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FI20125036L - Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning - Google Patents

Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning Download PDF

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Publication number
FI20125036L
FI20125036L FI20125036A FI20125036A FI20125036L FI 20125036 L FI20125036 L FI 20125036L FI 20125036 A FI20125036 A FI 20125036A FI 20125036 A FI20125036 A FI 20125036A FI 20125036 L FI20125036 L FI 20125036L
Authority
FI
Finland
Prior art keywords
polymer dispersion
aqueous polymer
preparing
controlling
size distribution
Prior art date
Application number
FI20125036A
Other languages
English (en)
Finnish (fi)
Other versions
FI123696B (sv
Inventor
Helena Peuranen
Perttu Heiska
Kimmo Huhtala
Nina Bruun
Original Assignee
Kemira Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FI20125036A priority Critical patent/FI123696B/sv
Application filed by Kemira Oyj filed Critical Kemira Oyj
Priority to EP13701675.4A priority patent/EP2802611B1/en
Priority to RU2014133043A priority patent/RU2627365C2/ru
Priority to ES13701675.4T priority patent/ES2610569T3/es
Priority to CN201380004802.3A priority patent/CN104053688B/zh
Priority to PL13701675T priority patent/PL2802611T3/pl
Priority to HUE13701675A priority patent/HUE033029T2/hu
Priority to BR112014016924-1A priority patent/BR112014016924B1/pt
Priority to KR1020197010668A priority patent/KR102046572B1/ko
Priority to PCT/FI2013/050031 priority patent/WO2013104832A1/en
Priority to PT137016754T priority patent/PT2802611T/pt
Priority to CA2861073A priority patent/CA2861073C/en
Priority to US13/739,071 priority patent/US9079995B2/en
Priority to KR1020147017594A priority patent/KR101970348B1/ko
Publication of FI20125036L publication Critical patent/FI20125036L/sv
Application granted granted Critical
Publication of FI123696B publication Critical patent/FI123696B/sv
Priority to US14/510,200 priority patent/US9212247B2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/14—Amylose derivatives; Amylopectin derivatives
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Paper (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
FI20125036A 2012-01-12 2012-01-12 Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning FI123696B (sv)

Priority Applications (15)

Application Number Priority Date Filing Date Title
FI20125036A FI123696B (sv) 2012-01-12 2012-01-12 Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning
PT137016754T PT2802611T (pt) 2012-01-12 2013-01-11 Método para controlar a distribuição de tamanho de partículas de polímero durante a preparação de uma dispersão polimérica aquosa, dispersão polimérica aquosa e a sua utilização
ES13701675.4T ES2610569T3 (es) 2012-01-12 2013-01-11 Método para controlar la distribución del tamaño de partículas de un polímero durante la preparación de una dispersión acuosa del polímero, dispersión acuosa del polímero y su uso
CN201380004802.3A CN104053688B (zh) 2012-01-12 2013-01-11 在制备水性聚合物分散体的过程中控制聚合物颗粒的粒径分布的方法、水性聚合物分散体及其用途
PL13701675T PL2802611T3 (pl) 2012-01-12 2013-01-11 Sposób regulacji składu granulometrycznego cząstek polimeru podczas przygotowywania wodnej dyspersji polimeru, wodna dyspersja polimeru i jej zastosowanie
HUE13701675A HUE033029T2 (hu) 2012-01-12 2013-01-11 Eljárás polimer részecskék méreteloszlásának szabályozására vizes polimer diszperzió készítése során; a vizes polimer diszperzió; és annak alkalmazása
EP13701675.4A EP2802611B1 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
KR1020197010668A KR102046572B1 (ko) 2012-01-12 2013-01-11 수성 중합체 분산액의 제조 동안 중합체 입자들의 크기 분포를 제어하기 위한 방법, 수성 중합체 분산액 및 이를 사용하는 방법
PCT/FI2013/050031 WO2013104832A1 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
RU2014133043A RU2627365C2 (ru) 2012-01-12 2013-01-11 Способ контроля распределения по размерам полимерных частиц в ходе получения водной полимерной дисперсии, водная полимерная дисперсия и ее применение
CA2861073A CA2861073C (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
US13/739,071 US9079995B2 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion
KR1020147017594A KR101970348B1 (ko) 2012-01-12 2013-01-11 수성 중합체 분산액의 제조 동안 중합체 입자들의 크기 분포를 제어하기 위한 방법, 수성 중합체 분산액 및 이를 사용하는 방법
BR112014016924-1A BR112014016924B1 (pt) 2012-01-12 2013-01-11 método para controlar a distribuição de partículas de polímero durante a preparação de uma dispersão aquosa de polímero
US14/510,200 US9212247B2 (en) 2012-01-12 2014-10-09 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20125036 2012-01-12
FI20125036A FI123696B (sv) 2012-01-12 2012-01-12 Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning

Publications (2)

Publication Number Publication Date
FI20125036L true FI20125036L (sv) 2013-07-13
FI123696B FI123696B (sv) 2013-09-30

Family

ID=48780409

Family Applications (1)

