[go: up one dir, main page]

ES476443A1 - Procedimiento para la preparacion de esterolinas inhibidorasde la sintesis de las prostaglandinas - Google Patents

Procedimiento para la preparacion de esterolinas inhibidorasde la sintesis de las prostaglandinas

Info

Publication number
ES476443A1
ES476443A1 ES476443A ES476443A ES476443A1 ES 476443 A1 ES476443 A1 ES 476443A1 ES 476443 A ES476443 A ES 476443A ES 476443 A ES476443 A ES 476443A ES 476443 A1 ES476443 A1 ES 476443A1
Authority
ES
Spain
Prior art keywords
beta
spiroketal
sterols
glycosides
steroids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES476443A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roecar Holdings NV
Roecar Holdings Netherlands Antilles NV
Original Assignee
Roecar Holdings NV
Roecar Holdings Netherlands Antilles NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roecar Holdings NV, Roecar Holdings Netherlands Antilles NV filed Critical Roecar Holdings NV
Publication of ES476443A1 publication Critical patent/ES476443A1/es
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/70Carbohydrates; Sugars; Derivatives thereof
    • A61K31/7028Compounds having saccharide radicals attached to non-saccharide compounds by glycosidic linkages
    • A61K31/7034Compounds having saccharide radicals attached to non-saccharide compounds by glycosidic linkages attached to a carbocyclic compound, e.g. phloridzin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/70Carbohydrates; Sugars; Derivatives thereof
    • A61K31/7028Compounds having saccharide radicals attached to non-saccharide compounds by glycosidic linkages
    • A61K31/7034Compounds having saccharide radicals attached to non-saccharide compounds by glycosidic linkages attached to a carbocyclic compound, e.g. phloridzin
    • A61K31/704Compounds having saccharide radicals attached to non-saccharide compounds by glycosidic linkages attached to a carbocyclic compound, e.g. phloridzin attached to a condensed carbocyclic ring system, e.g. sennosides, thiocolchicosides, escin, daunorubicin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J17/00Normal steroids containing carbon, hydrogen, halogen or oxygen, having an oxygen-containing hetero ring not condensed with the cyclopenta(a)hydrophenanthrene skeleton
    • C07J17/005Glycosides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J71/00Steroids in which the cyclopenta(a)hydrophenanthrene skeleton is condensed with a heterocyclic ring
    • C07J71/0005Oxygen-containing hetero ring

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Procedimiento para la preparación de esterolinas inhibidoras de la síntesis de las prostaglandinas, caracterizado porque una mezcla de sitoesterol y carbonato de plata en toluol o tolueno es destilado bajo agitación tanto tiempo hasta que el destilado resulte exento de agua, introduciéndose a continuación en la mezcla agitada y en ebullición, gota a gota unasolución de acetobromoglucosa en toluol, siguiendo destilándose el toluol de tal manera que la totalidad del agua, formada durante la reacción, es eliminada de forma aceotrópica, que, una vez añadida la solución de bromoacetoglucosa, se mantiene en ebullición durante tanto tiempo, hasta que el destilado esté exento de agua, filtrándose a continuación la mezcla de reacción para su separación, siendo eliminados los resíduos con toluol fresco y caliente, concentrándose el filtrado, unido con el líquido del lavado, a presión reducida, siendo recristalizado el resíduo de etanol o hexano, añadiéndose a la solución de sitosterol-glucósidotetracetato así obtenido en etanol, a una temperatura de 45º, agitándose la mezcla durante una hora, antes de añadir la cantidad correspondiente de agua, agitándose la mezcla una hora más, siendo precipitados los glucosídos de sitosterol que son separados por filtración y lavado con agua.
ES476443A 1977-12-31 1978-12-28 Procedimiento para la preparacion de esterolinas inhibidorasde la sintesis de las prostaglandinas Expired ES476443A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772759171 DE2759171A1 (de) 1977-12-31 1977-12-31 Arzneimittel mit wirkung als prostaglandinsynthetaseninhibitor

