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FR3081345B1 - Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote - Google Patents

Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote Download PDF

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Publication number
FR3081345B1
FR3081345B1 FR1854389A FR1854389A FR3081345B1 FR 3081345 B1 FR3081345 B1 FR 3081345B1 FR 1854389 A FR1854389 A FR 1854389A FR 1854389 A FR1854389 A FR 1854389A FR 3081345 B1 FR3081345 B1 FR 3081345B1
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fau
sio2
structural type
zeolith
structuring
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FR1854389A
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FR3081345A1 (fr
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Franco Raquel Martinez
Bogdan Harbuzaru
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to KR1020207033706A priority patent/KR102773805B1/ko
Priority to JP2020565770A priority patent/JP7493461B2/ja
Priority to CN201980034753.5A priority patent/CN112203763A/zh
Priority to US17/057,364 priority patent/US11560317B2/en
Priority to PCT/EP2019/062560 priority patent/WO2019224088A1/fr
Priority to EP19724489.0A priority patent/EP3801893A1/fr
Publication of FR3081345A1 publication Critical patent/FR3081345A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C07D211/14—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with hydrocarbon or substituted hydrocarbon radicals attached to the ring nitrogen atom
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de préparation d'une zéolithe de type structural AFX comprenant au moins les étapes suivantes : i) le mélange en milieu aqueux, d'une zéolithe de type structural FAU ayant un ratio molaire SiO2 (FAU)/Al2O3 (FAU) compris entre 6,00 et 200, bornes incluses, d'un composé organique azoté R, d'au moins une source d'au moins un métal alcalin et/ou alcalino-terreux M, le mélange réactionnel présentant la composition molaire suivante : (SiO2 (FAU))/(Al2O3 (FAU)) compris entre 6,00 et 200, H2O/(SiO2 (FAU)) compris entre 1,00 et 100, R/(SiO2 (FAU)) compris entre 0,01 à 0,60, M2/nO/(SiO2 (FAU)) compris entre 0,005 à 0,45, bornes incluses, jusqu'à l'obtention d'un gel précurseur homogène; ii) le traitement hydrothermal dudit gel précurseur obtenu à l'issue de l'étape i) à une température comprise entre 120°C et 220°C, pendant une durée comprise entre 12 heures et 15 jours.
FR1854389A 2018-05-24 2018-05-24 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote Active FR3081345B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1854389A FR3081345B1 (fr) 2018-05-24 2018-05-24 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote
JP2020565770A JP7493461B2 (ja) 2018-05-24 2019-05-16 有機窒素含有構造化剤存在下での高純度ａｆｘ構造ゼオライトの合成方法
CN201980034753.5A CN112203763A (zh) 2018-05-24 2019-05-16 在有机含氮结构化试剂的存在下合成非常高纯度afx结构沸石的方法
US17/057,364 US11560317B2 (en) 2018-05-24 2019-05-16 Method for synthesizing an AFX-structure zeolite of very high purity in the presence of an organic nitrogen-containing structuring agent
KR1020207033706A KR102773805B1 (ko) 2018-05-24 2019-05-16 유기 질소-함유 구조화제의 존재하에서 매우 높은 순도의 afx-구조 제올라이트의 합성 방법
PCT/EP2019/062560 WO2019224088A1 (fr) 2018-05-24 2019-05-16 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote
EP19724489.0A EP3801893A1 (fr) 2018-05-24 2019-05-16 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1854389A FR3081345B1 (fr) 2018-05-24 2018-05-24 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote
FR1854389 2018-05-24

Publications (2)

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FR3081345A1 FR3081345A1 (fr) 2019-11-29
FR3081345B1 true FR3081345B1 (fr) 2023-11-10

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FR1854389A Active FR3081345B1 (fr) 2018-05-24 2018-05-24 Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote

