GB1016087A - Process for producing organic carboxylic acids - Google Patents
Process for producing organic carboxylic acidsInfo
- Publication number
- GB1016087A GB1016087A GB1249764A GB1249764A GB1016087A GB 1016087 A GB1016087 A GB 1016087A GB 1249764 A GB1249764 A GB 1249764A GB 1249764 A GB1249764 A GB 1249764A GB 1016087 A GB1016087 A GB 1016087A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- carboxylic acids
- organic carboxylic
- methylbutene
- diisobutylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001735 carboxylic acids Chemical class 0.000 title 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 abstract 3
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- LAAVYEUJEMRIGF-UHFFFAOYSA-N 2,4,4-trimethylpent-2-ene Chemical compound CC(C)=CC(C)(C)C LAAVYEUJEMRIGF-UHFFFAOYSA-N 0.000 abstract 1
- LXQPBCHJNIOMQU-UHFFFAOYSA-N 2,4-dimethylpent-1-ene Chemical compound CC(C)CC(C)=C LXQPBCHJNIOMQU-UHFFFAOYSA-N 0.000 abstract 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 abstract 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 abstract 1
- -1 Aliphatic monocarboxylic acids Chemical class 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aliphatic monocarboxylic acids are prepared by adding an olefine <FORM:1016087/C2/1> to a reaction zone containing aqueous solution of sulphuric acid (82-88%), saturated with carbon monoxide. R1 and R2 are alkyl radicals and R3 and R4 are alkyl radicals or hydrogen, the total C atoms in the olefine being 4-16. The reaction is in the liquid phase and water is added to the reaction product to obtain the acid. Isobutylene, diisobutylene, 2-methylbutene-1, 2-methylbutene-2, 2,4-dimethylpentene - 2, 2,4,4 - trimethylpentene - 1, 2,2,4 - trimethyl - pentene - 2,2 - methylpentadecene - 2. Examples describe the preparation of isononanoic acid from diisobutylene, and pivalic acid from isobutylene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1249764A GB1016087A (en) | 1964-03-24 | 1964-03-24 | Process for producing organic carboxylic acids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1249764A GB1016087A (en) | 1964-03-24 | 1964-03-24 | Process for producing organic carboxylic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1016087A true GB1016087A (en) | 1966-01-05 |
Family
ID=10005686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1249764A Expired GB1016087A (en) | 1964-03-24 | 1964-03-24 | Process for producing organic carboxylic acids |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1016087A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0187714A3 (en) * | 1985-01-09 | 1988-04-27 | Rohm And Haas Company | Process for separating components of mixtures comprising sulfuric acid and carboxylic acid |
| EP0296275A1 (en) * | 1987-06-23 | 1988-12-28 | Idemitsu Petrochemical Co. Ltd. | Carboxylic acid mixture and process for producing the same |
| EP0298431A1 (en) * | 1987-07-06 | 1989-01-11 | Idemitsu Petrochemical Co. Ltd. | Process for producing carboxylic acid |
| US5223641A (en) * | 1986-01-14 | 1993-06-29 | Idemitsu Petrochemical Chemical Company, Limited | Carboxylic acid mixtures and process for producing the same |
-
1964
- 1964-03-24 GB GB1249764A patent/GB1016087A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0187714A3 (en) * | 1985-01-09 | 1988-04-27 | Rohm And Haas Company | Process for separating components of mixtures comprising sulfuric acid and carboxylic acid |
| US5223641A (en) * | 1986-01-14 | 1993-06-29 | Idemitsu Petrochemical Chemical Company, Limited | Carboxylic acid mixtures and process for producing the same |
| EP0296275A1 (en) * | 1987-06-23 | 1988-12-28 | Idemitsu Petrochemical Co. Ltd. | Carboxylic acid mixture and process for producing the same |
| EP0298431A1 (en) * | 1987-07-06 | 1989-01-11 | Idemitsu Petrochemical Co. Ltd. | Process for producing carboxylic acid |
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