Publications (1)

Publication Number Publication Date
ES476443A1 true ES476443A1 (es) 1979-10-16

Family

ID=6027873

Family Applications (1)

Application Number Title Priority Date Filing Date
ES476443A Expired ES476443A1 (es) 1977-12-31 1978-12-28 Procedimiento para la preparacion de esterolinas inhibidorasde la sintesis de las prostaglandinas

Country Status (19)

Country Link
JP (1) JPS54101436A (es)
AR (1) AR223334A1 (es)
AU (1) AU516933B2 (es)
BE (1) BE873222A (es)
CA (1) CA1113006A (es)
CH (1) CH637829A5 (es)
DE (1) DE2759171A1 (es)
DK (1) DK587778A (es)
ES (1) ES476443A1 (es)
FR (1) FR2425859A1 (es)
GB (1) GB2039217B (es)
IL (1) IL56345A (es)
IT (1) IT1109336B (es)
LU (1) LU80739A1 (es)
NL (1) NL7812656A (es)
NZ (1) NZ189297A (es)
PT (1) PT69012A (es)
SE (1) SE466683B (es)
ZA (1) ZA787399B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2926463A1 (de) * 1978-07-05 1980-01-24 Roecar Holdings Nv Spiroketaline und ihre verwendung
JPS5874619A (ja) * 1981-10-29 1983-05-06 Nippon Shinyaku Co Ltd リポソ−ム及びその製法
CA1209912A (en) 1982-04-19 1986-08-19 Siegfrid Drewes Extract of plants of the family of hypoxidaceae for treatment of cancer
US4602005A (en) * 1982-05-17 1986-07-22 Medical Research Foundation Of Oregon Tigogenin cellobioside for treating hypercholesterolemia and atherosclerosis
US4602003A (en) * 1982-05-17 1986-07-22 Medical Research Foundation Of Oregon Synthetic compounds to inhibit intestinal absorption of cholesterol in the treatment of hypercholesterolemia
DE3401178A1 (de) * 1984-01-14 1985-07-18 Roecar Holdings (Netherlands Antilles) N.V., Willemstad, Curacao, Niederländische Antillen Verwendung von phytosterolglykosiden zur behandlung erhoehter 5(6)(alpha)-epoxicholesterolspiegel
DE3416112A1 (de) * 1984-04-30 1985-10-31 Roecar Holdings (Netherlands Antilles) N.V., Willemstad, Curacao, Niederländische Antillen Verwendung von sterolinen und spiroketalinen als lipoxygenaseregulatoren
DE3829640C1 (es) * 1988-09-01 1990-04-26 Roecar Holdings (Netherlands Antilles) N.V., Willemstad, Curacao, Niederlaendische Antillen, Nl
US5166194A (en) * 1988-09-01 1992-11-24 Roecar Holdings Transdermally applicable pharmaceutical preparations having a pharmaceutically usable glycoside content
DE3829641A1 (de) * 1988-09-01 1990-03-15 Roecar Holdings Nv Transdermal anwendbare pharmazeutische zubereitungen mit sterolinen und/oder spiroketalinen
DE3829643A1 (de) * 1988-09-01 1990-03-15 Roecar Holdings Nv Phyto- und zoosterole und deren derivate mit verbesserter wasserloeslichkeit
DE3838716A1 (de) * 1988-11-15 1990-05-17 Kanoldt Arzneimittel Gmbh Arzneimittelzubereitung aus esterderivaten des hecogenins und dessen verwendung zur behandlung von benigner prostatahyperplasie
US5502038A (en) * 1993-06-21 1996-03-26 Medical Research Foundation Of Oregon Cholesterol sequestrant glycosides that inhibit intestinal cholesterol absorption

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IE35018B1 (en) * 1970-03-18 1975-10-15 Liebenberg R W Therapeutic agent
US3966918A (en) * 1973-12-12 1976-06-29 Nippon Shinyaku Co., Ltd. Method of preparing aqueous solutions of sterol glycosides and their ester derivatives
JPS51118817A (en) * 1975-04-08 1976-10-19 Nippon Shinyaku Co Ltd A process for preparing absorbable steroid glycoside pharmaceutical

