FI90816B - Mikrober dödande mikroemulsion - Google Patents
Mikrober dödande mikroemulsion Download PDFInfo
- Publication number
- FI90816B FI90816B FI883653A FI883653A FI90816B FI 90816 B FI90816 B FI 90816B FI 883653 A FI883653 A FI 883653A FI 883653 A FI883653 A FI 883653A FI 90816 B FI90816 B FI 90816B
- Authority
- FI
- Finland
- Prior art keywords
- carbon atoms
- weight
- alkyl
- parts
- group
- Prior art date
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- 239000004530 micro-emulsion Substances 0.000 title claims description 91
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- -1 halogenophenylamino Chemical group 0.000 claims description 46
- 239000004094 surface-active agent Substances 0.000 claims description 42
- 125000004432 carbon atom Chemical group C* 0.000 claims description 40
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 30
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 229910052736 halogen Inorganic materials 0.000 claims description 17
- 150000002367 halogens Chemical class 0.000 claims description 17
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- 239000003139 biocide Substances 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 229920001451 polypropylene glycol Polymers 0.000 claims description 10
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000003115 biocidal effect Effects 0.000 claims description 7
- 229920001400 block copolymer Polymers 0.000 claims description 7
- 241000233866 Fungi Species 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000003282 alkyl amino group Chemical group 0.000 claims description 4
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
- 125000004104 aryloxy group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000004663 dialkyl amino group Chemical group 0.000 claims description 4
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 241000195493 Cryptophyta Species 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000011109 contamination Methods 0.000 claims description 2
- 239000000498 cooling water Substances 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 5
- 125000004093 cyano group Chemical group *C#N 0.000 claims 3
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 2
- 241000894006 Bacteria Species 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000005017 substituted alkenyl group Chemical group 0.000 claims 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 1
- DFDBVSYZLJCHQG-UHFFFAOYSA-N 4,5-dichloro-3-octyl-1,2-thiazole 1-oxide Chemical compound CCCCCCCCC1=NS(=O)C(Cl)=C1Cl DFDBVSYZLJCHQG-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 235000015895 biscuits Nutrition 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 239000012267 brine Substances 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims 1
- 125000004426 substituted alkynyl group Chemical group 0.000 claims 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims 1
- 239000000243 solution Substances 0.000 description 25
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 24
- 239000003921 oil Substances 0.000 description 23
- 238000010790 dilution Methods 0.000 description 22
- 239000012895 dilution Substances 0.000 description 22
- 239000012141 concentrate Substances 0.000 description 18
- 235000008504 concentrate Nutrition 0.000 description 18
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 12
- 238000009472 formulation Methods 0.000 description 9
- 239000004907 Macro-emulsion Substances 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 7
- KOSFCMINOOZEJY-UHFFFAOYSA-N 3-(4,5-dichlorooctyl)-1,2-thiazole 1-oxide Chemical class CCCC(Cl)C(Cl)CCCC=1C=CS(=O)N=1 KOSFCMINOOZEJY-UHFFFAOYSA-N 0.000 description 6
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- FDHZSJWAYZGGKD-UHFFFAOYSA-N 3-octyl-1,2-thiazole 1-oxide Chemical compound CCCCCCCCC=1C=CS(=O)N=1 FDHZSJWAYZGGKD-UHFFFAOYSA-N 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 230000002538 fungal effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000228245 Aspergillus niger Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 238000005555 metalworking Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000546 pharmaceutical excipient Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- DYCRDXOGOYSIIA-UHFFFAOYSA-N 1-hexoxyethanol Chemical compound CCCCCCOC(C)O DYCRDXOGOYSIIA-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000004064 cosurfactant Substances 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical class 0.000 description 1
