FI20040365A0 - Nanorör av kol och kompositmaterial med reglerbara egenskaper som har framställts av dem, förfarande för framställning av nanorör av kol och av deras funktionella kompositmaterial och strukturer och anordningar som har framställts av dessa material - Google Patents
Nanorör av kol och kompositmaterial med reglerbara egenskaper som har framställts av dem, förfarande för framställning av nanorör av kol och av deras funktionella kompositmaterial och strukturer och anordningar som har framställts av dessa materialInfo
- Publication number
- FI20040365A0 FI20040365A0 FI20040365A FI20040365A FI20040365A0 FI 20040365 A0 FI20040365 A0 FI 20040365A0 FI 20040365 A FI20040365 A FI 20040365A FI 20040365 A FI20040365 A FI 20040365A FI 20040365 A0 FI20040365 A0 FI 20040365A0
- Authority
- FI
- Finland
- Prior art keywords
- carbon nanotubes
- therefor
- composite
- materials
- manufacture
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title 2
- 239000002041 carbon nanotube Substances 0.000 title 2
- 229910021393 carbon nanotube Inorganic materials 0.000 title 2
- 239000002131 composite material Substances 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000008204 material by function Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/164—Preparation involving continuous processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1278—Carbon monoxide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/02—Single-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/34—Length
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/36—Diameter
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C01P2004/13—Nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C01P2004/13—Nanotubes
- C01P2004/133—Multiwall nanotubes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electrochemistry (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Thermal Sciences (AREA)
- Textile Engineering (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20040365A FI121334B (sv) | 2004-03-09 | 2004-03-09 | Förfarande och anordningar för framställning av nanorör |
| PCT/FI2005/000145 WO2005085130A2 (en) | 2004-03-09 | 2005-03-09 | Single, multi-walled, functionalized and doped carbon nanotubes and composites thereof |
| JP2007502357A JP4920574B2 (ja) | 2004-03-09 | 2005-03-09 | 単層、多層、機能化及びドープ処理カーボンナノチューブ、並びにそれらの複合物 |
| EP05717272.8A EP1727767B8 (en) | 2004-03-09 | 2005-03-09 | Method for producing carbon nanotubes |
| CA2559070A CA2559070C (en) | 2004-03-09 | 2005-03-09 | Single, multi-walled, functionalized and doped carbon nanotubes and composites thereof |
| CNA2005800147556A CN1950296A (zh) | 2004-03-09 | 2005-03-09 | 单壁面、多壁面、官能化和施加添加剂的碳纳米管及其复合材料 |
| CN201310199156.2A CN103466592B (zh) | 2004-03-09 | 2005-03-09 | 单壁、多壁、官能化和掺杂的碳纳米管及其复合材料 |
| KR1020067020951A KR20070001220A (ko) | 2004-03-09 | 2005-03-09 | 단일벽, 다중벽, 기능성 및 도핑 탄소 나노튜브 및 이의복합체 |
| ES05717272.8T ES2660321T3 (es) | 2004-03-09 | 2005-03-09 | Procedimiento para la producción de nanotubos de carbono |
| US10/591,954 US8845995B2 (en) | 2004-03-09 | 2005-03-09 | Single, multi-walled, functionalized and doped carbon nanotubes and composites thereof |
| US14/318,726 US9556032B2 (en) | 2004-03-09 | 2014-06-30 | Single, multi-walled, functionalized and doped carbon nanotubes and composites thereof |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20040365A FI121334B (sv) | 2004-03-09 | 2004-03-09 | Förfarande och anordningar för framställning av nanorör |
| FI20040365 | 2004-03-09 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI20040365A0 true FI20040365A0 (sv) | 2004-03-09 |
