ES8501778A1 - Procedimiento para preparar un polibutadieno de peso molecular regulado. - Google Patents
Procedimiento para preparar un polibutadieno de peso molecular regulado.Info
- Publication number
- ES8501778A1 ES8501778A1 ES521759A ES521759A ES8501778A1 ES 8501778 A1 ES8501778 A1 ES 8501778A1 ES 521759 A ES521759 A ES 521759A ES 521759 A ES521759 A ES 521759A ES 8501778 A1 ES8501778 A1 ES 8501778A1
- Authority
- ES
- Spain
- Prior art keywords
- compound
- hydrogen fluoride
- nickel
- polymerization
- polybutadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 title abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 6
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 6
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 150000002816 nickel compounds Chemical class 0.000 abstract 4
- 230000000536 complexating effect Effects 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 abstract 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- -1 ethylene, propylene, 1-butene Chemical class 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000011707 mineral Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002815 nickel Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR UN POLIBUTADIENO DE PESO MOLECULAR REGULADO, CON ELEVADA PROPORCION DE CIS
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37184382A | 1982-04-26 | 1982-04-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES521759A0 ES521759A0 (es) | 1984-12-01 |
| ES8501778A1 true ES8501778A1 (es) | 1984-12-01 |
Family
ID=23465627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES521759A Expired ES8501778A1 (es) | 1982-04-26 | 1983-04-22 | Procedimiento para preparar un polibutadieno de peso molecular regulado. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0093075B1 (es) |
| JP (1) | JPS58196213A (es) |
| AU (1) | AU559471B2 (es) |
| BR (1) | BR8301902A (es) |
| CA (1) | CA1236647A (es) |
| DE (1) | DE3368648D1 (es) |
| ES (1) | ES8501778A1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4501866A (en) * | 1984-07-23 | 1985-02-26 | The Firestone Tire & Rubber Company | Continuous method for preparing high cis-1,4 polybutadiene |
| IN173082B (es) * | 1986-02-19 | 1994-02-05 | Goodyear Tire & Rubber | |
| US5412045A (en) * | 1994-09-16 | 1995-05-02 | Polysar Rubber Corporation | Preparation of high cis-1,4-polybutadiene with reduced gel |
| US5955553A (en) * | 1998-08-19 | 1999-09-21 | Bridgestone Corporation | Molecular weight regulation of cis-1,4-polybutadiene using carboxylates |
| KR100344230B1 (ko) * | 1999-10-13 | 2002-07-24 | 금호석유화학 주식회사 | 산소분자를 이용한 하이드록시 고 1,4-시스 폴리부타디엔의 제조방법 |
| KR100348763B1 (ko) | 2000-07-06 | 2002-08-13 | 금호석유화학 주식회사 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 분지도 조절방법 |
| KR101986201B1 (ko) | 2011-05-09 | 2019-06-07 | 가부시키가이샤 브리지스톤 | 고-cis 폴리디엔 제조방법 |
| US10066035B2 (en) * | 2015-12-07 | 2018-09-04 | Bridgestone Corporation | Catalyst systems and methods for preparation of 1,4-polybutadiene rubber |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2122956C3 (de) * | 1971-05-10 | 1979-09-06 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von flüssigen Butadienpolymerisaten |
| US3856764A (en) * | 1971-11-24 | 1974-12-24 | Goodyear Tire & Rubber | Polymerization process |
| US3962375A (en) * | 1973-12-13 | 1976-06-08 | The Goodyear Tire & Rubber Company | Polymerization process |
| US3910869A (en) * | 1974-01-31 | 1975-10-07 | Goodyear Tire & Rubber | Chemical process |
| US4020255A (en) * | 1975-05-07 | 1977-04-26 | The Goodyear Tire & Rubber Company | Continuous insitu catalyst addition for polybutadiene polymerization |
| JPS5873703A (ja) * | 1981-10-28 | 1983-05-04 | Sumitomo Metal Ind Ltd | 焼入れ性及び靭性にすぐれた粉末鍛造品の製造方法 |
| JPS5873701A (ja) * | 1981-10-28 | 1983-05-04 | Sumitomo Metal Ind Ltd | 焼入れ性及び靭性にすぐれた粉末鍛造品の製造方法 |
-
1983
- 1983-04-12 CA CA000425669A patent/CA1236647A/en not_active Expired
- 1983-04-14 BR BR8301902A patent/BR8301902A/pt not_active IP Right Cessation
- 1983-04-21 EP EP83630072A patent/EP0093075B1/en not_active Expired
- 1983-04-21 DE DE8383630072T patent/DE3368648D1/de not_active Expired
- 1983-04-22 ES ES521759A patent/ES8501778A1/es not_active Expired
- 1983-04-22 AU AU13868/83A patent/AU559471B2/en not_active Expired
- 1983-04-26 JP JP7370283A patent/JPS58196213A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU559471B2 (en) | 1987-03-12 |
| ES521759A0 (es) | 1984-12-01 |
| CA1236647A (en) | 1988-05-10 |
| AU1386883A (en) | 1983-11-03 |
| DE3368648D1 (en) | 1987-02-05 |
| EP0093075B1 (en) | 1986-12-30 |
| JPS58196213A (ja) | 1983-11-15 |
| BR8301902A (pt) | 1983-12-20 |
| EP0093075A1 (en) | 1983-11-02 |
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