GB1011909A - Treatment agents and antistatic finishes for materials of synthetic macromolecular substances, and a process for their application - Google Patents
Treatment agents and antistatic finishes for materials of synthetic macromolecular substances, and a process for their applicationInfo
- Publication number
- GB1011909A GB1011909A GB3486864A GB3486864A GB1011909A GB 1011909 A GB1011909 A GB 1011909A GB 3486864 A GB3486864 A GB 3486864A GB 3486864 A GB3486864 A GB 3486864A GB 1011909 A GB1011909 A GB 1011909A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- radical
- stearic acid
- glycol
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002521 macromolecule Polymers 0.000 title abstract 2
- 239000000463 material Substances 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 10
- 235000021355 Stearic acid Nutrition 0.000 abstract 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 5
- 239000008117 stearic acid Substances 0.000 abstract 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 3
- 239000002202 Polyethylene glycol Substances 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 3
- 150000004985 diamines Chemical class 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 230000001804 emulsifying effect Effects 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- 150000004668 long chain fatty acids Chemical class 0.000 abstract 2
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 1
- TZGPACAKMCUCKX-UHFFFAOYSA-N 2-hydroxyacetamide Chemical compound NC(=O)CO TZGPACAKMCUCKX-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- -1 ether alcohols Chemical class 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229920002994 synthetic fiber Polymers 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds, used for treating synthetic fibres &c. (see Division D1), of the formula <FORM:1011909/C3/1> where R1 is hydrogen, an alkyl radical of 1-4 carbon atoms or hydroxy alkyl of 2-4 carbon atoms, X denotes a radical of the formula -COR2 or -A3OCOR2, R2 is an alkyl radica of 10-20 carbon atoms, (A1-O) is an ethyleneoxy and/or propylene-oxy radical, A2 is an alkylene radical of 2-5 carbon atoms, A3 is an alkylene radical of 2-4 carbon atoms and n is 5-35. The compounds may be prepared either (1) by cyanoethylating a polyalkylene glycol, hydrogenating, and reacting the resultant diamine with a long chain fatty acid or an amide-forming derivative of such an acid, or (2) by forming the dichloride of the polyalkylene glycol, reacting this with a primary alkylamine or a primary or secondary hydroxyalkylamine and acylating the resultant diamine with a long chain fatty acid or an ester- or amide-forming derivative of such an acid. In examples: (A) acrylonitrile is added to polyethylene glycol (mol. wt. 810) and sodium methylate. After neutralization the product is hydrogenated and heated with stearic acid. (B) Polyethylene glycol (mol. wt. 810) is reacted with thionyl chloride. The dichloride obtained is stirred in monoethanolamine and anhydrous sodium carbonate, and the diamine formed is reacted with stearic acid. In further examples, stearic acid is reacted with o ,o 1-di-(aminopropyl)-octadecaethylene glycol ether and with o ,o 1-di-(aminopropyl)-tridecaethylene glycol ether. The treating agent may be used in aqueous solutions or dispersions which also contain dispersing, emulsifying or stabilizing agents, e.g. adducts of ethylene oxide with long chain alcohols, mercaptans, amines, carboxylic acids or esters or amides thereof, fatty alcohol sulphonates, alkylaryl sulphonates and partial esters of polybasic organic or inorganic acids and long chain alcohol or ether alcohols.ALSO:Textile materials of synthetic macromolecular substances are treated and given an antistatic finis by polyalkylene glycolamide of the formula <FORM:1011909/D1-D2/1> where R1 is hydrogen, an alkyl radical of 1-4 carbon atom or hydroxy alkyl of 2-4 carbon atoms X is a radical of the formula-COR2 or -A3-OCOR2 R2 is an alkyl radical having 10-20 carbon atoms (A (A1-O) is an ethyleneoxy and/or propyleneoxy radical, A2 is an alkylene radical having 2-5 carbon atoms, A3 is an alkylene radical haveing 2-4 carbon atoms, and n is 5-35. The treating agent is applied in the form of an aqueous solution or dispersion, or as a solution in an organic liquid. A dispersing, emulsifying or stabilising agent may also be present. Examples describe the treatment of polyester fibres, including dyed fibres and union cloth consisting of 45% wool and 55% polyester fibre, with, e.g. aqueous solutions of the reaction product of (1) stearic acid and w, w1-di-(aminopropyl)-octadeca-ethylent glycol either, (2) stearic acid and the reaction product of diethanl amine and the dichloride of a polyethylene glycol (mol wt 800).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0073303 | 1963-08-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1011909A true GB1011909A (en) | 1965-12-01 |
Family
ID=6977800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3486864A Expired GB1011909A (en) | 1963-08-29 | 1964-08-26 | Treatment agents and antistatic finishes for materials of synthetic macromolecular substances, and a process for their application |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE652361A (en) |
| CH (1) | CH417520A (en) |
| DE (1) | DE1444031A1 (en) |
| FR (1) | FR1411299A (en) |
| GB (1) | GB1011909A (en) |
| NL (1) | NL6409958A (en) |
-
1963
- 1963-08-29 DE DE19631444031 patent/DE1444031A1/en active Pending
-
1964
- 1964-07-21 CH CH952964A patent/CH417520A/en unknown
- 1964-08-26 GB GB3486864A patent/GB1011909A/en not_active Expired
- 1964-08-27 BE BE652361D patent/BE652361A/xx unknown
- 1964-08-27 NL NL6409958A patent/NL6409958A/xx unknown
- 1964-08-28 FR FR986529A patent/FR1411299A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL6409958A (en) | 1965-03-01 |
| FR1411299A (en) | 1965-09-17 |
| CH417520A (en) | 1966-02-28 |
| BE652361A (en) | 1965-03-01 |
| DE1444031A1 (en) | 1968-12-12 |
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