| FI20040365L FI20040365L (sv) | 2005-09-10 |
| FI121334B FI121334B (sv) | 2010-10-15 |
Family
ID=32039389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI20040365A FI121334B (sv) | 2004-03-09 | 2004-03-09 | Förfarande och anordningar för framställning av nanorör |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US8845995B2 (sv) |
| EP (1) | EP1727767B8 (sv) |
| JP (1) | JP4920574B2 (sv) |
| KR (1) | KR20070001220A (sv) |
| CN (2) | CN103466592B (sv) |
| CA (1) | CA2559070C (sv) |
| ES (1) | ES2660321T3 (sv) |
| FI (1) | FI121334B (sv) |
| WO (1) | WO2005085130A2 (sv) |
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|---|---|---|---|---|
| WO2007069267A2 (en) * | 2005-10-07 | 2007-06-21 | Gaurav Namdhar | Method and appartus for synthesis of carbon nanotubes |
| FI120195B (sv) * | 2005-11-16 | 2009-07-31 | Canatu Oy | Kolnanorör funktionaliserade med kovalent bundna fullerener, förfarande och anordning för att producera dem samt kompositer därav |
| EP1973845A4 (en) | 2005-12-19 | 2009-08-19 | Nantero Inc | PREPARATION OF CARBON NANOTUBES |
| FR2895393B1 (fr) * | 2005-12-23 | 2008-03-07 | Arkema Sa | Procede de synthese de nanotubes de carbone |
| CN101007631A (zh) * | 2006-01-27 | 2007-08-01 | 索尼株式会社 | 单层碳纳米管及其制备方法、以及电子元件的制备方法 |
| WO2007100306A1 (en) * | 2006-03-01 | 2007-09-07 | National University Of Singapore | Carbon nanotube(s) and method for making the same |
| US7713907B2 (en) * | 2006-03-06 | 2010-05-11 | Uchicago Argonne, Llc | Method of preparing size-selected metal clusters |
| FI121540B (sv) | 2006-03-08 | 2010-12-31 | Canatu Oy | Förfarande för förskjutande av molekylstrukturer med höga aspektförhållanden |
| EP1837306B1 (en) * | 2006-03-20 | 2011-07-20 | Research Institute of Petroleum Industry (RIPI) | Continuous process for producing carbon nanotubes |
| US7713858B2 (en) * | 2006-03-31 | 2010-05-11 | Intel Corporation | Carbon nanotube-solder composite structures for interconnects, process of making same, packages containing same, and systems containing same |
| US20070298168A1 (en) * | 2006-06-09 | 2007-12-27 | Rensselaer Polytechnic Institute | Multifunctional carbon nanotube based brushes |
| FI120450B (sv) | 2007-03-21 | 2009-10-30 | Beneq Oy | Anordning för framställning av nanorör |
| US7931734B2 (en) * | 2007-08-29 | 2011-04-26 | Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The Desert Research Institute | Particle separation |
| CN101471184B (zh) * | 2007-12-27 | 2011-11-09 | 清华大学 | 超级电容器 |
| CN101425381B (zh) * | 2007-11-02 | 2012-07-18 | 清华大学 | 超级电容器及其制备方法 |
| CN101425380B (zh) * | 2007-11-02 | 2013-04-24 | 清华大学 | 超级电容器及其制备方法 |
| US7826198B2 (en) * | 2007-12-29 | 2010-11-02 | Tsinghua University | Electrochemical capacitor with carbon nanotubes |
| US9293720B2 (en) * | 2008-02-19 | 2016-03-22 | New Jersey Institute Of Technology | Carbon nanotubes as charge carriers in organic and hybrid solar cells |
| US8148188B2 (en) * | 2008-02-26 | 2012-04-03 | Imec | Photoelectrochemical cell with carbon nanotube-functionalized semiconductor electrode |
| EP2263974B1 (en) * | 2008-04-16 | 2014-06-18 | Zeon Corporation | Equipment and method for producing orientated carbon nano-tube aggregates |
| US7727505B2 (en) * | 2008-05-21 | 2010-06-01 | International Business Machines Corporation | Methods for separating carbon nanotubes by enhancing the density differential |
| FI121156B (sv) * | 2008-06-27 | 2010-07-30 | Canatu Oy | Användning av kolnanoknoppsmolekyl för att växelverka med elektromagnetisk strålning i en anordning |