- IHDKBHLTKNUCCW-UHFFFAOYSA-N 1,3-thiazole 1-oxide Chemical compound O=S1C=CN=C1 IHDKBHLTKNUCCW-UHFFFAOYSA-N 0.000 description 1
- OXLXSOPFNVKUMU-UHFFFAOYSA-N 1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid Chemical class CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC OXLXSOPFNVKUMU-UHFFFAOYSA-N 0.000 description 1
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- VMJNTFXCTXAXTC-UHFFFAOYSA-N 2,2-difluoro-1,3-benzodioxole-5-carbonitrile Chemical group C1=C(C#N)C=C2OC(F)(F)OC2=C1 VMJNTFXCTXAXTC-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
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- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
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- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
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- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
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- 239000013530 defoamer Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
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- VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical class OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical class CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
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- ZLTPDFXIESTBQG-UHFFFAOYSA-N isothiazole Chemical compound C=1C=NSC=1 ZLTPDFXIESTBQG-UHFFFAOYSA-N 0.000 description 1
- 150000003854 isothiazoles Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
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- GVRNEIKWGDQKPS-UHFFFAOYSA-N nonyl benzenesulfonate Chemical class CCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVRNEIKWGDQKPS-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
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- 206010039083 rhinitis Diseases 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 239000003171 wood protecting agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/14—Additives which dissolves or releases substances when predefined environmental conditions are reached, e.g. pH or temperature
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Cosmetics (AREA)
- Colloid Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Claims (14)
1. Utspädningsstabil biocid mikroemulsion omfattande ett isotiazolon som har läg löslighet i vatten och som har f ormeln 5 R^, ,—0 Γ I· N-Y 10 väri Y är en osubstituerad alkylgrupp med 2-18 kolatomer, en substituerad alkylgrupp med 2-18 kolatomer och där ät-minstone en väteatom är ersatt med en hydroxi-, halogen-, 15 cyano-, alkylamino-, dialkylamino-, fenylamino-, halogen- fenylamino-, karboxi-, karbalkoxi-, alkoxi-, aryloxi-, mor-folino-, piperidino-, pyrrolidonyl-, karbamoxi- eller iso-tiazolonylgrupp, varvid totalantalet kolatomer i den substi-tuerade alkylgruppen icke överstiger 18, 20 en osubstituerad eller halogensubstituerad alkenylgrupp med 4-18 kolatomer, en osubstituerad eller halogensubstituerad alkynylgrupp med 4-18 kolatomer, en osubstituerad eller alkylsubstituerad cykloalkylgrupp med 25 en 4 - 6 kolatomer innehällande ring och med upp till 12 kolatomer, en osubstituerad eller halogen-, (Q-C*) alkyl- eller (Cj-C6)-alkoxisubstituerad aralkylgrupp, varvid totalantalet kolatomer i aralkylgruppen icke överstiger 10; eller 30 en osubstituerad eller halogen-, nitro-, (C^-Ce)alkyl- eller (C,-C6) karbalkoxisubstituerad arylgrupp, varvid totalantalet kolatomer i arylgruppen icke överstiger 10; och R och R1 är lika eller olika substituenter valda bland väte, halogen eller en ((VC4)alkylgrupp; 35 ett anjoniskt ytaktivt medel; ett andra ytaktivt medel som utgörs av en alkylalkohol och/- eller alkylalkoxylerad alkohol; samt vatten, ll 90816 käxmetecknad av att mikroemulsionen innehäller en polyoxiety-len/polyoxipropylenblockkopolymer med formeln: CH3
