GB1222772A - Hydrocracking process - Google Patents
Hydrocracking processInfo
- Publication number
- GB1222772A GB1222772A GB21288/69A GB2128869A GB1222772A GB 1222772 A GB1222772 A GB 1222772A GB 21288/69 A GB21288/69 A GB 21288/69A GB 2128869 A GB2128869 A GB 2128869A GB 1222772 A GB1222772 A GB 1222772A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vol
- lpg
- feed
- pressure
- propane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004517 catalytic hydrocracking Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical compound CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 230000002596 correlated effect Effects 0.000 abstract 1
- MEKDPHXPVMKCON-UHFFFAOYSA-N ethane;methane Chemical compound C.CC MEKDPHXPVMKCON-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- -1 hydrogen ions Chemical class 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000003350 kerosene Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/28—Propane and butane
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1,222,772. Making propane-butane mixtures. UNION OIL CO. OF CALIFORNIA. 25 April, 1969, No. 21288/69. Heading C5E. Propane-butane mixtures (LPG) are made by catalytic hydrocracking a mineral oil boiling below 650 F., and preferably below 500 F., at a temperature in the range 500 to 800 F. and at a pressure above 400 p.s.i.g. The catalyst comprises a minor amount of a Group VIII metal on a crystalline silicons zeolite base, e.g. Ni and/or Co on an alumino-silicate molecular sieve base. Suitable feedstocks are light and heavy gasolines, light gas oil and kerosene, and the feedstock should be completely vaporized in the reaction zone. Temperature, pressure and space velocity are correlated to give at least 40 vol. per cent LPG per pass, based on feed, and to minimize methane-ethane production, a maximum pressure of 3000 p.s.i.g. and space velocities in the range 0À5 to 12 being mentioned. Unconverted feedstock is recycled or passed to a second reactor. In the catalyst a substantial proportion of the ion-exchange capacity is satisfied by hydrogen ions or polyvalent metal ions, including rare eath metals. Natural or synthetic zeolites may be employed. In specific examples, C 5 and higher hydrocarbons amounting to over 50 vol. per cent of the feed are produced.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US377372A US3458299A (en) | 1964-06-23 | 1964-06-23 | Hydrocracking process |
| NL6906472A NL6906472A (en) | 1964-06-23 | 1969-04-25 | |
| GB21288/69A GB1222772A (en) | 1964-06-23 | 1969-04-25 | Hydrocracking process |
| DE19691923808 DE1923808A1 (en) | 1964-06-23 | 1969-05-09 | Hydrocracking process |
| FR6915427A FR2061828A7 (en) | 1964-06-23 | 1969-05-13 |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37737264A | 1964-06-23 | 1964-06-23 | |
| NL6906472A NL6906472A (en) | 1964-06-23 | 1969-04-25 | |
| GB21288/69A GB1222772A (en) | 1964-06-23 | 1969-04-25 | Hydrocracking process |
| DE19691923808 DE1923808A1 (en) | 1964-06-23 | 1969-05-09 | Hydrocracking process |
| FR6915427A FR2061828A7 (en) | 1964-06-23 | 1969-05-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1222772A true GB1222772A (en) | 1971-02-17 |
Family
ID=33163180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21288/69A Expired GB1222772A (en) | 1964-06-23 | 1969-04-25 | Hydrocracking process |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3458299A (en) |
| DE (1) | DE1923808A1 (en) |
| FR (1) | FR2061828A7 (en) |
| GB (1) | GB1222772A (en) |
| NL (1) | NL6906472A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3531267A (en) * | 1965-06-17 | 1970-09-29 | Chevron Res | Process for manufacturing fuel gas and synthesis gas |
| US4199328A (en) * | 1978-12-28 | 1980-04-22 | Texaco Inc. | Process for producing methane from naphtha |
| ITMI20040299A1 (en) * | 2004-02-23 | 2004-05-20 | Polimeri Europa Spa | PROCESS AND CATALYSTS FOR THE PRODUCTION OF LINEAR ALCANS |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2560433A (en) * | 1948-07-16 | 1951-07-10 | Gulf Research Development Co | Desulfurization of hydrocarbon oils |
| US2830880A (en) * | 1954-12-24 | 1958-04-15 | Hercules Powder Co Ltd | Catalytic treatment of sulfur-contaminated hydrocarbons for the production of hydrogen |
| NL106917C (en) * | 1957-12-12 | 1900-01-01 | ||
| US3069351A (en) * | 1959-07-17 | 1962-12-18 | Socony Mobil Oil Co Inc | Utilization of reformer make gas |
| US3077448A (en) * | 1960-05-03 | 1963-02-12 | Kellogg M W Co | Desulfurization process |
| GB930512A (en) * | 1961-01-04 | 1963-07-03 | Socony Mobil Oil Co Inc | Treatment of petroleum hydrocarbon mixtures |
| US3144414A (en) * | 1961-03-21 | 1964-08-11 | California Research Corp | Process for increasing the hydrocracking activity of a supported nickel catalyst using phosphorous pentafluoride |
| US3325465A (en) * | 1963-03-29 | 1967-06-13 | Mobil Oil Corp | Polymerization |
| US3329627A (en) * | 1963-04-19 | 1967-07-04 | Exxon Research Engineering Co | Synthetic zeolites |
| US3325316A (en) * | 1965-03-29 | 1967-06-13 | Gilmour C Macdonald | Pyrotechnic compositions of metal matrix with oxide dispersed therein |
-
1964
- 1964-06-23 US US377372A patent/US3458299A/en not_active Expired - Lifetime
-
1969
- 1969-04-25 NL NL6906472A patent/NL6906472A/xx unknown
- 1969-04-25 GB GB21288/69A patent/GB1222772A/en not_active Expired
- 1969-05-09 DE DE19691923808 patent/DE1923808A1/en active Pending
- 1969-05-13 FR FR6915427A patent/FR2061828A7/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2061828A7 (en) | 1971-06-25 |
| US3458299A (en) | 1969-07-29 |
| DE1923808A1 (en) | 1970-11-19 |
| NL6906472A (en) | 1970-10-27 |
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