GB1088370A - Improvements in or relating to the bonding of elastomeric materials to metal and composite structures so obtained - Google Patents
Improvements in or relating to the bonding of elastomeric materials to metal and composite structures so obtainedInfo
- Publication number
- GB1088370A GB1088370A GB43206/66A GB4320666A GB1088370A GB 1088370 A GB1088370 A GB 1088370A GB 43206/66 A GB43206/66 A GB 43206/66A GB 4320666 A GB4320666 A GB 4320666A GB 1088370 A GB1088370 A GB 1088370A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- zinc
- cobalt
- bonding
- pentadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002131 composite material Substances 0.000 title 1
- 239000000463 material Substances 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 229920001897 terpolymer Polymers 0.000 abstract 4
- 229920001971 elastomer Polymers 0.000 abstract 3
- 239000005060 rubber Substances 0.000 abstract 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 150000001868 cobalt Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 abstract 1
- HITROERJXNWVOI-SOFGYWHQSA-N (5e)-octa-1,5-diene Chemical compound CC\C=C\CCC=C HITROERJXNWVOI-SOFGYWHQSA-N 0.000 abstract 1
- RCJMVGJKROQDCB-UHFFFAOYSA-N 1,3-dimethyl-1,3-butadiene Natural products CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 abstract 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 abstract 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 1
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 abstract 1
- DRWYRROCDFQZQF-UHFFFAOYSA-N 2-methylpenta-1,4-diene Chemical compound CC(=C)CC=C DRWYRROCDFQZQF-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 239000004606 Fillers/Extenders Substances 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 229940022663 acetate Drugs 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000005540 biological transmission Effects 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- IIGAELMXVLEZPM-GRVYQHKQSA-L cobalt(2+);(9z,12z)-octadeca-9,12-dienoate Chemical compound [Co+2].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O.CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O IIGAELMXVLEZPM-GRVYQHKQSA-L 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 230000002787 reinforcement Effects 0.000 abstract 1
- 229940114926 stearate Drugs 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract 1
- 229960002447 thiram Drugs 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/0054—Producing footwear by compression moulding, vulcanising or the like; Apparatus therefor
- B29D35/0063—Moulds
- B29D35/0072—Last constructions; Mountings therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
Vulcanizable ethylene/a -olefin/diene terpolymer rubbers for bonding to zinc have incorporated therein 5 to 20 weight per cent of a cobalt salt of a carboxylic acid. The rubber may be a copolymer of ethylene, propylene and butadiene, isoprene, 2,3-dimethylbutadiene, 1,4-pentadiene, 2 - methyl - 1,4 - pentadiene, 1,5-hexadiene, 2 - methyl - 1,5 - hexadiene, 1,5-octadiene, dicyclopentadiene, 2-methylene-2,5-norbornene or 4,7,8,9 - tetrahydromethylindene. The terpolymer may be oil-extended. Specified cobalt salts are cobalt linoleate, stearate, oleate, acetate and naphthenate. The preferred vulcanizing agent is sulphur, and conventional accelerators, fillers, plasticizers and antioxidants may also be present. The compositions may be applied to zinc or zinc-plated steel, iron or aluminium articles, e.g. tyre cords or reinforcements for tubes, transmission belts or converyer belts, and simultaneously bonded and vulcanized. Examples describe the addition of cobalt naphthenate to compositions comprising mercaptobenzothiazole, tetramethyl thiuram disulphide, zinc oxide, carbon black, stearic acid, sulphur and ethylene/propylene/ cyclooctadiene terpolymers with and without extender oil, and various commercial ethylene terpolymer rubbers.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT973065 | 1965-04-27 | ||
| IT2209065 | 1965-10-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1088370A true GB1088370A (en) | 1967-10-25 |
Family
ID=26326267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB43206/66A Expired GB1088370A (en) | 1965-04-27 | 1966-09-28 | Improvements in or relating to the bonding of elastomeric materials to metal and composite structures so obtained |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1694753A1 (en) |
| ES (1) | ES332319A1 (en) |
| GB (1) | GB1088370A (en) |
| NL (1) | NL6613974A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2616613A1 (en) * | 1975-05-22 | 1976-12-09 | Yokohama Rubber Co Ltd | RUBBER MASS |
| DE2608113A1 (en) * | 1975-10-04 | 1977-04-14 | Yokohama Rubber Co Ltd | RUBBER MASS |
| DE2750909A1 (en) * | 1977-11-14 | 1979-05-17 | Continental Gummi Werke Ag | Rubber compsn. for direct bonding of satd. polymers to metals, - contg. cobalt cpd., phenolic resin and sulphur |
| EP0014067A1 (en) * | 1979-01-16 | 1980-08-06 | Uniroyal, Inc. | Method of bonding elastomers to fibres and an elastomer composition |
-
1966
- 1966-09-28 GB GB43206/66A patent/GB1088370A/en not_active Expired
- 1966-09-28 ES ES0332319A patent/ES332319A1/en not_active Expired
- 1966-10-04 DE DE19661694753 patent/DE1694753A1/en active Pending
- 1966-10-04 NL NL6613974A patent/NL6613974A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2616613A1 (en) * | 1975-05-22 | 1976-12-09 | Yokohama Rubber Co Ltd | RUBBER MASS |
| DE2608113A1 (en) * | 1975-10-04 | 1977-04-14 | Yokohama Rubber Co Ltd | RUBBER MASS |
| DE2750909A1 (en) * | 1977-11-14 | 1979-05-17 | Continental Gummi Werke Ag | Rubber compsn. for direct bonding of satd. polymers to metals, - contg. cobalt cpd., phenolic resin and sulphur |
| EP0014067A1 (en) * | 1979-01-16 | 1980-08-06 | Uniroyal, Inc. | Method of bonding elastomers to fibres and an elastomer composition |
Also Published As
| Publication number | Publication date |
|---|---|
| ES332319A1 (en) | 1967-07-16 |
| DE1694753A1 (en) | 1971-07-08 |
| NL6613974A (en) | 1967-04-05 |
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