2. Biocid mikroemulsion, k&nnetecknad av att den omfattar 20 komponenter i följande förhällanden: (A) 0,1 - 50 viktdelar av ett isotiazolon med en löslighet i vatten av mindre än l vikt-% och med formeln:
25 R**—_ I N-Y R1 30 väri Y är en osubstituerad alkylgrupp med 2-18 kolatomer, en substituerad alkylgrupp med 2-18 kolatomer och där ät-minstone en väteatom är ersatt med en hydroxi-, halogen-, cyano-, alkylamino-, dialkylamino-, fenylamino-, halogen-35 fenylamino-, karboxi-, karbalkoxi-, alkoxi-, aryloxi-, mor-folino-, piperidino-, pyrrolidonyl-, karbamoxi- eller iso-tiazolonylgrupp, varvid totalantalet kolatomer i den substi-tuerade alkylgruppen icke överstiger 18, en osubstituerad eller halogensubstituerad alkenylgrupp med 40 4-18 kolatomer, en osubstituerad eller halogensubstituerad alkynylgrupp med 4-18 kolatomer, en osubstituerad eller alkylsubstituerad cykloalkylgrupp med en 4 - 6 kolatomer innehällande ring och med upp tili 12 kol-5 atomer, en osubstituerad eller halogen-, (C,-C6)alkyl- eller (Cj-C6) -alkoxisubstituerad aralkylgrupp, varvid totalantalet kolatomer i aralkylgruppen icke överstiger 10; eller en osubstituerad eller halogen-, nitro-, (Cj-Cs)alkyl- eller 10 (C,-C6) karbalkoxisubstituerad arylgrupp, varvid totalantalet kolatomer i arylgruppen icke överstiger 10; och R och R1 är lika eller olika substituenter valda bland väte, halogen eller en (C,-C4) alkylgrupp; och 15 (B) 0,1 - 25 viktdelar av ett anjoniskt ytaktivt medel; (C) 0,1 - 25 viktdelar av ett andra ytaktivt medel som utgörs av en alkylalkohol och/eller alkylalkoxylerad alkohol; 20 (D) 0,5 - 50 viktdelar av en polyoxietylen/polyoxipropylen- blockkopolymer med formeln: CH3 s I
25 R3(-CHCH20) (CHjCHjO) H m1 n1 väri R3 är (C^-Ce)alkoxi eller en rest med formeln 30 H0(CH2CH20) , n1 35 väri m1 är ett hei tai större än 15, och n1 är ett hei tai stör-re än 10; (E) 10 - 99 viktdelar vatten; och 40 (F) 0 - 30 viktdelar av ett hjälpmedel; 90816 förutsatt att totalmängden av komponenternas A-F viktdelar är 100.
3. Mikroemulsion enligt patentkravet 2, kannetecknad av att 5 den omfattar 1-30 viktdelar av isotiazolonet; 1-15 viktdelar av det anjoniska ytaktiva medlet; 1-20 viktdelar av det andra ytaktiva medlet; 1-40 viktdelar av polyoxiety-len/polyoxipropylenkopolymeren; 20 - 98 viktdelar vatten och 0-20 viktdelar av hjälpmedlet per 100 viktdelar av de sex 10 specifiserade komponenterna.
4. Mikroemulsion enligt patentkravet 2, k&nnetecknad av att den innehäller 1 - 12,5 viktdelar av isotiazolonet; 1-4 viktdelar av det anjoniska ytaktiva medlet; 1-6 viktdelar 15 av det andra ytaktiva medlet; 1-10 viktdelar av kopolyme- ren; 50 - 90 viktdelar vatten och 0-16 viktdelar av hjälpmedlet per 100 viktdelar av de sex specifiserade komponenterna.
5. Mikroemulsion enligt vilket som heist av de föregäende patentkraven, kannetecknad av att det anjoniska ytaktiva medlet omfattar ett alkylarylsulf onatsalt, alkyl (Cg-C*,) sulfat -sait; (Cjo-Ctt) fettalkoholetoxylatsulfatsalt, mono- eller dial-kyl (C4-C13) sulfobämstensyrasalt och/eller en sulfatiserad 25 olja.
5 I R3 ( - CHCHjO) ( CHjCHjO ) H m1 n1 10 väri R3 är C6) alkoxi eller en rest med formeln H0(CH2CH20) n1 15 väri m1 är ett heltal större än 15, och n1 är ett heltal stör-re än 10.
6. Mikroemulsion enligt vilket som heist av de föregäende patentkraven, kannetecknad av att det andra ytaktiva medlet är en (C4-Cjo) alkylalkohol eller alkylalkoxylerad alkohol med 30 formeln CHj( 0^).(0(¼¾) .OH eller CHjiCHjMOCjH^.OH, väri n är 0 eller ett heitai 1-7 och m är ett heltal 1-4.
7. Mikroemulsion enligt vilket som heist av de föregäende patentkraven, kannetecknad av att polyoxietylen/polyoxipro- 35 pylenkopolymeren har en viktmedelmolekylvikt pä över 1750.
8. Mikroemulsion enligt patentkravet 7, kannetecknad av att polyoxietylen/polyoxipropylenkopolymeren har en viktmedelmo-lekylvikt pi over 3000.
9. Mikroemulsion enligt vilket som heist av de föregiende patentkraven, kinnetecknad av att isotiazolonet innehiller n-oktyl-4-isotiazolin-3-on och/eller n-oktyl-4,5-diklor-iso-tiazolon.