| US8396700B2 (en) * | 2008-09-02 | 2013-03-12 | Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The Desert Research Institute | Aggregate simulation |
| RU2389550C1 (ru) * | 2008-09-22 | 2010-05-20 | Учреждение Российской академии наук Институт неорганической химии им. А.В. Николаева Сибирского отделения РАН | Способ получения нанесенного катализатора и способ получения углеродных нанотруб |
| CN102196993B (zh) * | 2008-10-24 | 2014-05-14 | 株式会社可乐丽 | 金属性碳纳米管的制造方法、碳纳米管分散液、含碳纳米管的膜及透明导电膜 |
| RU2373995C1 (ru) * | 2008-11-01 | 2009-11-27 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения высокодисперсных нанесенных катализаторов и синтез углеродных нанотрубок |
| US20100224479A1 (en) * | 2009-02-02 | 2010-09-09 | The Board of Regents of the Nevada System of Higher Educ., on Behalf of the Desert Res. Inst. | Morphology engineering of aggregates |
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| US8664573B2 (en) * | 2009-04-27 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-based resistive heating for deicing composite structures |
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| KR101132717B1 (ko) | 2010-02-23 | 2012-04-06 | 단국대학교 산학협력단 | 세라믹/cnt 복합체 및 이의 제조방법 |
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| WO2014151138A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Reactors, systems, and methods for forming solid products |
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| JP2778434B2 (ja) * | 1993-11-30 | 1998-07-23 | 昭和電工株式会社 | 気相法炭素繊維の製造方法 |
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| JPH11107052A (ja) * | 1997-09-30 | 1999-04-20 | Nikkiso Co Ltd | 気相成長炭素繊維の連続製造装置及び気相成長炭素繊維の連続製造方法 |
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| KR100432056B1 (ko) * | 2001-07-20 | 2004-05-17 | (주)케이에이치 케미컬 | 탄소나노튜브의 제조 방법 |
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| US20040265211A1 (en) * | 2001-12-14 | 2004-12-30 | Dillon Anne C. | Hot wire production of single-wall carbon nanotubes |
| JP4010974B2 (ja) | 2002-05-22 | 2007-11-21 | 昭和電工株式会社 | 気相法炭素繊維の製造方法 |
| GB0216654D0 (en) * | 2002-07-17 | 2002-08-28 | Univ Cambridge Tech | CVD Synthesis of carbon nanoutubes |
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| FI20035120L (sv) | 2003-07-04 | 2005-01-05 | Valtion Teknillinen | Carbon onion particle synthesis |
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- 2005-03-09 EP EP05717272.8A patent/EP1727767B8/en not_active Expired - Lifetime
- 2005-03-09 CN CN201310199156.2A patent/CN103466592B/zh not_active Expired - Lifetime
- 2005-03-09 ES ES05717272.8T patent/ES2660321T3/es not_active Expired - Lifetime
- 2005-03-09 US US10/591,954 patent/US8845995B2/en active Active
- 2005-03-09 CN CNA2005800147556A patent/CN1950296A/zh active Pending
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| Publication number | Publication date |
|---|---|
| CA2559070C (en) | 2013-05-14 |
| FI20040365L (sv) | 2005-09-10 |
| KR20070001220A (ko) | 2007-01-03 |
| CN103466592A (zh) | 2013-12-25 |
| EP1727767B8 (en) | 2018-01-17 |
| JP2007527844A (ja) | 2007-10-04 |
| CN1950296A (zh) | 2007-04-18 |
| US9556032B2 (en) | 2017-01-31 |
| ES2660321T3 (es) | 2018-03-21 |
| CA2559070A1 (en) | 2005-09-15 |
| US20070148962A1 (en) | 2007-06-28 |
| EP1727767B1 (en) | 2017-11-22 |
| CN103466592B (zh) | 2016-01-20 |
| WO2005085130A3 (en) | 2006-04-06 |
| JP4920574B2 (ja) | 2012-04-18 |
| FI121334B (sv) | 2010-10-15 |
| US8845995B2 (en) | 2014-09-30 |
| US20140348721A1 (en) | 2014-11-27 |
| EP1727767A2 (en) | 2006-12-06 |
| WO2005085130A2 (en) | 2005-09-15 |
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