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US (1) US11560317B2 (fr)
EP (1) EP3801893A1 (fr)
JP (1) JP7493461B2 (fr)
KR (1) KR102773805B1 (fr)
CN (1) CN112203763A (fr)
FR (1) FR3081345B1 (fr)
WO (1) WO2019224088A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3081347B1 (fr) 2018-05-24 2023-07-28 Ifp Energies Now Procede de preparation d'une zeolithe de type structural afx de haute purete avec un structurant organique azote
FR3095199B1 (fr) 2019-04-19 2021-10-29 Ifp Energies Now Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite
FR3111886B1 (fr) * 2020-06-29 2022-06-24 Ifp Energies Now Synthese directe d’un catalyseur a base de zeolithe afx contenant du cuivre pour la reduction selective des nox
FR3123006B1 (fr) 2021-05-21 2023-06-02 Ifp Energies Now Synthese d’un catalyseur a base de zeolithe afx contenant du palladium pour l’adsorption des nox
CN115121281B (zh) * 2022-07-14 2023-07-25 宿迁联盛科技股份有限公司 一种金属铁掺杂的fau型沸石的制备及其在701阻聚剂合成中的应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4508837A (en) 1982-09-28 1985-04-02 Chevron Research Company Zeolite SSZ-16
US5194235A (en) 1992-08-27 1993-03-16 Chevron Research And Technology Company Synthesis of SSZ-16 zeolite catalyst
US5958370A (en) * 1997-12-11 1999-09-28 Chevron U.S.A. Inc. Zeolite SSZ-39
FR2914635B1 (fr) * 2007-04-05 2009-11-20 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mel
FR2936790B1 (fr) * 2008-10-07 2010-09-24 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtw
MY195237A (en) * 2012-02-07 2023-01-11 Basf Se Process For The Preparation of a Zeolitic Material
US9802831B2 (en) * 2014-07-23 2017-10-31 Chevron U.S.A. Inc. Synthesis of high silica zeolite via interzeolite transformation without OSDAs
US10173211B2 (en) * 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
RU2732126C2 (ru) * 2014-11-14 2020-09-11 Джонсон Мэтти Паблик Лимитед Компани Afx цеолит
CN110540215B (zh) * 2014-11-21 2024-02-06 三菱化学株式会社 Aei型铝硅酸盐沸石、催化剂和废气处理方法
JP6430303B2 (ja) 2015-03-16 2018-11-28 国立大学法人横浜国立大学 Ａｆｘ型ゼオライトの製法
EP3377194A1 (fr) * 2015-11-16 2018-09-26 Exxonmobil Upstream Research Company Matériaux adsorbants et procédés d'adsorption de dioxyde de carbone
GB2551623A (en) * 2016-04-22 2017-12-27 Johnson Matthey Plc Methods of producing SAPO-56, an AFX-containing molecular sieve
US9868643B2 (en) * 2016-05-20 2018-01-16 Chevron U.S.A. Inc. Synthesis of zeolite SSZ-16
KR20190009806A (ko) * 2016-05-24 2019-01-29 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매 금속을 포함하는 합성 제올라이트
WO2018064318A1 (fr) 2016-09-30 2018-04-05 Johnson Matthey Public Limited Company Nouvelle synthèse de zéolite avec un métal alcalinoterreux
US10414665B2 (en) 2016-09-30 2019-09-17 Johnson Matthey Public Limited Company Synthesis of AFX zeolite

Also Published As

Publication number Publication date
JP7493461B2 (ja) 2024-05-31
KR20210013692A (ko) 2021-02-05
KR102773805B1 (ko) 2025-02-26
US11560317B2 (en) 2023-01-24
JP2021524431A (ja) 2021-09-13
US20210188651A1 (en) 2021-06-24
EP3801893A1 (fr) 2021-04-14
WO2019224088A1 (fr) 2019-11-28
CN112203763A (zh) 2021-01-08
FR3081345A1 (fr) 2019-11-29

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