GB426956A - A process for improving textile materials - Google Patents
A process for improving textile materialsInfo
- Publication number
- GB426956A GB426956A GB28070/33A GB2807033A GB426956A GB 426956 A GB426956 A GB 426956A GB 28070/33 A GB28070/33 A GB 28070/33A GB 2807033 A GB2807033 A GB 2807033A GB 426956 A GB426956 A GB 426956A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- ethylene oxide
- formaldehyde
- moles
- silk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 13
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 6
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 5
- 239000000194 fatty acid Substances 0.000 abstract 5
- 229930195729 fatty acid Natural products 0.000 abstract 5
- 150000004665 fatty acids Chemical class 0.000 abstract 5
- 150000001412 amines Chemical class 0.000 abstract 4
- -1 ethyl butanolamine Chemical compound 0.000 abstract 4
- 229920002955 Art silk Polymers 0.000 abstract 3
- 229920000742 Cotton Polymers 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 150000001408 amides Chemical class 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 3
- 150000002894 organic compounds Chemical class 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- 239000005642 Oleic acid Substances 0.000 abstract 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000003240 coconut oil Substances 0.000 abstract 2
- 235000019864 coconut oil Nutrition 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 abstract 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 abstract 2
- 229960004418 trolamine Drugs 0.000 abstract 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 1
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 abstract 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical group C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 abstract 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 abstract 1
- IWSZDQRGNFLMJS-UHFFFAOYSA-N 2-(dibutylamino)ethanol Chemical compound CCCCN(CCO)CCCC IWSZDQRGNFLMJS-UHFFFAOYSA-N 0.000 abstract 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 abstract 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 abstract 1
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 abstract 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 1
- 235000021314 Palmitic acid Nutrition 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- 108010077895 Sarcosine Proteins 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229940037003 alum Drugs 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000007514 bases Chemical class 0.000 abstract 1
- MIAUJDCQDVWHEV-UHFFFAOYSA-N benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1S(O)(=O)=O MIAUJDCQDVWHEV-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical class CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 abstract 1
- 150000002169 ethanolamines Chemical class 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 125000005456 glyceride group Chemical group 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical class CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 229940055577 oleyl alcohol Drugs 0.000 abstract 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 abstract 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 abstract 1
- 229960003656 ricinoleic acid Drugs 0.000 abstract 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229940043230 sarcosine Drugs 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229950000244 sulfanilic acid Drugs 0.000 abstract 1
- 229960003080 taurine Drugs 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Textile materials are rendered resistant to creasing by impregnating them with aqueous solutions of formaldehyde (or compounds supplying formaldehyde) in the presence of non-oxidizing acid-reacting compounds, acting on them with organic compounds containing a basic group and at least one radicle with 4 or more carbon atoms, and heating them. The organic compounds last mentioned must not be of resinous character or capable of forming resins with formaldehyde. The process is particularly useful with cotton, mercerized or other hydrated cellulose, artificial silk, linen, and mixed fabrics containing for instance cotton and artificial silk, cotton and wool, or silk and artificial silk. Formaldehyde may be employed as a 30 per cent solution, or as trioxymethylene. In the organic compounds, the basic group may be nitrogenous or of the oxonium type. Suitable compounds include dibutylamines, diamylamines, dodecylamine, cetylamine, octodecylamine, monooleyl amine, monostearyl