10 10. Förfarande för inhibering av tillväxten av bakterier, svampar eller alger pi ett stille som ir utsatt för konta-mination förorsakad av bakterier, svampar eller alger, känne-tecknat av att ytan av stillet piförs eller i stillet införs en effektiv mingd av en mikroemulsion enligt vilket som heist 15 av patentkraven 1 - 9.
11. Förfarande enligt patentkravet 10, kannetecknat av att stillet utgörs av en borroljekomposition, ett kylvattensys-tem, en fast skyddande eller dekorativ film, ett tyg, leder, 20 papper eller tri, tvittvatten frin tvatteri, en kosmetisk komposition, ett brinslesystem, ett plastmaterial eller en emulsion.
12. Anvandning av en eller flera polyoxietylen/polyoxipropy-25 lenblockkopolymerer med formeln CH3 R3(-CHCH20) (CHjCHjO) H, väri R3 ir (C^-C*)alkoxi eller en m1 n1 30 rest med formeln HO(CH2CHjO) , väri m1 ir ett heltal större in n1 15, och n1 ir ett heltal större in 10, tillsammans med ett 35 anjoniskt ytaktivt medel, ett andra ytaktivt medel som utgörs av en alkylalkohol och/eller alkylalkoxylerad alkohol, och vatten för bildande av en stabil biocid mikroemulsion av ett isotiazolon som har lig löslighet i vatten, vilket isotiazo-lon har formeln li 5 90816 Γ l* N-Y väri Y är en osubstituerad alkylgrupp med 2-18 kolatomer, en substituerad alkylgrupp med 2-18 kolatomer och där ät-minstone en väteatom är ersatt med en hydroxi-, halogen-, 10 cyano-, alkylamino-, dialkylamino-, fenylamino-, halogen- fenylamino-, karboxi-, karbalkoxi-, alkoxi-, aryloxi-, mor-folino-, piperidino-, pyrrolidonyl-, karbamoxi- eller iso-tiazolonylgrupp, varvid totalantalet kolatomer i den substi-tuerade alkylgruppen icke överstiger 18, 15 en osubstituerad eller halogensubstituerad alkenylgrupp med 4-18 kolatomer, en osubstituerad eller halogensubstituerad alkynylgrupp med 4-18 kolatomer, en osubstituerad eller alkylsubstituerad cykloalkylgrupp med 20 en 4 - 6 kolatomer innehällande ring och med upp tili 12 kolatomer, en osubstituerad eller halogen-, (Cj-C6)alkyl- eller (C,-C6) alkoxisubstituerad aralkylgrupp, varvid totalantalet kolatomer i aralkylgruppen icke överstiger 10; eller 25 en osubstituerad eller halogen-, nitro-, (C^Cj)alkyl- eller (C,-C6) karbalkoxisubstituerad arylgrupp, varvid totalantalet kolatomer i arylgruppen icke överstiger 10; och R och R1 är lika eller olika substituenter valda bland väte, halogen eller en (C,-C4)alkylgrupp.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8192287A | 1987-08-05 | 1987-08-05 | |
| US8192287 | 1987-08-05 | ||
| US20962088 | 1988-06-22 | ||
| US07/209,620 US4954338A (en) | 1987-08-05 | 1988-06-22 | Microbicidal microemulsion |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI883653A0 FI883653A0 (sv) | 1988-08-04 |
| FI883653L FI883653L (sv) | 1989-02-06 |
| FI90816B true FI90816B (sv) | 1993-12-31 |
| FI90816C FI90816C (sv) | 1994-04-11 |
Family
ID=26766134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI883653A FI90816C (sv) | 1987-08-05 | 1988-08-04 | Mikrober dödande mikroemulsion |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4954338A (sv) |
| EP (1) | EP0302701B1 (sv) |
| JP (1) | JPH0832613B2 (sv) |
| AU (1) | AU610215B2 (sv) |
| BR (1) | BR8803875A (sv) |
| CA (1) | CA1297402C (sv) |
