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GB1041046A - Oxidation of hydrocarbons and alcohols - Google Patents

Oxidation of hydrocarbons and alcohols

Info

Publication number
GB1041046A
GB1041046A GB42509/64A GB4250964A GB1041046A GB 1041046 A GB1041046 A GB 1041046A GB 42509/64 A GB42509/64 A GB 42509/64A GB 4250964 A GB4250964 A GB 4250964A GB 1041046 A GB1041046 A GB 1041046A
Authority
GB
United Kingdom
Prior art keywords
catalyst
hydrogen
alcohol
oxygen
give
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42509/64A
Inventor
George Wallace Hooper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB42509/64A priority Critical patent/GB1041046A/en
Publication of GB1041046A publication Critical patent/GB1041046A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/029—Preparation from hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process of oxidation of an aromatic, cycloaliphatic or olefinic hydrocarbon to give a phenol, alcohol or glycol respectively, or of an alcohol to give an aldehyde or ketone comprises contacting the hydrocarbon or the alcohol with a crude hydrogen peroxide solution produced by contacting hydrogen and oxygen in the presence of liquid water and an acid with a solid catalyst, the catalyst being capable of promoting the combination of hydrogen and oxygen to give hydrogen peroxide. The catalyst may, for example, comprise at least one element from Group Ib and/or Group VIII of the Periodic Table and a carrier. In a preferred embodiment of the process, hydrogen and oxygen are passed into an acidic water-containing liquid phase containing said catalyst and the organic compound which is to be oxidized. The decomposition of the hydrogen peroxide may be promoted by homogeneous catalysis or by radiation. Examples are given.
GB42509/64A 1962-06-21 1962-06-21 Oxidation of hydrocarbons and alcohols Expired GB1041046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB42509/64A GB1041046A (en) 1962-06-21 1962-06-21 Oxidation of hydrocarbons and alcohols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB42509/64A GB1041046A (en) 1962-06-21 1962-06-21 Oxidation of hydrocarbons and alcohols

Publications (1)

Publication Number Publication Date
GB1041046A true GB1041046A (en) 1966-09-01

Family

ID=10424747

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42509/64A Expired GB1041046A (en) 1962-06-21 1962-06-21 Oxidation of hydrocarbons and alcohols

Country Status (1)

Country Link
GB (1) GB1041046A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7307188B2 (en) 2004-04-09 2007-12-11 Gtc Technology, Inc. Purification of carboxylic acids by complexation with selective solvents
WO2011051643A1 (en) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Selective catalytic oxidation of c1-c3 alkanes
WO2011051642A1 (en) * 2009-10-29 2011-05-05 University College Cardiff Consultants, Ltd Hydrocarbon selective oxidation with heterogenous gold catalysts

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7307188B2 (en) 2004-04-09 2007-12-11 Gtc Technology, Inc. Purification of carboxylic acids by complexation with selective solvents
WO2011051643A1 (en) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Selective catalytic oxidation of c1-c3 alkanes
WO2011051642A1 (en) * 2009-10-29 2011-05-05 University College Cardiff Consultants, Ltd Hydrocarbon selective oxidation with heterogenous gold catalysts

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