GB1045293A - Novel sulfur-curable terpolymers and process for the preparation thereof - Google Patents
Novel sulfur-curable terpolymers and process for the preparation thereofInfo
- Publication number
- GB1045293A GB1045293A GB752464A GB752464A GB1045293A GB 1045293 A GB1045293 A GB 1045293A GB 752464 A GB752464 A GB 752464A GB 752464 A GB752464 A GB 752464A GB 1045293 A GB1045293 A GB 1045293A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium hydride
- preparation
- groups
- terpolymers
- curable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001897 terpolymer Polymers 0.000 title abstract 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 3
- 229910000091 aluminium hydride Inorganic materials 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002879 Lewis base Substances 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Linear amorphous sulphur-curable terpolymers are obtained by terpolymerizing two different mono-alpha-olefines with an alkenyl-cycloalkene using a catalyst comprising a compound of a transition metal of Groups IVb or Vb (Derning Table) and an aluminium hydride soluble in aromatic hydrocarbons, said aluminium hydride having the formula AlHXY where X and Y are hydrogen, halogen or <FORM:1045293/C3/1> groups, R1 and R2 being alkyl, aryl, alkaryl, cycloalkyl or the nitrogen atom may form part of a heterocyclic molecule. The aluminium hydride may be complexed with a Lewis base. Lists of catalysts components are given. In the examples ethylene, propylene and 4-vinyl-cyclohexene-1 are terpolymerized using vanadium or titanium tetrachloride and one of the following:-HCl2Al.O(C2H5)2; HAl.BrN(CH3)2; H2Al.N(CH3)2 and H3Al.N(CH3)3.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT391863 | 1963-02-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1045293A true GB1045293A (en) | 1966-10-12 |
Family
ID=11111960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB752464A Expired GB1045293A (en) | 1963-02-27 | 1964-02-24 | Novel sulfur-curable terpolymers and process for the preparation thereof |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1520853A1 (en) |
| GB (1) | GB1045293A (en) |
| LU (1) | LU45527A1 (en) |
| NL (1) | NL6401948A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6871140B1 (en) | 2000-02-25 | 2005-03-22 | Costar Group, Inc. | System and method for collection, distribution, and use of information in connection with commercial real estate |
-
1964
- 1964-02-24 GB GB752464A patent/GB1045293A/en not_active Expired
- 1964-02-24 DE DE19641520853 patent/DE1520853A1/en active Pending
- 1964-02-25 LU LU45527A patent/LU45527A1/xx unknown
- 1964-02-27 NL NL6401948A patent/NL6401948A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6871140B1 (en) | 2000-02-25 | 2005-03-22 | Costar Group, Inc. | System and method for collection, distribution, and use of information in connection with commercial real estate |
Also Published As
| Publication number | Publication date |
|---|---|
| LU45527A1 (en) | 1965-08-25 |
| DE1520853A1 (en) | 1970-01-29 |
| NL6401948A (en) | 1964-08-28 |
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