| DE (1) | DE3886127T2 (sv) |
| DK (1) | DK436188A (sv) |
| ES (1) | ES2060653T3 (sv) |
| FI (1) | FI90816C (sv) |
| HU (1) | HU204656B (sv) |
| IE (1) | IE62583B1 (sv) |
| IL (1) | IL87333A (sv) |
| MX (1) | MX163430B (sv) |
| NO (1) | NO175282C (sv) |
| NZ (1) | NZ225655A (sv) |
| PT (1) | PT88194B (sv) |
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| JPH02784A (ja) * | 1988-10-08 | 1990-01-05 | Katayama Chem Works Co Ltd | イソチアゾロン組成物及びその用途 |
| US5198455A (en) * | 1989-01-03 | 1993-03-30 | Rohm And Haas Company | Organic stabilizers |
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| US3523121A (en) * | 1967-03-09 | 1970-08-04 | Rohm & Haas | Certain 2-carbamoyl-3-isothiazolenes |
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-
1988
- 1988-06-22 US US07/209,620 patent/US4954338A/en not_active Expired - Lifetime
- 1988-07-27 CA CA000573136A patent/CA1297402C/en not_active Expired - Lifetime
- 1988-07-28 IE IE232388A patent/IE62583B1/en not_active IP Right Cessation
- 1988-07-29 MX MX12477A patent/MX163430B/es unknown
- 1988-08-01 NO NO883395A patent/NO175282C/no not_active IP Right Cessation
- 1988-08-02 DE DE88307123T patent/DE3886127T2/de not_active Expired - Lifetime
- 1988-08-02 ES ES88307123T patent/ES2060653T3/es not_active Expired - Lifetime
- 1988-08-02 EP EP88307123A patent/EP0302701B1/en not_active Expired - Lifetime
- 1988-08-02 NZ NZ225655A patent/NZ225655A/xx unknown
- 1988-08-04 DK DK436188A patent/DK436188A/da not_active Application Discontinuation
- 1988-08-04 JP JP63195278A patent/JPH0832613B2/ja not_active Expired - Lifetime
- 1988-08-04 PT PT88194A patent/PT88194B/pt not_active IP Right Cessation
- 1988-08-04 IL IL87333A patent/IL87333A/xx not_active IP Right Cessation
- 1988-08-04 AU AU20404/88A patent/AU610215B2/en not_active Ceased
- 1988-08-04 BR BR8803875A patent/BR8803875A/pt not_active IP Right Cessation
- 1988-08-04 FI FI883653A patent/FI90816C/sv not_active IP Right Cessation
- 1988-08-05 HU HU884103A patent/HU204656B/hu not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA1297402C (en) | 1992-03-17 |
| DK436188A (da) | 1989-02-06 |
| FI90816C (sv) | 1994-04-11 |
| FI883653L (sv) | 1989-02-06 |
| NZ225655A (en) | 1991-11-26 |
| PT88194B (pt) | 1995-07-18 |
| AU610215B2 (en) | 1991-05-16 |
| BR8803875A (pt) | 1989-02-21 |
| EP0302701B1 (en) | 1993-12-08 |
| MX163430B (es) | 1992-05-12 |
| NO175282B (no) | 1994-06-20 |
| DE3886127D1 (de) | 1994-01-20 |
| FI883653A0 (sv) | 1988-08-04 |
| EP0302701A3 (en) | 1990-02-28 |
| EP0302701A2 (en) | 1989-02-08 |
| NO883395D0 (no) | 1988-08-01 |
| DK436188D0 (da) | 1988-08-04 |
| US4954338A (en) | 1990-09-04 |
| NO883395L (no) | 1989-02-06 |
| IL87333A (en) | 1993-05-13 |
| IE62583B1 (en) | 1995-02-08 |
| AU2040488A (en) | 1989-04-20 |
| HU204656B (en) | 1992-02-28 |
| IL87333A0 (en) | 1989-01-31 |
| NO175282C (no) | 1994-10-05 |
| JPH01131102A (ja) | 1989-05-24 |
| IE882323L (en) | 1989-02-05 |
| HUT49448A (en) | 1989-10-30 |
| PT88194A (pt) | 1989-06-30 |
| DE3886127T2 (de) | 1994-04-28 |
| JPH0832613B2 (ja) | 1996-03-29 |
| ES2060653T3 (es) | 1994-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BB | Publication of examined application | ||
| MM | Patent lapsed |
Owner name: ROHM AND HAAS CO |