Also Published As

Publication number Publication date
IT1109336B (it) 1985-12-16
GB2039217A (en) 1980-08-06
SE466683B (sv) 1992-03-23
AR223334A1 (es) 1981-08-14
NL7812656A (nl) 1979-07-03
IL56345A0 (en) 1979-03-12
JPS54101436A (en) 1979-08-10
IL56345A (en) 1984-11-30
DK587778A (da) 1979-07-01
DE2759171A1 (de) 1979-07-12
FR2425859A1 (fr) 1979-12-14
AU4302478A (en) 1979-07-05
FR2425859B1 (es) 1983-04-08
SE7813443L (sv) 1979-07-01
AU516933B2 (en) 1981-07-02
LU80739A1 (de) 1980-01-22
ZA787399B (en) 1980-01-30
CH637829A5 (de) 1983-08-31
DE2759171C2 (es) 1990-10-25
GB2039217B (en) 1982-08-04
NZ189297A (en) 1984-10-19
PT69012A (pt) 1979-01-01
BE873222A (fr) 1979-06-29
CA1113006A (en) 1981-11-24
IT7852493A0 (it) 1978-12-29

Similar Documents

Publication Publication Date Title
ES476443A1 (es) Procedimiento para la preparacion de esterolinas inhibidorasde la sintesis de las prostaglandinas
Horst et al. Lymphatic absorption and metabolism of orally administered testosterone undecanoate in man
US4829060A (en) 11 Beta-N,N-dimethylaminophenyl-estradienes, their manufacture and pharmaceutical preparations containing them
Miyamura et al. Steroid saponins from Paris polyphylla Sm.-supplement
GB1494097A (en) D-homo-20-keto-pregnanes
GB1503388A (en) Pharmaceutically active complexes and pharmaceutical compositions containing them
Ling et al. Synthesis and in vitro activity of some epimeric 20α-hydroxy, 20-oxime and aziridine pregnene derivatives as inhibitors of human 17α-hydroxylase/C17, 20-lyase and 5α-reductase
NZ188755A (en) Formulations of steroids of estrane,androstane and 19-nor-pregnane series and tocol or a derivative thereof
GB1508745A (en) Steroidal(16alpha,17-d)cyclohexenes
CA1028952A (en) Method of preparing sterol and steroid glycoside compositions
Varma et al. Biosynthesis of Plant Sterols: IX. The mode of oxygenation at carbon atom 26 in the formation of sapogenins from cholesterol
KIM et al. Progesterone derivatives that bind to the digitalis receptor: structure-activity relationships
Goodwin Biosynthesis of plant sterols
GB1495531A (en) 11beta-alkyl steroids of the estrane series
Schneider Metabolism of dehydroisoandrosterone and other steroids by surviving slices of the potato tuber and additional plant tissues
Gustafsson et al. Steroids in meconium from male and female newborn infants
CA1090330A (en) 14.beta.-HYDROXY 3-DEOXYCARDENOLIDES
Chawla et al. Chemical constituents of Tricholepis glaberrima
DE3587160D1 (de) Anwendung von sterolinen und spiroketalinen zur herstellung von medikamenten zur behandlung von psoriasis.
GB1158331A (en) Delta<4,9,11>-Trienes of the 19-Nor-Androstane Series and Process for their manufacture
Kaufmann et al. 21-Hydroxylation of pregnenolone by microsomal preparations of rat and human adrenals
Ponou et al. Manniosides BF, five new triterpenoid saponins from the leaves of Schefflera mannii (Hook. f.) Harms
Elgamal et al. Constituents of local plants
GB1496318A (en) Cholesta-1,5,7-triene-3beta,25-diol and 25-hydroxy-cholesta-1,5,7-trien-3-one
AU529292B2 (en) 17-substituted pregnane steroids

Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20010201