amine; dodecyl, cetyl, oleyl, and octodecyl ethanolamines; sulphanilic acid; the esters or amides of higher fatty acids and hydroxyalkylamines such as mono, di, and triethanolamine, ethyl butanolamine, or cyclohexyl propanolamine, e.g. triethanol amine mono-oleic acid ester, dibutyl ethanol amine, palmitic acid ester, coco-nut oil fatty acid monoethanol amide, stearic acid monoethanolamide or oleic acid diethanol amide; the condensation products of ethylene oxide with amines or with esters or amides from fatty acids and alkylolamines; condensation products of ethylene oxide with fatty acids of high molecular weight, e.g. coco-nut oil, fatty acid, palmitic, stearic, ricinoleic, or oleic acid, or with their glycerides, or with the corresponding alcohols. The products from 20 moles of ethylene oxide and 1 mole of oleyl alcohol, or from 10 moles of ethylene oxide and 1 of dodecyl alcohol, or from 40 moles of ethylene oxide and 1 of castor oil, are given as instances; from 4 to 50 moles of ethylene oxide may however be employed for each mole of acid or alcohol. The acid-reacting substance may be hydrochloric,sulphuric,amino-sulphonic, thiocyanic, acetic, chloracetic, ethionic, or a benzene disulphonic acid, or aluminium chloride or alum, and is used in such quantity that the bath has a faintly acid reaction. If insoluble the amines are insoluble, the acid is slightly in excess of that required to convert them into soluble salts. The textiles may be impregnated with a solution of all the reagents, squeezed or hydroextracted, dried, and then heated for a short time to 100--160 DEG or 200 DEG C.; or they may be successively treated with an acid-formaldehyde bath and with a solution of the basic compound, which may be used in proportions between 0,1 and 100 grm. per litre, but preferably not more than 50. Examples are given of the treatment of artificial viscose silk. Specification 414,576 is referred to. According to the Provisional Specification the nitrogenous compound may be glycocoll, sarcosine, or taurine.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2118685X | 1933-08-19 | ||
| DE452248X | 1934-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB426956A true GB426956A (en) | 1935-04-11 |
Family
ID=32043849
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28070/33A Expired GB426956A (en) | 1933-08-19 | 1933-10-11 | A process for improving textile materials |
| GB34531/35A Expired GB452248A (en) | 1933-08-19 | 1935-12-12 | Improvements in or relating to the treatment of textile materials |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34531/35A Expired GB452248A (en) | 1933-08-19 | 1935-12-12 | Improvements in or relating to the treatment of textile materials |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US2118685A (en) |
| DE (1) | DE907287C (en) |
| FR (2) | FR777426A (en) |
| GB (2) | GB426956A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2420730A (en) * | 1944-06-09 | 1947-05-20 | Du Pont | Treatment of polymers with acylamides and aldehydes |
| US3089747A (en) * | 1958-04-04 | 1963-05-14 | American Viscose Corp | Method of preparing rayon plisse |
| BE594748A (en) * | 1959-06-10 | |||
| US3465036A (en) * | 1964-07-07 | 1969-09-02 | American Cyanamid Co | 2-carboxyethoxymethyl-tris (2-(n-methylolcarbamoyl)-ethoxymethyl) methane |
| CN103243433A (en) * | 2013-05-21 | 2013-08-14 | 海安县鑫荣纺织有限责任公司 | Blended yarn of cotton fiber, coconut fiber and silkworm pupa protein fiber |
| CN114349933B (en) * | 2021-12-24 | 2023-05-30 | 万华化学集团股份有限公司 | Self-repairing waterborne polyurethane and preparation method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE492664C (en) * | 1920-05-19 | 1930-02-27 | Hans Karplus Dr | Process for the finishing of rayon, staple fiber and fabrics made from them |
-
1933
- 1933-10-11 GB GB28070/33A patent/GB426956A/en not_active Expired
-
1934
- 1934-08-13 US US739714A patent/US2118685A/en not_active Expired - Lifetime
- 1934-08-17 FR FR777426D patent/FR777426A/en not_active Expired
- 1934-12-13 DE DEB5964D patent/DE907287C/en not_active Expired
-
1935
- 1935-12-05 US US53005A patent/US2143352A/en not_active Expired - Lifetime
- 1935-12-10 FR FR46935D patent/FR46935E/en not_active Expired
- 1935-12-12 GB GB34531/35A patent/GB452248A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2118685A (en) | 1938-05-24 |
| FR46935E (en) | 1936-11-07 |
| US2143352A (en) | 1939-01-10 |
| FR777426A (en) | 1935-02-19 |
| GB452248A (en) | 1936-08-19 |
| DE907287C (en) | 1954-03-22 |
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