GB1063617A - Manufacture of organic acids - Google Patents
Manufacture of organic acidsInfo
- Publication number
- GB1063617A GB1063617A GB2424264A GB2424264A GB1063617A GB 1063617 A GB1063617 A GB 1063617A GB 2424264 A GB2424264 A GB 2424264A GB 2424264 A GB2424264 A GB 2424264A GB 1063617 A GB1063617 A GB 1063617A
- Authority
- GB
- United Kingdom
- Prior art keywords
- manufacture
- catalyst
- organic acids
- nickel
- kgm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000007524 organic acids Chemical class 0.000 title 1
- 235000005985 organic acids Nutrition 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- -1 cobalt metals Chemical class 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000005673 monoalkenes Chemical class 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- NAVSKFYJNZQECG-UHFFFAOYSA-N nickel;propanoic acid Chemical compound [Ni].CCC(O)=O NAVSKFYJNZQECG-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the production of aliphatic carboxylic acids comprises contacting in the liquid phase a monoolefin containing 1-5 carbon atoms, carbon monoxide and water at a temperature of from 260 DEG to 350 DEG C. and a pressure of from 2500 to 6000 p.s.i.g. (176-423 kgm./cm.2) in the presence of a carbonylation catalyst and in the presence of boric acid. Catalysts specified include nickel and cobalt metals, alloys, salts, oxides and hydrides. The examples relate to the preparation of propionic acid using ethylene as olefinic starting material and nickel propionate as catalyst in continuous processes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2424264A GB1063617A (en) | 1964-06-11 | 1964-06-11 | Manufacture of organic acids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2424264A GB1063617A (en) | 1964-06-11 | 1964-06-11 | Manufacture of organic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1063617A true GB1063617A (en) | 1967-03-30 |
Family
ID=10208668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2424264A Expired GB1063617A (en) | 1964-06-11 | 1964-06-11 | Manufacture of organic acids |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1063617A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5705683A (en) * | 1994-07-13 | 1998-01-06 | Basf Aktiengesellschaft | Carbonylation of olefins |
-
1964
- 1964-06-11 GB GB2424264A patent/GB1063617A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5705683A (en) * | 1994-07-13 | 1998-01-06 | Basf Aktiengesellschaft | Carbonylation of olefins |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Wakamatsu et al. | Synthesis of N-acyl amino-acids by a carbonylation reaction | |
| GB1004895A (en) | Process for the production of isophthalic and terephthalic acids | |
| JPS523030A (en) | Process for manufacturing high purity terephthalic acid | |
| ES405581A1 (en) | Production of mainly linear aldehydes | |
| GB1063617A (en) | Manufacture of organic acids | |
| SE7416284L (en) | ||
| GB1071350A (en) | Process for the preparation of high purity terephthalic acid | |
| GB1469147A (en) | Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in an organic solvent | |
| ES461021A1 (en) | Process for the preparation of iso- or terephthalic acid | |
| GB987274A (en) | Improvements in and relating to the production of halides of unsaturated aliphatic acids or derivatives thereof | |
| ES404182A1 (en) | Preparation of terephthalic acid isophthalic acid and the monomethyl esters thereof | |
| GB1266391A (en) | ||
| GB1016087A (en) | Process for producing organic carboxylic acids | |
| GB817622A (en) | Improvements in or relating to catalytic processes for preparing ketones from secondary alcohols | |
| GB952718A (en) | Process for producing acetaldehyde | |
| ES8501731A1 (en) | Catalyst system and a process for preparing acetic acid by catalytic rearrangement of methyl formate. | |
| SU437745A1 (en) | The method of producing acetic acid and methyl acetate | |
| GB708441A (en) | Synthesis of oxygenated organic compounds | |
| ES438732A1 (en) | Process for the preparation of acetoxybutanal | |
| GB785985A (en) | Improvements in the carbonylation of olefinic compounds | |
| GB787258A (en) | Process for the production of ketones and carboxylic acids | |
| SU481303A1 (en) | Method for preparing catalyst for dehydrating higher fatty acid esters | |
| GB1072429A (en) | N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone | |
| GB1421278A (en) | Process for the production of primary amines | |
| ES221462A1 (en) | A manufacturing procedure of tereftal acid (Machine-translation by Google Translate, not legally binding) |