GB1083989A - Improvements in and relating to the electrodeposition of silver-antimony alloys - Google Patents
Improvements in and relating to the electrodeposition of silver-antimony alloysInfo
- Publication number
- GB1083989A GB1083989A GB8976/65A GB897665A GB1083989A GB 1083989 A GB1083989 A GB 1083989A GB 8976/65 A GB8976/65 A GB 8976/65A GB 897665 A GB897665 A GB 897665A GB 1083989 A GB1083989 A GB 1083989A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silver
- antimony
- added
- electrodeposition
- relating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LGFYIAWZICUNLK-UHFFFAOYSA-N antimony silver Chemical group [Ag].[Sb] LGFYIAWZICUNLK-UHFFFAOYSA-N 0.000 title abstract 2
- 229910001245 Sb alloy Inorganic materials 0.000 title 1
- 239000002140 antimony alloy Substances 0.000 title 1
- 238000004070 electrodeposition Methods 0.000 title 1
- BIHLHMHULOMJLI-UHFFFAOYSA-N 3-[bis(2-hydroxyethyl)amino]propan-1-ol Chemical compound OCCCN(CCO)CCO BIHLHMHULOMJLI-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal selenocyanate Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001463 antimony compounds Chemical class 0.000 abstract 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- HKSGQTYSSZOJOA-UHFFFAOYSA-N potassium argentocyanide Chemical compound [K+].[Ag+].N#[C-].N#[C-] HKSGQTYSSZOJOA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/64—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of silver
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
A hard silver-antimony plate is formed using as electrolyte a silver salt solution to which is added a complex of antimony made by mixing an alkanolamine with an inorganic antimony compound. In examples, a bath containing 30 to 35g potassium silver cyanide per litre, fue Na CN, and Na2 Co3 has added to it 0.5 to 1g of a product mode by heating at 40 DEG C. a mixture of 1 mol. Sb Cl3 and 3 to 6 mols. of triethanolamine, methyldiethanolamine, diethanolpropanolamine or like compound. A small amount of alkali metal selenocyanate is added to improve the lustre.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH34943A DE1246349B (en) | 1964-04-10 | 1964-04-10 | Bath for the galvanic deposition of silver-antimony alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1083989A true GB1083989A (en) | 1967-09-20 |
Family
ID=7433313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8976/65A Expired GB1083989A (en) | 1964-04-10 | 1965-03-02 | Improvements in and relating to the electrodeposition of silver-antimony alloys |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3425917A (en) |
| CH (1) | CH453029A (en) |
| DE (1) | DE1246349B (en) |
| GB (1) | GB1083989A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013142765A1 (en) * | 2012-03-23 | 2013-09-26 | Technic, Inc. | Silver antimony coatings and connectors |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2330962A (en) * | 1941-03-31 | 1943-10-05 | Parke Davis & Co | Organic compound of antimony and process for making it |
| US2555375A (en) * | 1948-11-13 | 1951-06-05 | Battelle Development Corp | Process of plating bright silver alloy |
| US2817628A (en) * | 1953-10-16 | 1957-12-24 | Gen Motors Corp | Antimony plating bath |
| US2801959A (en) * | 1953-12-03 | 1957-08-06 | Harshaw Chem Corp | Alkaline antimony plating |
| US2735809A (en) * | 1955-01-31 | 1956-02-21 | Mirror bright silver plating | |
| US2777810A (en) * | 1956-10-03 | 1957-01-15 | Elechem Corp | Bath for electroplating silver |
| DE1182014B (en) * | 1960-04-12 | 1964-11-19 | Riedel & Co | Bath for the galvanic deposition of silver-antimony or silver-bismuth alloys of high hardness |
| DE1140425B (en) * | 1961-05-19 | 1962-11-29 | Schering Ag | Alkaline reacting complex baths for the galvanic deposition of silver coatings |
| NL290554A (en) * | 1962-03-22 |
-
1964
- 1964-04-10 DE DESCH34943A patent/DE1246349B/en active Pending
-
1965
- 1965-03-02 GB GB8976/65A patent/GB1083989A/en not_active Expired
- 1965-03-29 CH CH428465A patent/CH453029A/en unknown
- 1965-04-05 US US445701A patent/US3425917A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3425917A (en) | 1969-02-04 |
| DE1246349B (en) | 1967-08-03 |
| CH453029A (en) | 1968-05-31 |
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