GB1149152A - A method of producing a gas rich in methane - Google Patents
A method of producing a gas rich in methaneInfo
- Publication number
- GB1149152A GB1149152A GB33489/67A GB3348967A GB1149152A GB 1149152 A GB1149152 A GB 1149152A GB 33489/67 A GB33489/67 A GB 33489/67A GB 3348967 A GB3348967 A GB 3348967A GB 1149152 A GB1149152 A GB 1149152A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- cracking
- nickel
- heated
- methane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 6
- 238000005336 cracking Methods 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 3
- 229910052759 nickel Inorganic materials 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1,149,152. Making combustible gas. METALLGESELLSCHAFT A.G. 20 July, 1967 [3 Sept., 1966], No. 33489/67. Heading C5E. In the preparation of a methane-rich gas, a normally liquid hydrocarbon having an upper boiling limit of 350‹ C. and containing from 6 to 30 carbon atoms per molecule is heated to 350-400‹ C. and passed, together with 1À5 to 3 kg. of steam per kg. of hydrocarbon also heated to 350-400‹ C., into a reactor in which it is cracked at below 450‹ C. using a catalyst comprising metallic cobalt or nickel on a magnesium silicate carrier, the resulting gas is cooled to 200-250‹ C., passed over a methanation catalyst and then scrubbed to reduce its carbon dioxide content to not more than 4% by volume. A suitable cracking catalyst contains 5-40% by weight of cobalt or nickel and may contain an activating addition of 0À05 to 3% by weight of platinum. The methanation catalyst may be the same as the cracking catalyst or may be a different catalyst such as an alumina carrier containing nickel. Sulphur compounds may be converted with added hydrogen in a catalytic desulphurization reaction carried out before the cracking. The cracking reaction may be carried out at a pressure of 20 atmospheres gauge or at normal pressure.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEM0070808 | 1966-09-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1149152A true GB1149152A (en) | 1969-04-16 |
Family
ID=7313634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33489/67A Expired GB1149152A (en) | 1966-09-03 | 1967-07-20 | A method of producing a gas rich in methane |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS548681B1 (en) |
| AT (1) | AT275704B (en) |
| CH (1) | CH457696A (en) |
| ES (1) | ES343372A1 (en) |
| FI (1) | FI44145B (en) |
| GB (1) | GB1149152A (en) |
| NO (1) | NO121970B (en) |
| SE (1) | SE361877B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2271333C2 (en) * | 2004-03-25 | 2006-03-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Hydrogen-containing gas generation process |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105797731B (en) * | 2016-04-15 | 2018-08-21 | 西安向阳航天材料股份有限公司 | A kind of high temperature resistant type methanation catalyst and preparation method thereof |
-
1967
- 1967-06-14 CH CH840067A patent/CH457696A/en unknown
- 1967-06-21 FI FI1748/67A patent/FI44145B/fi active
- 1967-06-26 SE SE09121/67*A patent/SE361877B/xx unknown
- 1967-07-13 NO NO169040A patent/NO121970B/no unknown
- 1967-07-20 GB GB33489/67A patent/GB1149152A/en not_active Expired
- 1967-07-24 ES ES343372A patent/ES343372A1/en not_active Expired
- 1967-08-21 AT AT764767A patent/AT275704B/en active
- 1967-09-03 JP JP5633567A patent/JPS548681B1/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2271333C2 (en) * | 2004-03-25 | 2006-03-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Hydrogen-containing gas generation process |
Also Published As
| Publication number | Publication date |
|---|---|
| CH457696A (en) | 1968-06-15 |
| NO121970B (en) | 1971-05-03 |
| AT275704B (en) | 1969-11-10 |
| FI44145B (en) | 1971-06-01 |
| ES343372A1 (en) | 1968-09-01 |
| DE1545463B2 (en) | 1976-04-01 |
| JPS548681B1 (en) | 1979-04-18 |
| SE361877B (en) | 1973-11-19 |
| DE1545463A1 (en) | 1970-01-29 |
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