Application Number Title Priority Date Filing Date
FI20125036A FI123696B (sv) 2012-01-12 2012-01-12 Förfarande för reglering av storleksfördelning av polymerpartiklar vid framställning av en vattenhaltig polymerdispersion, vattenhaltig polymerdispersion och dess användning

Country Status (13)

Country Link
US (2) US9079995B2 (sv)
EP (1) EP2802611B1 (sv)
KR (2) KR101970348B1 (sv)
CN (1) CN104053688B (sv)
BR (1) BR112014016924B1 (sv)
CA (1) CA2861073C (sv)
ES (1) ES2610569T3 (sv)
FI (1) FI123696B (sv)
HU (1) HUE033029T2 (sv)
PL (1) PL2802611T3 (sv)
PT (1) PT2802611T (sv)
RU (1) RU2627365C2 (sv)
WO (1) WO2013104832A1 (sv)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103866626B (zh) * 2014-02-28 2016-06-29 新昌县澄潭镇博纳机械厂 一种阿拉伯胶施胶剂及其制备方法
US10221089B2 (en) * 2015-09-10 2019-03-05 Corning Incorporated Optical fiber with low fictive temperature
FI128576B (sv) 2015-12-21 2020-08-14 Kemira Oyj Förfarande för framställning av en limämneskomposition, limämneskomposition och användning därav
FI126948B (sv) * 2016-03-22 2017-08-31 Kemira Oyj Vattenhaltig polymerdispersion, dess användning och metod för framställning av vattenhaltig polymerdispersion
FI20165235A7 (sv) * 2016-03-22 2017-09-23 Kemira Oyj Sammansättning för modifiering av reologi för bestrykningssmet, dess användning och bestrykningssmet
US11242423B2 (en) 2017-03-30 2022-02-08 Kemira Oyj Surface sizing composition, method of production, and use thereof
CN108690213A (zh) * 2018-05-29 2018-10-23 芜湖市元奎新材料科技有限公司 硅溶胶改性的丙烯酸乳液
JP6760344B2 (ja) 2018-09-18 2020-09-23 栗田工業株式会社 製紙用表面サイズ剤
CN110093811B (zh) * 2019-06-17 2022-03-29 南昌市龙然实业有限公司 一种储存稳定、强附着性的表面施胶剂及其制备方法
KR102781700B1 (ko) 2020-03-19 2025-03-18 삼성전자 주식회사 전자 장치의 화면을 홀로그램으로 표시하는 거치 장치
CN112961293A (zh) * 2021-04-21 2021-06-15 安徽工程大学 一种两步制备高表面活性两亲性接枝淀粉浆料的制备方法及其产品和应用

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Publication number Priority date Publication date Assignee Title
US5705563A (en) * 1991-10-07 1998-01-06 Basf Aktiengesellschaft Aqueous polymer dispersions
DE19806745A1 (de) * 1998-02-18 1999-08-19 Bayer Ag Feinteilige Polymerdispersionen zur Papierleimung
US6114417A (en) * 1998-10-16 2000-09-05 Cytec Technology Corp. Paper sizing agents and methods
DE10004893A1 (de) * 2000-02-04 2001-08-16 Bayer Ag 2-Komponentensystem zur Herstellung eines Stone-wash-Effektes auf gefärbtem Baumwoll- oder baumwollhaltigen Geweben
EP1321574A1 (de) * 2001-12-18 2003-06-25 Chemische Fabrik Brühl Mare GmbH Oberflächenleimungsmittel
DE102005030787A1 (de) * 2005-06-29 2007-01-11 Basf Ag Feinteilige, stärkehaltige Polymerdispersionen
CA2667875A1 (en) * 2006-11-10 2008-05-15 Basf Se Finely divided, starch-containing polymer dispersions
MY156284A (en) * 2008-05-21 2016-01-29 Bayer Cropscience Ag Insecticidal formulations with improved long-term activity on surfaces
CN102656192B (zh) * 2009-10-02 2016-06-01 巴斯夫欧洲公司 含淀粉的细碎聚合物分散体、其生产方法及其在造纸中作为施胶剂的用途

Also Published As

Publication number Publication date
CA2861073C (en) 2018-10-16
BR112014016924B1 (pt) 2021-03-09
FI123696B (sv) 2013-09-30
US20130184407A1 (en) 2013-07-18
ES2610569T3 (es) 2017-04-28
KR101970348B1 (ko) 2019-04-18
PT2802611T (pt) 2017-01-13
KR102046572B1 (ko) 2019-11-20
PL2802611T3 (pl) 2017-05-31
US20150025194A1 (en) 2015-01-22
EP2802611B1 (en) 2016-10-12
BR112014016924A2 (pt) 2017-06-13
WO2013104832A1 (en) 2013-07-18
US9079995B2 (en) 2015-07-14
KR20140123478A (ko) 2014-10-22
CA2861073A1 (en) 2013-07-18
RU2627365C2 (ru) 2017-08-07
CN104053688A (zh) 2014-09-17
EP2802611A1 (en) 2014-11-19
KR20190043176A (ko) 2019-04-25
US9212247B2 (en) 2015-12-15
BR112014016924A8 (pt) 2017-07-04
CN104053688B (zh) 2016-06-01
HUE033029T2 (hu) 2017-11-28
RU2014133043A (ru) 2016-02-27

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