1967-11-18 |
| ES338147A1 (en) | 1968-04-01 |
| DE1618816B2 (en) | 1978-07-20 |
| CH467740A (en) | 1969-01-31 |
| LU53206A1 (en) | 1967-05-16 |
| SE350023B (en) | 1972-10-16 |
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